ChemInform Abstract: Palladium-Catalyzed Three-Component Reaction of Allenes, Aryl Iodides, and Diazo Compounds: Approach to 1,3-Dienes.

ChemInform ◽  
2014 ◽  
Vol 45 (4) ◽  
pp. no-no
Author(s):  
Qing Xiao ◽  
Binglong Wang ◽  
Leiming Tian ◽  
Yang Yang ◽  
Jian Ma ◽  
...  
Keyword(s):  
Diazo Compounds ◽  
Aryl Iodides ◽  
Three Component Reaction ◽  
Palladium Catalyzed

Palladium‐Catalyzed Three‐Component Reaction of Allenes, Aryl Iodides, and Diazo Compounds: Approach to 1,3‐Dienes

2013 ◽  
Vol 125 (35) ◽  
pp. 9475-9478 ◽  
Author(s):  
Qing Xiao ◽  
Binglong Wang ◽  
Leiming Tian ◽  
Yang Yang ◽  
Jian Ma ◽  
...  
Keyword(s):  
Diazo Compounds ◽  
Aryl Iodides ◽  
Three Component Reaction ◽  
Palladium Catalyzed

Palladium-Catalyzed Three-Component Reaction of Allenes, Aryl Iodides, and Diazo Compounds: Approach to 1,3-Dienes

2013 ◽  
Vol 52 (35) ◽  
pp. 9305-9308 ◽  
Author(s):  
Qing Xiao ◽  
Binglong Wang ◽  
Leiming Tian ◽  
Yang Yang ◽  
Jian Ma ◽  
...  
Keyword(s):  
Diazo Compounds ◽  
Aryl Iodides ◽  
Three Component Reaction ◽  
Palladium Catalyzed

Regio- and Stereoselective Palladium-Catalyzed Intermolecular Three-Component Aryletherification of Terminal Allenes

Synthesis ◽  
2018 ◽  
Vol 50 (20) ◽  
pp. 4097-4103 ◽  
Author(s):  
Shufeng Chen ◽  
Xin-Xing Wu ◽  
Chenjun Wang ◽  
Wanrong Zhao ◽  
Haiying Zhao
Keyword(s):  
Steric Effect ◽  
High Selectivity ◽  
Aryl Iodides ◽  
Three Component Reaction ◽  
Palladium Catalyzed ◽  
One Step

A palladium-catalyzed three-component intermolecular aryl­etherification reaction of ferrocene-substituted allenes, aryl iodides and phenols or alcohols is reported. In this three-component reaction, two new C–C and C–O bonds are formed in one step with high regio- and stereoselectivity. The high selectivity obtained in this reaction can be attributed to the steric effect of the bulky ferrocene group.

Palladium-catalyzed three-component reaction for the synthesis of 3,3-disubstituted allylic alcohols with regio- and stereoselectivity

2018 ◽  
Vol 42 (3) ◽  
pp. 1736-1739 ◽  
Author(s):  
Gang Hu ◽  
Jingtao Wang ◽  
Zefei Li ◽  
Yajing Liu ◽  
Ping Gong
Keyword(s):  
Allylic Alcohols ◽  
Dicarbonyl Compounds ◽  
Aryl Iodides ◽  
Three Component Reaction ◽  
Palladium Catalyzed ◽  
Component Assembly

A novel three-component assembly of allenic alcohols, aryl iodides and 1,3-dicarbonyl compounds into 3,3-disubstituted allylic alcohols was promoted in the presence of a palladium source.

scholarly journals Palladium-Catalyzed Hydroarylation of Diazocarboxylates and Diazophosphonates

Synthesis ◽  
2019 ◽  
Vol 52 (05) ◽  
pp. 775-780
Author(s):  
Sergey M. Golitsin ◽  
Irina P. Beletskaya ◽  
Igor D. Titanyuk
Keyword(s):  
Formic Acid ◽  
Diazo Compounds ◽  
Aryl Iodides ◽  
Synthetic Procedure ◽  
Palladium Catalyzed ◽  
Diazoacetic Ester

A simple synthetic procedure for the Pd-catalyzed hydro­arylation of diazoacetic ester has been previously developed in our laboratory. Now we have applied this methodology for hydroarylation of α-diazocarboxylates/α-diazophosphonates. Diazo compounds reacted with aryl iodides and formic acid to afford diarylated esters or phosphonates in yields up to 71%.

Synthesis of Indoles through Palladium-Catalyzed Three-Component Reaction of Aryl Iodides, Alkynes, and Diaziridinone

2018 ◽  
Vol 20 (20) ◽  
pp. 6440-6443 ◽  
Author(s):  
Bo Zhou ◽  
Zhuo Wu ◽  
Ding Ma ◽  
Xiaoming Ji ◽  
Yanghui Zhang
Keyword(s):  
Aryl Iodides ◽  
Three Component Reaction ◽  
Palladium Catalyzed

Synthesis of S-aryl thioesters via palladium-catalyzed thiocarbonylation of aryl iodides and aryl sulfonyl hydrazides

2020 ◽  
Vol 7 (19) ◽  
pp. 2938-2943
Author(s):  
Yeojin Kim ◽  
Kwang Ho Song ◽  
Sunwoo Lee
Keyword(s):  
Aryl Iodide ◽  
Aryl Iodides ◽  
Palladium Catalyzed

Aryl sulfonyl hydrazide reacted with aryl iodide in the presence of CO to give the corresponding S-aryl thioesters.

Palladium-catalyzed carbonylative transformation of aryl iodides and sulfonyl chlorides: convenient access to thioesters

2020 ◽  
Vol 7 (6) ◽  
pp. 885-889 ◽  
Author(s):  
Xinxin Qi ◽  
Zhi-Peng Bao ◽  
Xiao-Feng Wu
Keyword(s):  
Sulfonyl Chlorides ◽  
Aryl Iodides ◽  
Palladium Catalyzed ◽  
Convenient Access

A palladium-catalyzed carbonylative transformation of aryl iodides and sulfonyl chlorides to thioesters has been studied.

Palladium-Catalyzed Asymmetric Annulation Between Aryl Iodides and Racemic Epoxides Using a Chiral Norbornene Cocatalyst

2018 ◽  
Author(s):  
Guangbin Dong ◽  
Renhe Li
Keyword(s):  
Isopropyl Ester ◽  
Synthetic Route ◽  
Initial Development ◽  
Aryl Iodides ◽  
Palladium Catalyzed

Herein, we describe our initial development of an asymmetric Pd-catalyzed annulation between aryl iodides and racemic epoxides for synthesis of 2,3-dihydrobenzofurans using a chiral norbornene cocatalyst. A series of enantiopure ester-, amide- and imide-substituted norbornenes have been prepared with a reliable synthetic route. Promising enantioselectivity (42-45% ee) has been observed using the isopropyl ester-substituted norbornene (N1*) and the amide-substituted norbornene (N7*).

Sign in / Sign up

Export Citation Format

Share Document