Key properties of Ni–MgO–CeO2, Ni–MgO–ZrO2, and Ni–MgO–Ce(1−x)Zr(x)O2catalysts for the reforming of methane with carbon dioxide

2018 ◽  
Vol 20 (7) ◽  
pp. 1621-1633 ◽  
Author(s):  
Won-Jun Jang ◽  
Hak-Min Kim ◽  
Jae-Oh Shim ◽  
Seong-Yeun Yoo ◽  
Kyung-Won Jeon ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Storage Capacity ◽  
Oxygen Storage Capacity ◽  
Catalytic Performance ◽  
Oxygen Storage ◽  
Key Factors

The size of Ni particles and the oxygen storage capacity are found to be the primary and secondary key factors that influence the catalytic performance, respectively.

Pt/porous nanorods of ceria as efficient high temperature catalysts with remarkable catalytic stability for carbon dioxide reforming of methane

2015 ◽  
Vol 3 (35) ◽  
pp. 18074-18082 ◽  
Author(s):  
Zhiyun Zhang ◽  
Jing Li ◽  
Wei Gao ◽  
Yuanyuan Ma ◽  
Yongquan Qu
Keyword(s):  
Carbon Dioxide ◽  
Thermal Stability ◽  
Catalytic Activity ◽  
Storage Capacity ◽  
Oxygen Storage Capacity ◽  
Oxygen Storage ◽  
High Catalytic Activity ◽  
Carbon Dioxide Reforming ◽  
Catalytic Stability ◽  
High Oxygen Storage Capacity

Pt/porous nanorods of CeO2 with a large surface area, a high oxygen storage capacity and a remarkable thermal stability exhibit high catalytic activity and stability for the carbon dioxide reforming of methane reaction at 800 °C.

High oxygen storage capacity and enhanced catalytic performance of NiO/NixCe1−xO2−δ nanorods: synergy between Ni-doping and 1D morphology

RSC Advances ◽  
2015 ◽  
Vol 5 (67) ◽  
pp. 54571-54579 ◽  
Author(s):  
Araceli Romero-Núñez ◽  
Gabriela Díaz
Keyword(s):  
Storage Capacity ◽  
Chemical Properties ◽  
Oxygen Storage Capacity ◽  
Catalytic Performance ◽  
Oxygen Storage ◽  
Doped Ceria ◽  
Ni Doping ◽  
Specific Composition ◽  
Physical Chemical ◽  
High Oxygen Storage Capacity

NiO/Ni-doped ceria nanorods have been synthesized. Their unique structure combines specific composition and 1D morphology, which provide great improvements in their physical chemical properties.

scholarly journals Effect of support oxygen storage capacity on the catalytic performance of Rh nanoparticles for CO2 reforming of methane

2019 ◽  
Vol 243 ◽  
pp. 490-501 ◽  
Author(s):  
Ioannis V. Yentekakis ◽  
Grammatiki Goula ◽  
Maria Hatzisymeon ◽  
Ioanna Betsi-Argyropoulou ◽  
Georgia Botzolaki ◽  
...  
Keyword(s):  
Storage Capacity ◽  
Oxygen Storage Capacity ◽  
Catalytic Performance ◽  
Oxygen Storage ◽  
Co2 Reforming ◽  
Co2 Reforming Of Methane ◽  
Effect Of Support

Enhanced catalytic performance of a Pt-xCeO2/Graphene catalyst for DMFCs by adjusting the crystal-plane and shape of nanoscale ceria

RSC Advances ◽  
2015 ◽  
Vol 5 (91) ◽  
pp. 74899-74906 ◽  
Author(s):  
Weihua Wang ◽  
Mingda Zhu ◽  
Xiaolin Lu ◽  
Yanfang Gao ◽  
Lijun Li ◽  
...  
Keyword(s):  
Carbon Monoxide ◽  
Storage Capacity ◽  
Oxygen Storage Capacity ◽  
Catalytic Performance ◽  
Oxygen Storage ◽  
Crystal Plane

Oxygen storage capacity is influenced by the morphology and crystal-plane(s) of CeO2, which can thus affect the ability of this material to oxidise carbon monoxide.

scholarly journals First of Its Kind Automotive Catalyst Prepared by Recycled PGMs-Catalytic Performance

Catalysts ◽  
2021 ◽  
Vol 11 (8) ◽  
pp. 942
Author(s):  
Anastasia Maria Moschovi ◽  
Mattia Giuliano ◽  
Marios Kourtelesis ◽  
Giovanna Nicol ◽  
Ekaterini Polyzou ◽  
...  
Keyword(s):  
Oxygen Storage Capacity ◽  
Catalytic Performance ◽  
Platinum Group Metals ◽  
Oxygen Storage ◽  
Small Scale ◽  
Gas Mixture ◽  
Oxidation Reactions ◽  
Fresh Catalyst ◽  
Metal Precursors ◽  
Automotive Catalytic Converters

The production of new automotive catalytic converters requires the increase of the quantity of Platinum Group Metals in order to deal with the strict emission standards that are imposed for vehicles. The use of PGMs coming from the recycling of spent autocatalysts could greatly reduce the cost of catalyst production for the automotive industry. This paper presents the synthesis of novel automotive Three-Way Catalysts (PLTWC, Pd/Rh = 55/5, 60 gPGMs/ft3) and diesel oxidation catalysts (PLDOC, Pt/Pd = 3/1, 110 gPGMs/ft3) from recovered PGMs, without further refinement steps. The catalysts were characterized and evaluated in terms of activity in comparison with benchmark catalysts produced using commercial metal precursors. The small-scale catalytic monoliths were successfully synthesized as evidenced by the characterization of the samples with XRF analysis, optical microscopy, and N2 physisorption. Hydrothermal ageing of the catalysts was performed and led to a significant decrease of the specific surface area of all catalysts (recycled and benchmarks) due to sintering of the support material and metal particles. The TWCs were studied for their activity in CO and unburned hydrocarbon oxidation reactions under a slightly lean environment of the gas mixture (λ > 1) as well as for their ability to reduce NOx under a slightly rich gas mixture (λ < 1). Recycled TWC fresh catalyst presented the best performance amongst the catalysts studied for the abatement of all pollutant gases, and they also showed the highest Oxygen Storage Capacity value. Moreover, comparing the aged samples, the catalyst produced from recycled PGMs presented higher activity than the one synthesized with the use of commercial PGM metal precursors. The results obtained for the DOC catalysts showed that the aged PLDOC catalyst outperformed both the fresh catalyst and the aged DOC catalyst prepared with the use of commercial metal precursors for the oxidation of CO, hydrocarbons, and NO. The latter reveals the effect of the presence of several impurities in the recovered PGMs solutions.

Autothermal Reforming of Propane Over Ni Catalysts Supported on a Variety of Perovskites

2007 ◽  
Vol 7 (11) ◽  
pp. 4013-4016 ◽  
Author(s):  
SeungSoo Lim ◽  
DongJu Moon ◽  
JongHo Kim ◽  
YoungChul Kim ◽  
NamCook Park ◽  
...  
Keyword(s):  
Thermal Stability ◽  
Storage Capacity ◽  
Flow Reactor ◽  
Oxygen Storage Capacity ◽  
Autothermal Reforming ◽  
Oxygen Storage ◽  
Hydrogen Yield ◽  
Impregnation Method ◽  
Ni Catalysts ◽  
Atmospheric Flow

Autothermal reforming of propane for hydrogen over Ni catalysts supported on a variety of perovskites was performed in an atmospheric flow reactor. Perovskite is known for its higher thermal stability and oxygen storage capacity, but catalytic activity of itself is low. A sites of the ABO3 structured perovskites were occupied by La while B sites by one of Fe, Co, Ni, and Al by citrate method. The composition of the reactant mixture was H2O/C/O2 = 8.96/1.0/1.1. The changes in the states of the catalysts after reaction were analyzed by XRD, TPD, and TGA. Ni/LaAlO3 catalyst maintained the perovskite structure after reaction. It showed higher hydrogen yield and thermal stability compared to those of the catalysts with Fe, Co, or Ni in B sites. Catalysts prepared by deposition-precipitation (DP) method showed higher activity than those prepared by impregnation method, presumably due to the smaller sizes of the NiO crystal particles.

Mn3O4 doped with highly dispersed Zr species: a new non-noble metal oxide with enhanced activity for three-way catalysis

2016 ◽  
Vol 40 (12) ◽  
pp. 10108-10115 ◽  
Author(s):  
Genyuan Zhao ◽  
Jing Li ◽  
Wenshuang Zhu ◽  
Xueqin Ma ◽  
Yonghua Guo ◽  
...  
Keyword(s):  
Metal Oxide ◽  
Manganese Oxide ◽  
Noble Metal ◽  
Storage Capacity ◽  
Catalytic Properties ◽  
Oxygen Storage Capacity ◽  
Oxide Catalysts ◽  
Oxygen Storage ◽  
Highly Dispersed ◽  
Three Way Catalysis

Herein, we demonstrate the influence of zirconium species on promoting the oxygen storage capacity and three-way catalytic properties of zirconium-manganese oxide catalysts.

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