scholarly journals Determination of hydrogen sulfide and hydrogen peroxide in complex samples of milk and urine by spectroscopic standard addition data and chemometrics methods

RSC Advances ◽  
2017 ◽  
Vol 7 (46) ◽  
pp. 28626-28636 ◽  
Author(s):  
Masoud Shariati-Rad ◽  
Narges Salarmand ◽  
Farzaneh Jalilvand
Keyword(s):  
Hydrogen Peroxide ◽  
Hydrogen Sulfide ◽  
Spectroscopic Data ◽  
Standard Addition ◽  
Complex Samples ◽  
Net Analyte Signal ◽  
Analyte Signal ◽  
Standard Additions

Spectroscopic data of standard additions were collected and used to calculate the spectrum of the unknown interferent(s) based on the net analyte signal.

scholarly journals Net Analyte Signal Standard Additions Method for Simultaneous Determination of Sulfamethoxazole and Trimethoprim in Pharmaceutical Formulations and Biological Fluids

2012 ◽  
Vol 9 (2) ◽  
pp. 680-692 ◽  
Author(s):  
M. H. Givianrad ◽  
M. Mohagheghian
Keyword(s):  
Simultaneous Determination ◽  
Biological Fluid ◽  
Biological Fluids ◽  
Aqueous Media ◽  
Standard Addition ◽  
Pharmaceutical Formulations ◽  
Net Analyte Signal ◽  
Analyte Signal ◽  
Standard Additions

The applicability of a novel net analyte signal standard addition method (NASSAM) to the resolving of overlapping spectra corresponding to the sulfamethoxazole and trimethoprim was verified by UV-visible spectrophotometry. The results confirmed that the net analyte signal standard additions method with simultaneous addition of both analytes is suitable for the simultaneous determination of sulfamethoxazole and trimethoprim in aqueous media. Moreover, applying the net analyte signal standard additions method revealed that the two drugs could be determined simultaneously with the concentration ratios of sulfamethoxazole to trimethoprim varying from 1:35 to 60:1 in the mixed samples. In addition, the limits of detections were 0.26 and 0.23 μmol L-1for sulfamethoxazole and trimethoprim, respectively. The proposed method has been effectively applied to the simultaneous determination of sulfamethoxazole and trimethoprim in some synthetic, pharmaceutical formulation and biological fluid samples.

Generalized Net Analyte Signal Standard Addition as a Novel Method for Simultaneous Determination: Application in Spectrophotometric Determination of Some Pesticides

2014 ◽  
Vol 97 (1) ◽  
pp. 252-258 ◽  
Author(s):  
Karim Asadpour-Zeynali ◽  
Elhameh Saeb ◽  
Javad Vallipour ◽  
Mehdi Bamorowat
Keyword(s):  
Spectrophotometric Determination ◽  
Standard Addition ◽  
Standard Addition Method ◽  
Addition Method ◽  
Net Analyte Signal ◽  
Analyte Signal ◽  
Novel Method ◽  
Single Standard ◽  
Generalized Net

Abstract Simultaneous spectrophotometric determination of three neonicotinoid insecticides (acetamiprid,imidacloprid, and thiamethoxam) by a novel methodnamed generalized net analyte signal standard addition method (GNASSAM) in some binary and ternarysynthetic mixtures was investigated. For this purpose, standard addition was performed using a single standard solution consisting of a mixture ofstandards of all analytes. Savings in time and amount of used materials are some of the advantages of this method. All determinations showed appropriate applicability of this method with less than 5% error. This method may be applied for linearlydependent data in the presence of known interferents. The GNASSAM combines the advantages of both the generalized standard addition method and net analyte signal; therefore, it may be a properalternative for some other multivariate methods.

scholarly journals Net analyte signal standard addition method for the simultaneous determination of cadmium and nickel

2009 ◽  
Vol 74 (7) ◽  
pp. 789-799 ◽  
Author(s):  
Karim Asadpour-Zeynali ◽  
Reza Majidi ◽  
Masoud Tahmasebpour
Keyword(s):  
Simultaneous Determination ◽  
Standard Addition ◽  
Differential Pulse ◽  
Single Step ◽  
Standard Addition Method ◽  
Differential Pulse Polarography ◽  
Addition Method ◽  
Net Analyte Signal ◽  
Analyte Signal

A novel net analyte signal standard addition method (NASSAM) is presented for the simultaneous determination of Cd2+ and Ni2+ in their mixture by differential pulse polarography. The method combines the advantages of the standard addition method with the net analyte signal concept, which enables the extraction of information concerning a certain analyte from voltammograms of multi-component mixtures. This method has some advantages, such as: the use of a full voltammogram, realization in a single step, therefore it does not require calibration and prediction steps and only a few measurements are required for the determination. The simultaneous determination of Cd2+ and Ni2+ was performed in Britton-Robinson buffer (pH 2.87) and 0.40 M potassium thiocyanate solution.

scholarly journals Simultaneous Determination of Antazoline and Naphazoline by the Net Analyte Signal Standard Addition Method and Spectrophotometric Technique

2010 ◽  
Vol 93 (6) ◽  
pp. 1995-2001 ◽  
Author(s):  
Karim Asadpour-Zeynali ◽  
Raoof Ghavami ◽  
Roghayeh Esfandiari ◽  
Payam Soheili-Azad
Keyword(s):  
Simultaneous Determination ◽  
Multivariate Calibration ◽  
Standard Addition ◽  
Single Step ◽  
Standard Addition Method ◽  
Addition Method ◽  
Net Analyte Signal ◽  
Analyte Signal ◽  
Calibration Methods

Abstract A novel net analyte signal standard addition method (NASSAM) was used for simultaneous determination of the drugs anthazoline and naphazoline. The NASSAM can be applied for determination of analytes in the presence of known interferents. The proposed method is used to eliminate the calibration and prediction steps of multivariate calibration methods; the determination is carried out in a single step for each analyte. The accuracy of the predictions against the H-point standard addition method is independent of the shape of the analyte and interferent spectra. The net analyte signal concept was also used to calculate multivariate analytical figures of merit, such as LOD, selectivity, and sensitivity. The method was successfully applied to the simultaneous determination of anthazoline and naphazoline in a commercial eye drop sample.

scholarly journals New Method for the On-Line Determination of Molybdenum Via New Microphotometric Home Mode Instrument, Using Hight Emitting Diode as a Variable Intensity Radiant Source with a Miniture Photosilicone Diode Detector for System: Molybdenum(VI)-Hydrogen Peroxide-Ammonium Solution

2007 ◽  
Vol 4 (4) ◽  
pp. 571-582
Author(s):  
Baghdad Science Journal
Keyword(s):  
Hydrogen Peroxide ◽  
Classical Method ◽  
Wave Length ◽  
Research Work ◽  
Standard Addition ◽  
Ammonia Solution ◽  
Variable Intensity ◽  
Measurement Variation ◽  
On Line

This research work aims to the determination of molybdenum (VI) ion via the formation of peroxy molybdenum compounds which has red-brown colour with absorbance wave length at 455nm for the system of ammonia solution-hydrogen peroxide-molybdenum (VI) using a completely newly developed microphotometer based on the ON-Line measurement. Variation of responses expressed in millivolt. A correlation coefficient of 0.9925 for the range of 2.5-150 ?g.ml-1 with percentage linearity of 98.50%. A detection limit of 0.25 ?g.ml-1 was obtained. All physical and chemical variable were optimized interferences of cation and anion were studied classical method of measurement were done and compared well with newly on-line measurements. Application for the use of developed method on alloy samples, using standard addition method and agreed quite wall.

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