Pt/porous nanorods of ceria as efficient high temperature catalysts with remarkable catalytic stability for carbon dioxide reforming of methane

2015 ◽  
Vol 3 (35) ◽  
pp. 18074-18082 ◽  
Author(s):  
Zhiyun Zhang ◽  
Jing Li ◽  
Wei Gao ◽  
Yuanyuan Ma ◽  
Yongquan Qu

Pt/porous nanorods of CeO2 with a large surface area, a high oxygen storage capacity and a remarkable thermal stability exhibit high catalytic activity and stability for the carbon dioxide reforming of methane reaction at 800 °C.

2016 ◽  
Vol 6 (3) ◽  
pp. 897-907 ◽  
Author(s):  
Jie Li ◽  
Xiaofei Liu ◽  
Wangcheng Zhan ◽  
Yun Guo ◽  
Yanglong Guo ◽  
...  

Ce0.5Zr0.5O2 prepared by the complexing–coprecipitation method (CZ-2) exhibits higher oxygen storage capacity (OSC) and thermal stability than that prepared by coprecipitation (CZ-1) or the complexing–coprecipitation-solution (CZ-3) method. After being aged at 1100 °C for 6 h, CZ-2a exhibited the highest OSC and catalytic activity.


2019 ◽  
Vol 7 (3) ◽  
pp. 1013-1021 ◽  
Author(s):  
Kosuke Beppu ◽  
Saburo Hosokawa ◽  
Hiroyuki Asakura ◽  
Kentaro Teramura ◽  
Tsunehiro Tanaka

Pd/Sr3(Fe0.8Ni0.2)2O7−δ showed a high catalytic activity for NO reduction under a wide range of oxygen concentrations due to the excellent oxygen storage capacity.


2007 ◽  
Vol 7 (11) ◽  
pp. 4013-4016 ◽  
Author(s):  
SeungSoo Lim ◽  
DongJu Moon ◽  
JongHo Kim ◽  
YoungChul Kim ◽  
NamCook Park ◽  
...  

Autothermal reforming of propane for hydrogen over Ni catalysts supported on a variety of perovskites was performed in an atmospheric flow reactor. Perovskite is known for its higher thermal stability and oxygen storage capacity, but catalytic activity of itself is low. A sites of the ABO3 structured perovskites were occupied by La while B sites by one of Fe, Co, Ni, and Al by citrate method. The composition of the reactant mixture was H2O/C/O2 = 8.96/1.0/1.1. The changes in the states of the catalysts after reaction were analyzed by XRD, TPD, and TGA. Ni/LaAlO3 catalyst maintained the perovskite structure after reaction. It showed higher hydrogen yield and thermal stability compared to those of the catalysts with Fe, Co, or Ni in B sites. Catalysts prepared by deposition-precipitation (DP) method showed higher activity than those prepared by impregnation method, presumably due to the smaller sizes of the NiO crystal particles.


2018 ◽  
Vol 3 (1) ◽  
pp. 75-85 ◽  
Author(s):  
Gregory M. Mullen ◽  
Edward J. Evans ◽  
Benjamin C. Siegert ◽  
Nathan R. Miller ◽  
Benjamin K. Rosselet ◽  
...  

The size of ceria particles influenced the activity of Au/CeO2 catalysts for ethanol oxidation, demonstrating a linear correlation between oxygen storage capacity and catalytic activity.


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