scholarly journals Accurate analysis of the size distribution and crystallinity of boron doped Si nanocrystals via Raman and PL spectra

RSC Advances ◽  
2017 ◽  
Vol 7 (54) ◽  
pp. 34244-34250 ◽  
Author(s):  
X. Jia ◽  
Z. Lin ◽  
T. Zhang ◽  
B. Puthen-Veettil ◽  
T. Yang ◽  
...  

Through fitting of Raman and PL spectra, Si nanocrystal size distributions and Si crystalline fractions are obtained.

1994 ◽  
Vol 358 ◽  
Author(s):  
J. B. Khurgin ◽  
E. W. Forsythe ◽  
S. I. Kim ◽  
B. S. Sywe ◽  
B. A. Khan ◽  
...  

ABSTRACTA systematic study of the PL spectra of Si quantum nanocrystals in the SiO2 matrix has been performed. The results have been fitted to a quantum-confinement model that includes the nanocrystal size dispersion rather than a specific size of the nanocrystal. This serves as a strong confirmation of the confinement-induced nature of the PL. It has been shown that if the dispersion is taken into account, the position of the emission peak as well as the PL width can always be correlated with the average size of the nanocrystal.


RSC Advances ◽  
2015 ◽  
Vol 5 (68) ◽  
pp. 55119-55125 ◽  
Author(s):  
Xuguang Jia ◽  
Pengfei Zhang ◽  
Ziyun Lin ◽  
Rebecca Anthony ◽  
Uwe Kortshagen ◽  
...  

A model is developed to fit the PL spectrum based on spontaneous emission. With this model, we can quantitatively analyse the QD size and its distribution using the PL spectra only, saving the need of time consuming and destructive characterization methods such as TEM.


2011 ◽  
Vol 109 (8) ◽  
pp. 083526 ◽  
Author(s):  
Weiwei Ke ◽  
Xue Feng ◽  
Yidong Huang

Author(s):  
Mo Ji ◽  
Martin Strangwood ◽  
Claire Davis

AbstractThe effects of Nb addition on the recrystallization kinetics and the recrystallized grain size distribution after cold deformation were investigated by using Fe-30Ni and Fe-30Ni-0.044 wt pct Nb steel with comparable starting grain size distributions. The samples were deformed to 0.3 strain at room temperature followed by annealing at 950 °C to 850 °C for various times; the microstructural evolution and the grain size distribution of non- and fully recrystallized samples were characterized, along with the strain-induced precipitates (SIPs) and their size and volume fraction evolution. It was found that Nb addition has little effect on recrystallized grain size distribution, whereas Nb precipitation kinetics (SIP size and number density) affects the recrystallization Avrami exponent depending on the annealing temperature. Faster precipitation coarsening rates at high temperature (950 °C to 900 °C) led to slower recrystallization kinetics but no change on Avrami exponent, despite precipitation occurring before recrystallization. Whereas a slower precipitation coarsening rate at 850 °C gave fine-sized strain-induced precipitates that were effective in reducing the recrystallization Avrami exponent after 50 pct of recrystallization. Both solute drag and precipitation pinning effects have been added onto the JMAK model to account the effect of Nb content on recrystallization Avrami exponent for samples with large grain size distributions.


2004 ◽  
Vol 4 (5) ◽  
pp. 1255-1263 ◽  
Author(s):  
B. Mayer ◽  
M. Schröder ◽  
R. Preusker ◽  
L. Schüller

Abstract. Cloud single scattering properties are mainly determined by the effective radius of the droplet size distribution. There are only few exceptions where the shape of the size distribution affects the optical properties, in particular the rainbow and the glory directions of the scattering phase function. Using observations by the Compact Airborne Spectrographic Imager (CASI) in 180° backscatter geometry, we found that high angular resolution aircraft observations of the glory provide unique new information which is not available from traditional remote sensing techniques: Using only one single wavelength, 753nm, we were able to determine not only optical thickness and effective radius, but also the width of the size distribution at cloud top. Applying this novel technique to the ACE-2 CLOUDYCOLUMN experiment, we found that the size distributions were much narrower than usually assumed in radiation calculations which is in agreement with in-situ observations during this campaign. While the shape of the size distribution has only little relevance for the radiative properties of clouds, it is extremely important for understanding their formation and evolution.


1991 ◽  
Vol 113 (4) ◽  
pp. 402-411 ◽  
Author(s):  
T. J. Labus ◽  
K. F. Neusen ◽  
D. G. Alberts ◽  
T. J. Gores

A basic investigation of the factors which influence the abrasive jet mixing process was conducted. Particle size analysis was performed on abrasive samples for the “as-received” condition, at the exit of the mixing tube, and after cutting a target material. Grit size distributions were obtained through sieve analysis for both water and air collectors. Two different mixing chamber geometries were evaluated, as well as the effects of pressure, abrasive feed rate, cutting speed, and target material properties on particle size distributions. An analysis of the particle size distribution shows that the main particle breakdown is from 180 microns directly to 63 microns or less, for a nominal 80 grit garnet. This selective breakdown occurs during the cutting process, but not during the mixing process.


2005 ◽  
Vol 44 (7) ◽  
pp. 1146-1151 ◽  
Author(s):  
Axel Seifert

Abstract The relation between the slope and shape parameters of the raindrop size distribution parameterized by a gamma distribution is examined. The comparison of results of a simple rain shaft model with an empirical relation based on disdrometer measurements at the surface shows very good agreement, but a more detailed discussion reveals some difficulties—for example, deviations from the gamma shape and the overestimation of collisional breakup.


2014 ◽  
Vol 67 (4) ◽  
pp. 405-412
Author(s):  
Christiane Ribeiro da Silva ◽  
Vládia C. G. de Souza ◽  
Jair C. Koppe

A methodology to determine the size distribution curve of the ROM was developed in a Brazilian iron ore mine. The size of the larger fragments was determined taking photographs and setting the scale of the images to analyze their dimensions (length of their edges and areas). This was implemented according to a specific protocol of sampling that involves split and homogenization stages in situ of a considerable quantity of ore (about 259 metric tonnes). During the sampling process, larger fragments were separated and smaller size material was screened. The methodology was developed initially in order to preview the performance of a primary gyratory crusher that is fed directly from trucks. Operational conditions of the equipment such as closed and open-side settings could be adjusted previously, obtaining different product size distributions. Variability of size of the fragments affects subsequent stages of crushing and can increase circulating load in the circuit. This leads to a decrease of productivity or recovery of the ore dressing. The results showed insignificant errors of accuracy and reproducibility of the sampling protocol when applied to friable itabirite rocks.


2018 ◽  
Vol 9 ◽  
pp. 2287-2296
Author(s):  
Lukáš Ondič ◽  
Marian Varga ◽  
Ivan Pelant ◽  
Alexander Kromka ◽  
Karel Hruška ◽  
...  

We have fabricated two-dimensional photonic crystals (PhCs) on the surface of Si nanocrystal-rich SiO2 layers with the goal to maximize the photoluminescence extraction efficiency in the normal direction. The fabricated periodic structures consist of columns ordered into square and hexagonal pattern with lattice constants computed such that the red photoluminescence of Si nanocrystals (SiNCs) could couple to leaky modes of the PhCs and could be efficiently extracted to surrounding air. Samples having different lattice constants and heights of columns were investigated in order to find the configuration with the best performance. Spectral overlap of the leaky modes with the luminescence spectrum of SiNCs was verified experimentally by measuring photonic band diagrams of the leaky modes employing angle-resolved spectroscopy and also theoretically by computing the reflectance spectra. The extraction enhancement within different spatial angles was evaluated by means of micro-photoluminescence spectroscopy. More than 18-fold extraction enhancement was achieved for light propagating in the normal direction and up to 22% increase in overall intensity was obtained at the spatial collection angle of 14°.


Author(s):  
Runjia Liu ◽  
Yong Zang ◽  
Rui Xiao

Abstract Detailed understanding the particle mixing and segregation dynamic is essential in successfully designing and reasonably operating multicomponent fluidized bed. In this work, a novel fluorescent tracer technique combining image processing method has been used to investigate the mixing and segregation behavior in a binary fluidized bed with wide size distributions. The particle number percentage in each layer for different gas velocities is obtained by an image processing method. Fluidization, mixing and segregation behavior has been discussed in terms of bed pressure drop, gas velocity and mixing index. Different types of binary particle systems, including the jetsam and the flotsam-rich system, are analyzed and compared. The mixing indexes at different minimum fluidization velocities are also analyzed and compared with other work. The results show that the theoretical minimum fluidization velocity calculated from the bed pressure drop cannot represent the whole fluidization for a wide size distribution binary particle system. The effect of a wide size distribution is an inflection point in the mixing index curve. There is also a dead region in the bottom of the bed that consists of particles with large size and a low degree of sphericity. The particles in the dead region are extraordinarily difficult to fluidize and should be considered in the design of fluidized beds in industrial applications.


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