Synthesis and characterization of an iron complex bearing a hemilabile NNN-pincer for catalytic hydrosilylation of organic carbonyl compounds

2018 ◽  
Vol 47 (10) ◽  
pp. 3243-3247 ◽  
Author(s):  
Hsiu-Jung Lin ◽  
Sean Lutz ◽  
Catherine O'Kane ◽  
Matthias Zeller ◽  
Chun-Hsing Chen ◽  
...  
Keyword(s):  
Carbonyl Compounds ◽  
Iron Complex ◽  
Synthesis And Characterization ◽  
Catalytic Hydrosilylation

A new design of a low-coordinate iron complex, bearing a hemilabile ligand, served as an effective hydrosilylation pre-catalyst.

Synthesis and Characterization of an Iron Complex Bearing a Cyclic Tetra-N-heterocyclic Carbene Ligand: An Artifical Heme Analogue?

2015 ◽  
Vol 54 (8) ◽  
pp. 3797-3804 ◽  
Author(s):  
Markus R. Anneser ◽  
Stefan Haslinger ◽  
Alexander Pöthig ◽  
Mirza Cokoja ◽  
Jean-Marie Basset ◽  
...  
Keyword(s):  
Iron Complex ◽  
Synthesis And Characterization

Cu-Catalyzed Borylative and Silylative Transformations of Allenes: Use of β-Functionalized Allyl Copper Intermediates in Organic Synthesis

Synthesis ◽  
2018 ◽  
Vol 50 (09) ◽  
pp. 1737-1749 ◽  
Author(s):  
Tetsuaki Fujihara ◽  
Yasushi Tsuji
Keyword(s):  
Organic Synthesis ◽  
Carbonyl Compounds ◽  
Synthesis And Characterization ◽  
Future Outlook

Herein, copper-catalyzed borylative and silylative transformations of allenes using borylcopper or silylcopper as the active catalytic species are described. First, the synthesis and characterization of borylcopper and silylcopper complexes are briefly introduced. Next, the borylative transformations of allenes are summarized including hydro­boration, carboboration, and borylative allylation of carbonyl compounds. We next deal with the silylative transformations of allenes such as hydrosilylation, carbosilylation, and silylative allylation of carbonyl compounds.1 Introduction2 Synthesis of Borylcopper and Silylcopper Complexes3 Borylative Transformations4 Silylative Transformations5 Conclusions and Future Outlook

Design, Synthesis and Characterization of 2,4-Dimethylphenyl Hydrazine based Chemosensors

2020 ◽  
Vol 4 (1) ◽  
pp. 46-58
Author(s):  
Saema Salim ◽  
Qamar Ali
Keyword(s):  
Carbonyl Compounds ◽  
Biological Properties ◽  
Synthesis And Characterization ◽  
Design Synthesis ◽  
Anti Inflammatory ◽  
Aromatic Carbonyl Compounds

Hydrazones are a unique division of compounds found in various syntheses. They have an important role in synthetic chemistrydue to their different biological properties, such as antifungal, anticonvulsant, antibacterial, antimalarial, anti-inflammatory and anti-TB properties. This paper reports the syntheses of a series of 3 hydrazones based on the condensation of 2,4-dimethylphenyl hydrazine HCl with different aromatic carbonyl compounds. The structures of the synthesized compounds were confirmed by EIMS. These compounds can act as ideal candidates in chemosensor chemistry.

A new anthraquinoid ligand for the iron-catalyzed hydrosilylation of carbonyl compounds at room temperature: new insights and kinetics

2018 ◽  
Vol 47 (21) ◽  
pp. 7272-7281 ◽  
Author(s):  
Álvaro Raya-Barón ◽  
Carmen P. Galdeano-Ruano ◽  
Pascual Oña-Burgos ◽  
Antonio Rodríguez-Diéguez ◽  
Robert Langer ◽  
...  
Keyword(s):  
Carbonyl Compounds ◽  
Room Temperature ◽  
Synthesis And Characterization ◽  
Highly Active ◽  
Aldehydes And Ketones

The synthesis and characterization of a highly active Fe(ii) catalyst for the hydrosilylation of aldehydes and ketones have been described.

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