scholarly journals Heteroleptic nickel(ii)–diNHC complexes and an unusual ‘reverse’ carbene-transfer reaction to silver(i)

2017 ◽  
Vol 46 (34) ◽  
pp. 11318-11326 ◽  
Author(s):  
Han Vinh Huynh ◽  
Christine Hui Min Koh ◽  
Van Ha Nguyen
Keyword(s):  
Transfer Reaction ◽  
Carbene Transfer

An unusual NHC transfer reaction to silver was discovered in the study of heteroleptic nickel dicarbene complexes as aqueous Suzuki–Miyaura catalysts.

Dual Catalysis: Proton/Metal-Catalyzed Tandem Benzofuran Annulation/Carbene Transfer Reaction

2016 ◽  
Vol 18 (6) ◽  
pp. 1322-1325 ◽  
Author(s):  
Jun Ma ◽  
Kai Chen ◽  
Hongguang Fu ◽  
Li Zhang ◽  
Wanqing Wu ◽  
...  
Keyword(s):  
Transfer Reaction ◽  
Carbene Transfer ◽  
Dual Catalysis ◽  
Metal Catalyzed

scholarly journals A fully recyclable heterogenized Cu catalyst for the general carbene transfer reaction in batch and flow

2015 ◽  
Vol 6 (2) ◽  
pp. 1510-1515 ◽  
Author(s):  
Lourdes Maestre ◽  
Erhan Ozkal ◽  
Carles Ayats ◽  
Álvaro Beltrán ◽  
M. Mar Díaz-Requejo ◽  
...  
Keyword(s):  
Transfer Reaction ◽  
Transfer Reactions ◽  
Highly Active ◽  
Cu Catalyst ◽  
Carbene Transfer

Carbene transfer reactions can be performed in batch and flow with a highly active, chemically stable heterogenized tris(triazolyl)methyl copper(i) catalyst.

scholarly journals Copper‐Catalyzed Selective Pyrrole Functionalization by Carbene Transfer Reaction

2020 ◽  
Vol 362 (10) ◽  
pp. 1998-2004 ◽  
Author(s):  
Anabel M. Rodríguez ◽  
Francisco Molina ◽  
M. Mar Díaz‐Requejo ◽  
Pedro J. Pérez
Keyword(s):  
Transfer Reaction ◽  
Carbene Transfer

Sustainable Carbene Transfer Reactions with Iron and Light

Synlett ◽  
2019 ◽  
Vol 30 (17) ◽  
pp. 1929-1934 ◽  
Author(s):  
Claire Empel ◽  
Rene M. Koenigs
Keyword(s):  
Visible Light ◽  
Transfer Reaction ◽  
Reactive Intermediates ◽  
Building Blocks ◽  
Transfer Reactions ◽  
Iron Catalysts ◽  
Metal Free ◽  
Scalable Applications ◽  
Carbene Transfer

Carbenes are versatile, highly reactive intermediates with great importance in chemistry. We recently reported on our findings on safe and scalable applications of hazardous diazoacetonitrile using cheap and commercially available iron catalysts in efficient carbene transfer reactions, ranging from cyclopropanation towards C–H functionalization reactions for the synthesis of biologically important building blocks. More lately, we uncovered the reactivity of diazoalkanes under photochemical conditions using visible light and were able to demonstrate a variety of different, metal-free carbene transfer reactions, which now open up new sustainable ways for the construction of small functional molecules.1 Introduction2 Iron-Catalyzed Carbene Transfer Reactions of Diazoacetonitrile3 Metal-free Carbene Transfer Reaction with Visible Light4 Summary

scholarly journals Front Cover Picture: Copper‐Catalyzed Selective Pyrrole Functionalization by Carbene Transfer Reaction (Adv. Synth. Catal. 10/2020)

2020 ◽  
Vol 362 (10) ◽  
pp. 1905-1905
Author(s):  
Anabel M. Rodríguez ◽  
Francisco Molina ◽  
M. Mar Díaz‐Requejo ◽  
Pedro J. Pérez
Keyword(s):  
Transfer Reaction ◽  
Front Cover ◽  
Carbene Transfer
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