A 3D cadmium–vanadium bimetallic framework with luminescence properties

2017 ◽  
Vol 41 (14) ◽  
pp. 6781-6784 ◽  
Author(s):  
Ning Li ◽  
Jianguo Zhao ◽  
Li Xu ◽  
Zhong Zhang ◽  
Liping Hung ◽  
...  

Luminescent properties of a novel cadmium–vanadium bimetallic 3D framework possessing a pillared-layer.

RSC Advances ◽  
2014 ◽  
Vol 4 (91) ◽  
pp. 49892-49899 ◽  
Author(s):  
Hui Luo ◽  
Yan-Yu Zhu ◽  
Zhen-Gang Sun ◽  
Cheng-Qi Jiao ◽  
Guang-Ning Zhang ◽  
...  

Two new 3D nickel(ii) carboxyphosphonates 1 and 2 were synthesized under hydrothermal conditions. The surface photovoltage and luminescent properties were studied.


2015 ◽  
Vol 47 (3) ◽  
pp. 269-272 ◽  
Author(s):  
M.S. Rabasovic ◽  
D. Sevic ◽  
J. Krizan ◽  
M.D. Rabasovic ◽  
N. Romcevic

In this report presented are structure, morphology and luminescence properties of nanopowders based on gadolinium zirconium oxide (Gd2Zr2O7) doped by europium ions (Eu3+). The nanopowders were prepared using a flame combustion method, the most frequently used process due to the simplicity and low cost of the synthesis procedures and also due to the possibility of tailoring the size and morphology of particles. The produced material is suitable for various optical devices. The luminescence properties of synthesized nanopowders were characterized by emission spectra and luminescence lifetimes obtained by using the streak camera system. Moreover, emission spectra were obtained and compared for powders as-obtained and after additional annealing at 1200o C. Luminescence emission spectra clearly show peaks characteristic for the strong emission lines at 611 nm and 630 nm corresponding to the 5D0 ? 7F2 long lived transition.


2010 ◽  
Vol 663-665 ◽  
pp. 441-444
Author(s):  
Zhen Hua Liang ◽  
Yu Zhi Feng ◽  
Xiao Xia Liu ◽  
Gui Hua Peng

CaMoO4: Eu3+ red phosphors were synthesized by co-precipitation method with H3BO3 as an additive and the relationship between H3BO3 doping amount and luminescent properties were studied. The brightness increased with increasing H3BO3 amount, the brightness of the CaMoO4: Eu3+ powder with 10 mol% H3BO3 was 3.2 times higher than that of the phosphor without H3BO3.


Molecules ◽  
2020 ◽  
Vol 25 (11) ◽  
pp. 2465
Author(s):  
Hai-Yan Ju ◽  
Gang Zhang ◽  
Ming Yang ◽  
De-Zheng Liu ◽  
Yong-Sheng Yang ◽  
...  

The new rigid planar ligand 2,5-bis(3-(pyridine-4-yl)phenyl)thiazolo[5,4-d]thiazole (BPPT) has been synthesized, which is an excellent building block for assembling coordination polymer. Under solvothermal reaction conditions, cadmium ion with BPPT in the presence of various carboxylic acids including (1,1′-biphenyl)-4,4′-dicarboxylic acid (BPDC), isophthalic acid (IP), and benzene-1,3,5-tricarboxylic acid (BTC) gave rise to three coordination complexes, viz, [Cd(BPPT)(BPDA)](BPPT)n (1), [Cd(BPPT) (IP)] (CH3OH) (2), and [Cd3(BPPT)3(BTC)2(H2O)2] (3). The structures of 1, 2, and 3 were characterized by single crystal X-ray diffraction. The IR spectra as well as thermogravimetric and luminescence properties were also investigated. Complex 1 is a two-dimensional (2D) network and further stretched to a 3D supramolecular structure through π–π stacking interaction. The complexes 2 and 3 show 3D framework. The complexes 1, 2, and 3 exhibited luminescence property at room temperature.


2015 ◽  
Vol 68 (2) ◽  
pp. 322 ◽  
Author(s):  
Wenlong Liu ◽  
Mengqiang Wu ◽  
Xueying Wang ◽  
Wei Wang ◽  
Dayu Liu ◽  
...  

Using a hydrothermal synthesis, the self-assembly of MnII ions and 1,4-bis(1-imidazol-yl)-2,5-dimethyl benzene with two dicarboxylate ligands, 2-nitrobenzene-1,4-dicarboxylic acid (2-H2ata) and 5-methylbenzene-1,3-dicarboxylic acid (5-CH3-H2ip) constructed two interesting coordination polymers: [Mn(2-ata)(bimb)]n (1) and {[Mn(5-CH3-ip)(bimb)1.5]·2H2O}n (2), where bimb refers to 1,4-bis(1-imidazol-yl)-2,5-dimethyl benzene. Their structures were determined by single-crystal X-ray diffraction, elemental analysis, and infrared spectroscopy. Complex 1 exhibits a 2-fold interpenetrated pcu net. Complex 2 shows an unusual polycatenated 2D+2D→3D framework. In addition, the solid-state photoluminescent properties of 1 and 2 were investigated at room temperature.


2014 ◽  
Vol 47 ◽  
pp. 37-41 ◽  
Author(s):  
Wei Zhou ◽  
Jing Zhang ◽  
Zhen-Gang Sun ◽  
Yan-Yu Zhu ◽  
Cheng-Qi Jiao ◽  
...  

2014 ◽  
Vol 707 ◽  
pp. 102-105
Author(s):  
Yi Jiang ◽  
Su Wen Li

The optical functionalized YVO4: Eu3+/MCM-41 mesoporous composites were prepared by hydrothermal method. The structure, morphology, luminescence properties and fluorescence dynamics were studied systemically. The compared studies of the luminescence properties of YVO4: Eu3+/MCM-41 with YVO4: Eu3+ nanocrystal were performed. The results show that the YVO4: Eu3+/MCM-41 retains high ordered mesoporous structure of MCM-41. In YVO4: Eu3+/MCM-41, the intrinsic excitation bands of Eu3+ disappears and the lifetimes of Eu3+ become short. The luminescent efficiency of YVO4: Eu3+/MCM-41 is higher than ones of the YVO4: Eu3+ nanocrystal.


2010 ◽  
Vol 34 (11) ◽  
pp. 2429 ◽  
Author(s):  
Na Zhang ◽  
Zhengang Sun ◽  
Yanyu Zhu ◽  
Jing Zhang ◽  
Lei Liu ◽  
...  

2012 ◽  
Vol 600 ◽  
pp. 246-249 ◽  
Author(s):  
Su Wen Li ◽  
Shu Guang Ju

Eu(DBM)3phen@MSBA-15 composite was prepared and the luminescence properties was characterized. The Eu(DBM)3phen complexes are uniformly distributed into the channels of the modified SBA-15. The luminescent properties of Eu(DBM)3phen@MSBA-15 composite are systematically studied in contrast to the pure complexes. The results indicate that the excitation bands assigned to the π-π* electron transition of the ligands in Eu(DBM)3phen@MSBA-15 are narrower than that in Eu3+ complexes, and the 5D0-7F0 transitions emmission become partly allowed. The emission lines for the 5D0-7F2 transitions become broader. The photostability of the emissions improves considerably, which is essential for future applications of RE complexes in molecular optical and electrical devices.


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