scholarly journals Copper‐Catalyzed Selective Pyrrole Functionalization by Carbene Transfer Reaction

2020 ◽  
Vol 362 (10) ◽  
pp. 1998-2004 ◽  
Author(s):  
Anabel M. Rodríguez ◽  
Francisco Molina ◽  
M. Mar Díaz‐Requejo ◽  
Pedro J. Pérez
2017 ◽  
Vol 46 (34) ◽  
pp. 11318-11326 ◽  
Author(s):  
Han Vinh Huynh ◽  
Christine Hui Min Koh ◽  
Van Ha Nguyen

An unusual NHC transfer reaction to silver was discovered in the study of heteroleptic nickel dicarbene complexes as aqueous Suzuki–Miyaura catalysts.


2016 ◽  
Vol 18 (6) ◽  
pp. 1322-1325 ◽  
Author(s):  
Jun Ma ◽  
Kai Chen ◽  
Hongguang Fu ◽  
Li Zhang ◽  
Wanqing Wu ◽  
...  

2015 ◽  
Vol 6 (2) ◽  
pp. 1510-1515 ◽  
Author(s):  
Lourdes Maestre ◽  
Erhan Ozkal ◽  
Carles Ayats ◽  
Álvaro Beltrán ◽  
M. Mar Díaz-Requejo ◽  
...  

Carbene transfer reactions can be performed in batch and flow with a highly active, chemically stable heterogenized tris(triazolyl)methyl copper(i) catalyst.


Synlett ◽  
2019 ◽  
Vol 30 (17) ◽  
pp. 1929-1934 ◽  
Author(s):  
Claire Empel ◽  
Rene M. Koenigs

Carbenes are versatile, highly reactive intermediates with great importance in chemistry. We recently reported on our findings on safe and scalable applications of hazardous diazoacetonitrile using cheap and commercially available iron catalysts in efficient carbene transfer reactions, ranging from cyclopropanation towards C–H functionalization reactions for the synthesis of biologically important building blocks. More lately, we uncovered the reactivity of diazoalkanes under photochemical conditions using visible light and were able to demonstrate a variety of different, metal-free carbene transfer reactions, which now open up new sustainable ways for the construction of small functional molecules.1 Introduction2 Iron-Catalyzed Carbene Transfer Reactions of Diazoacetonitrile3 Metal-free Carbene Transfer Reaction with Visible Light4 Summary


2020 ◽  
Vol 362 (10) ◽  
pp. 1905-1905
Author(s):  
Anabel M. Rodríguez ◽  
Francisco Molina ◽  
M. Mar Díaz‐Requejo ◽  
Pedro J. Pérez

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