Palladium-catalyzed three-component reaction for the synthesis of 3,3-disubstituted allylic alcohols with regio- and stereoselectivity

2018 ◽  
Vol 42 (3) ◽  
pp. 1736-1739 ◽  
Author(s):  
Gang Hu ◽  
Jingtao Wang ◽  
Zefei Li ◽  
Yajing Liu ◽  
Ping Gong

A novel three-component assembly of allenic alcohols, aryl iodides and 1,3-dicarbonyl compounds into 3,3-disubstituted allylic alcohols was promoted in the presence of a palladium source.

2013 ◽  
Vol 125 (35) ◽  
pp. 9475-9478 ◽  
Author(s):  
Qing Xiao ◽  
Binglong Wang ◽  
Leiming Tian ◽  
Yang Yang ◽  
Jian Ma ◽  
...  

Synthesis ◽  
2018 ◽  
Vol 50 (20) ◽  
pp. 4097-4103 ◽  
Author(s):  
Shufeng Chen ◽  
Xin-Xing Wu ◽  
Chenjun Wang ◽  
Wanrong Zhao ◽  
Haiying Zhao

A palladium-catalyzed three-component intermolecular aryl­etherification reaction of ferrocene-substituted allenes, aryl iodides and phenols or alcohols is reported. In this three-component reaction, two new C–C and C–O bonds are formed in one step with high regio- and stereoselectivity. The high selectivity obtained in this reaction can be attributed to the steric effect of the bulky ferrocene group.


2013 ◽  
Vol 52 (35) ◽  
pp. 9305-9308 ◽  
Author(s):  
Qing Xiao ◽  
Binglong Wang ◽  
Leiming Tian ◽  
Yang Yang ◽  
Jian Ma ◽  
...  

ChemInform ◽  
2014 ◽  
Vol 45 (4) ◽  
pp. no-no
Author(s):  
Qing Xiao ◽  
Binglong Wang ◽  
Leiming Tian ◽  
Yang Yang ◽  
Jian Ma ◽  
...  

2018 ◽  
Vol 20 (20) ◽  
pp. 6440-6443 ◽  
Author(s):  
Bo Zhou ◽  
Zhuo Wu ◽  
Ding Ma ◽  
Xiaoming Ji ◽  
Yanghui Zhang

2001 ◽  
Vol 31 (23) ◽  
pp. 3665-3669 ◽  
Author(s):  
Hong Zhao ◽  
Ming-Zhong Cai ◽  
Rong-Hua Hu ◽  
Cai-Sheng Song

2015 ◽  
Vol 6 (5) ◽  
pp. 2777-2781 ◽  
Author(s):  
Yang Yu ◽  
Uttam K. Tambar

A palladium-catalyzed coupling of α-bromocarbonyl compounds and allylic alcohols has been developed for the generation of acyclic aryl-substituted dicarbonyl compounds.


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