scholarly journals Free radical and RAFT polymerization of vinyl esters in metal–organic-frameworks

2017 ◽  
Vol 8 (40) ◽  
pp. 6204-6208 ◽  
Author(s):  
Jongkook Hwang ◽  
Hui-Chun Lee ◽  
Markus Antonietti ◽  
Bernhard V. K. J. Schmidt
Keyword(s):  
Free Radical ◽  
Radical Polymerization ◽  
Raft Polymerization ◽  
Metal Organic Frameworks ◽  
Vinyl Esters ◽  
Reversible Deactivation ◽  
Metal Organic ◽  
Reversible Deactivation Radical Polymerization ◽  
First Time

In here, the reversible deactivation radical polymerization of vinyl esters inside metal–organic frameworks is presented for the first time.

scholarly journals Living Radical Polymerization by the RAFT Process - A Second Update

2009 ◽  
Vol 62 (11) ◽  
pp. 1402 ◽  
Author(s):  
Graeme Moad ◽  
Ezio Rizzardo ◽  
San H. Thang
Keyword(s):  
Radical Polymerization ◽  
Chain Transfer ◽  
Raft Polymerization ◽  
Diverse Range ◽  
Reversible Addition ◽  
Reversible Deactivation ◽  
Modified Surfaces ◽  
Diagnostic Applications ◽  
Reversible Deactivation Radical Polymerization ◽  
End Group

This paper provides a second update to the review of reversible deactivation radical polymerization achieved with thiocarbonylthio compounds (ZC(=S)SR) by a mechanism of reversible addition–fragmentation chain transfer (RAFT) that was published in June 2005 (Aust. J. Chem. 2005, 58, 379–410). The first update was published in November 2006 (Aust. J. Chem. 2006, 59, 669–692). This review cites over 500 papers that appeared during the period mid-2006 to mid-2009 covering various aspects of RAFT polymerization ranging from reagent synthesis and properties, kinetics and mechanism of polymerization, novel polymer syntheses and a diverse range of applications. Significant developments have occurred, particularly in the areas of novel RAFT agents, techniques for end-group removal and transformation, the production of micro/nanoparticles and modified surfaces, and biopolymer conjugates both for therapeutic and diagnostic applications.

scholarly journals Living Radical Polymerization by the RAFT Process – A Third Update

2012 ◽  
Vol 65 (8) ◽  
pp. 985 ◽  
Author(s):  
Graeme Moad ◽  
Ezio Rizzardo ◽  
San H. Thang
Keyword(s):  
Radical Polymerization ◽  
Chain Transfer ◽  
Raft Polymerization ◽  
Diverse Range ◽  
Reversible Addition ◽  
Reversible Deactivation ◽  
Modified Surfaces ◽  
Diagnostic Applications ◽  
Reversible Deactivation Radical Polymerization ◽  
End Group

This paper provides a third update to the review of reversible deactivation radical polymerization (RDRP) achieved with thiocarbonylthio compounds (ZC(=S)SR) by a mechanism of reversible addition-fragmentation chain transfer (RAFT) that was published in June 2005 (Aust. J. Chem. 2005, 58, 379). The first update was published in November 2006 (Aust. J. Chem. 2006, 59, 669) and the second in December 2009 (Aust. J. Chem. 2009, 62, 1402). This review cites over 700 publications that appeared during the period mid 2009 to early 2012 covering various aspects of RAFT polymerization which include reagent synthesis and properties, kinetics and mechanism of polymerization, novel polymer syntheses, and a diverse range of applications. This period has witnessed further significant developments, particularly in the areas of novel RAFT agents, techniques for end-group transformation, the production of micro/nanoparticles and modified surfaces, and biopolymer conjugates both for therapeutic and diagnostic applications.

scholarly journals Determining the effect of side reactions on product distributions in RAFT polymerization by MALDI-TOF MS

2015 ◽  
Vol 6 (30) ◽  
pp. 5437-5450 ◽  
Author(s):  
Antonio Veloso ◽  
Wendy García ◽  
Amaia Agirre ◽  
Nicholas Ballard ◽  
Fernando Ruipérez ◽  
...  
Keyword(s):  
Radical Polymerization ◽  
Raft Polymerization ◽  
Side Reactions ◽  
Maldi Tof Ms ◽  
Maldi Tof ◽  
Product Distributions ◽  
Wide Range ◽  
Reversible Deactivation ◽  
Reversible Deactivation Radical Polymerization ◽  
Tof Ms

RAFT polymerization has emerged as one of the most versatile reversible deactivation radical polymerization techniques and is capable of polymerizing a wide range of monomers under various conditions.

Facile access to functional polyacrylates with dual stimuli response and tunable surface hydrophobicity

2021 ◽  
Author(s):  
Sk Arif Mohammad ◽  
Subrata Dolui ◽  
Devendra Kumar ◽  
Shivshankar R. Mane ◽  
Sanjib Banerjee
Keyword(s):  
Ambient Temperature ◽  
Radical Polymerization ◽  
Methyl Acrylate ◽  
Surface Hydrophobicity ◽  
Alloy Nanoparticles ◽  
Reversible Deactivation ◽  
Stimuli Response ◽  
Magnetically Separable ◽  
Reversible Deactivation Radical Polymerization ◽  
First Time

Magnetically separable and reusable Ni-Co alloy nanoparticles was employed to achieve ambient temperature reversible deactivation radical polymerization (RDRP) of methyl acrylate (MA), for the first time, yielding well-defined PMA (at...

Photocontrolled iodine-mediated reversible-deactivation radical polymerization with a semifluorinated alternating copolymer as the macroinitiator

2020 ◽  
Vol 11 (47) ◽  
pp. 7497-7505
Author(s):  
Jiannan Cheng ◽  
Kai Tu ◽  
Enjie He ◽  
Jinying Wang ◽  
Lifen Zhang ◽  
...  
Keyword(s):  
Block Copolymers ◽  
Radical Polymerization ◽  
Room Temperature ◽  
Blue Led ◽  
Led Light ◽  
Alternating Copolymers ◽  
Alternating Copolymer ◽  
Reversible Deactivation ◽  
Novel Strategy ◽  
Reversible Deactivation Radical Polymerization

A novel strategy for preparing block copolymers with semifluorinated alternating copolymers as macroinitiators was established by photocontrolled iodine-mediated RDRP under irradiation with blue LED light at room temperature.

scholarly journals Cubane Cu4I4(phosphine)4 Complexes as New Co-initiator for Free Radical Photopolymerization: Towards Aromatic Amine-Free Systems

2021 ◽  
Author(s):  
Jacques Lalevée ◽  
Fatima Hammoud ◽  
Mahmoud Rahal ◽  
Julien Egly ◽  
Fabrice Morlet-Savary ◽  
...  
Keyword(s):  
Free Radical ◽  
Radical Polymerization ◽  
Aromatic Amine ◽  
Free Radical Polymerization ◽  
Copper Iodide ◽  
Free Radical Photopolymerization ◽  
Acrylate Monomers ◽  
First Time

The investigation of copper-iodide cubane derivatives as new co-initiators for the free radical polymerization (FRP) of acrylate monomers under mild irradiation conditions is described for the first time here. These...

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