Growth kinetics and mechanisms of multinary copper-based metal sulfide nanocrystals

Nanoscale ◽  
2017 ◽  
Vol 9 (34) ◽  
pp. 12470-12478 ◽  
Author(s):  
Keqiang Chen ◽  
Jing Zhou ◽  
Wen Chen ◽  
Qiaohui Zhong ◽  
Tingqiang Yang ◽  
...  
Keyword(s):  
Growth Kinetics ◽  
Metal Sulfide ◽  
Sulfide Nanocrystals

Schematic for the possible mechanism of the phase tunable synthesis of multinary copper-based metal sulfide NCs.

Simple and Generalized Synthesis of Semiconducting Metal Sulfide Nanocrystals

2009 ◽  
Vol 19 (10) ◽  
pp. 1645-1649 ◽  
Author(s):  
Sang-Hyun Choi ◽  
Kwangjin An ◽  
Eung-Gyu Kim ◽  
Jung Ho Yu ◽  
Jeong Hyun Kim ◽  
...  
Keyword(s):  
Metal Sulfide ◽  
Sulfide Nanocrystals

Generalized and Facile Synthesis of Semiconducting Metal Sulfide Nanocrystals

2003 ◽  
Vol 125 (36) ◽  
pp. 11100-11105 ◽  
Author(s):  
Jin Joo ◽  
Hyon Bin Na ◽  
Taekyung Yu ◽  
Jung Ho Yu ◽  
Young Woon Kim ◽  
...  
Keyword(s):  
Metal Sulfide ◽  
Facile Synthesis ◽  
Sulfide Nanocrystals

scholarly journals From Metal Thiobenzoates to Metal Sulfide Nanocrystals: An Experimental and Theoretical Investigation

Nanomaterials ◽  
2012 ◽  
Vol 2 (2) ◽  
pp. 113-133 ◽  
Author(s):  
Zhihua Zhang ◽  
Wen Pei Lim ◽  
Chiong Teck Wong ◽  
Hairuo Xu ◽  
Fenfang Yin ◽  
...  
Keyword(s):  
Theoretical Investigation ◽  
Metal Sulfide ◽  
Sulfide Nanocrystals

CdS and ZnS Nanoparticles Growth in Different Reaction Media: Synthesis and Characterization

2005 ◽  
Vol 879 ◽  
Author(s):  
F. Antolini ◽  
E. Trave ◽  
L. Mirenghi ◽  
M. Re ◽  
G. Mattei ◽  
...  
Keyword(s):  
Direct Synthesis ◽  
Particle Surface ◽  
Metal Sulfide ◽  
Spherical Shape ◽  
Radiative Transition ◽  
Growth Conditions ◽  
Electron Recombination ◽  
Defect Center ◽  
Average Size ◽  
Sulfide Nanocrystals

AbstractIn this work we report on the growth of cadmium sulfide and zinc sulfide nanocrystals by thermolysis, starting from a metal thiolate in a (i) solventless way, (ii) by a novel route in tryoctilphosphine oxide (TOPO), and (iii) by direct synthesis in a polystyrene matrix. The x-ray diffraction (XRD) and transmission electron microscopy (TEM) show that the nanocrystals fabricated by the different methods are under optimized growth conditions single crystals of zincblende structure and of regular spherical shape. The average size was estimated to be between 2.0-3.0 nm with a size dispersion that depends on the synthesis route and is in the range between 10% and 20%. The XPS results indicate that for the nanoparticles obtained via solventless strategy the sulfur is present both as bonded to the metal atom and to the organic residue, while in the TOPO synthesized nanoparticles the sulfur signal has only one component associated to the metal-sulfide bond. The photoluminescence spectroscopy (PL) analysis of CdS crystals clearly evidences the typical emissions of nanosized zincblende CdS monocrystalline particles. Furthermore, the optical spectroscopy data indicate that the size distribution of the Cdsulfide - TOPO nanoparticles seems to be generally larger than that ones grown directly in polymer matrix. For all the CdS samples, the metal-sulfide nanocrystals exhibit a trap-related radiative transition at about 2eV that can be attributed to the hole-electron recombination at particle surface defect-center.

A Facile “Dispersion-Decomposition” Route to Metal Sulfide Nanocrystals

2011 ◽  
Vol 17 (37) ◽  
pp. 10445-10452 ◽  
Author(s):  
Zhongbin Zhuang ◽  
Xiaotang Lu ◽  
Qing Peng ◽  
Yadong Li
Keyword(s):  
Metal Sulfide ◽  
Sulfide Nanocrystals

Construction of dual-carbon-confined metal sulfide nanocrystals via bio-mimetic reactors enabling superior Fenton-like catalysis

2021 ◽  
Author(s):  
Tao Xu ◽  
Yanping Long ◽  
Chao He ◽  
Xin Song ◽  
Weifeng Zhao ◽  
...  
Keyword(s):  
Metal Sulfide ◽  
Sulfide Nanocrystals

Peroxymonosulfate (PMS) based Fenton-like reactions are widely proposed for the degradation of refractory pollutants. However, the contradiction between achieving delicate architecture of efficient Fenton-like catalysts and the inevitable high operation...

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