Luminescent Tb(iii) and Sm(iii) complexes with a 1,4,7-triazacyclononane-based tris-aryloxide ligand for high-performance oxygen sensors

2017 ◽  
Vol 46 (28) ◽  
pp. 9126-9130 ◽  
Author(s):  
Hidetaka Nakai ◽  
Masafumi Kuyama ◽  
Juncheol Seo ◽  
Takahiro Goto ◽  
Takahiro Matsumoto ◽  
...  

This paper presents (i) a high-performance Tb(iii)-based oxygen sensor (1Tb/PS) and (ii) a lanthanide(iii)-based colorimetric luminescent oxygen sensor (1TbSm/PS).

2017 ◽  
Vol 5 (44) ◽  
pp. 11395-11402 ◽  
Author(s):  
Yongyun Mao ◽  
Qian Zhao ◽  
Jianchang Wu ◽  
Tingting Pan ◽  
Bingpu Zhou ◽  
...  

Organic–inorganic hybrid 3-(trimethoxysily)propylmethacrylate-co-platinum porphyrin-co-methacrylolsobutyl-polyhedral oligomeric silsesquioxane (TPMA-PtTPP-POSS) copolymer films were synthesized and applied as high-performance oxygen sensors.


2017 ◽  
Vol 41 (14) ◽  
pp. 6646-6652 ◽  
Author(s):  
Ke Zhang ◽  
Lingling Luo ◽  
Wenjie Li ◽  
Honglin Zhang ◽  
Yi Zhang ◽  
...  

A ratiometric dissolved oxygen sensor synthesized via a swelling method exhibits high sensitivity, good reversibility and photo-stability.


2021 ◽  
Vol 11 (1) ◽  
Author(s):  
Philip E. Schaner ◽  
Ly-Binh-An Tran ◽  
Bassem I. Zaki ◽  
Harold M. Swartz ◽  
Eugene Demidenko ◽  
...  

AbstractDuring a first-in-humans clinical trial investigating electron paramagnetic resonance tumor oximetry, a patient injected with the particulate oxygen sensor Printex ink was found to have unexpected fluorodeoxyglucose (FDG) uptake in a dermal nodule via positron emission tomography (PET). This nodule co-localized with the Printex ink injection; biopsy of the area, due to concern for malignancy, revealed findings consistent with ink and an associated inflammatory reaction. Investigations were subsequently performed to assess the impact of oxygen sensors on FDG-PET/CT imaging. A retrospective analysis of three clinical tumor oximetry trials involving two oxygen sensors (charcoal particulates and LiNc-BuO microcrystals) in 22 patients was performed to evaluate FDG imaging characteristics. The impact of clinically used oxygen sensors (carbon black, charcoal particulates, LiNc-BuO microcrystals) on FDG-PET/CT imaging after implantation in rat muscle (n = 12) was investigated. The retrospective review revealed no other patients with FDG avidity associated with particulate sensors. The preclinical investigation found no injected oxygen sensor whose mean standard uptake values differed significantly from sham injections. The risk of a false-positive FDG-PET/CT scan due to oxygen sensors appears low. However, in the right clinical context the potential exists that an associated inflammatory reaction may confound interpretation.


2016 ◽  
Vol 4 (29) ◽  
pp. 11422-11429 ◽  
Author(s):  
Lei Yao ◽  
Gang Ou ◽  
Wei Liu ◽  
Xiaohui Zhao ◽  
Hiroki Nishijima ◽  
...  

Fabrication of oxygen sensors using Ce0.8Sm0.1Nd0.1O2−δ/Al2O3multilayered electrolytes with high interfacial ionic conductivity which endows the sensors with low operating temperature and excellent performances.


1990 ◽  
Vol 1 (1-6) ◽  
pp. 312-318 ◽  
Author(s):  
Akiyoshi Asada ◽  
Hideo Yamamoto ◽  
Mitsuhiro Nakazawa ◽  
Hiroshi Osanai

2020 ◽  
Vol 896 ◽  
pp. 249-254
Author(s):  
Dragos Tutunea ◽  
Ilie Dumitru ◽  
Oana Victoria Oţăt ◽  
Laurentiu Racila ◽  
Ionuţ Daniel Geonea ◽  
...  

During the operation of internal combustion engines the air-fuel ratio (A/F) is an important parameter which affects fuel consumption and pollutant emissions. The automotive oxygen sensor (Lambda) measures the quantity of residual oxygen in the combustion gases. Sensor degradation in time due to the exposure to high temperatures causes a distortion in controlling the A/F with the increase in gas emissions. In this paper an experimental stand is designed to test oxygen sensor degradation in laboratory condition. Four oxygen sensors were tested function of temperature and time recording their variation in resistance and voltage. The results showed similar values in the curves for all sensors tested.


2014 ◽  
Vol 2 (36) ◽  
pp. 7589-7598 ◽  
Author(s):  
L. H. Hutter ◽  
B. J. Müller ◽  
K. Koren ◽  
S. M. Borisov ◽  
I. Klimant

New high performance optical oxygen sensing materials based on NIR-emitting indicators covalently bound to various polymers overcome main limitations of the conventional sensors.


2014 ◽  
Vol 605 ◽  
pp. 483-486 ◽  
Author(s):  
Katarina Cvejin ◽  
Libu Manjakkal ◽  
Jan Kulawik ◽  
Krzysztof Zaraska ◽  
Dorota Szwagierczak

Perovskites with formula A1-xSrxBO3-δ (A = La, Nd, Sm; B = Fe or Co) have been synthesized by solid state reaction method and have been studied as materials for oxygen sensor application. The obtained powders were used for making thick film pastes that were later screen printed as sensing electrodes on yttria stabilized zirconia (YSZ) substrates. Sensing electrodes were exposed to low concentration oxygen gas at elevated temperatures. Measurements of the electromotive force of electrochemical cells with the fabricated electrodes were carried out as a function of temperature. The investigation indicated that all of the synthesized materials show Nernstian behavior in a relatively wide temperature range, although the most promising for oxygen electrochemical sensor application is strontium doped samarium cobaltite.


2013 ◽  
Vol 2013 ◽  
pp. 1-8 ◽  
Author(s):  
M. V. Miniaev ◽  
M. B. Belyakova ◽  
N. V. Kostiuk ◽  
D. V. Leshchenko ◽  
T. A. Fedotova

Well-known cause of frequent failures of closed oxygen sensors is the appearance of gas bubbles in the electrolyte. The problem is traditionally associated with insufficient sealing of the sensor that is not always true. Study of a typical temperature regime of measurement system based on Clark sensor showed that spontaneous release of the gas phase is a natural effect caused by periodic warming of the sensor to a temperature of the test liquid. The warming of the sensor together with the incubation medium causes oversaturation of electrolyte by dissolved gases and the allocation of gas bubbles. The lower rate of sensor heating in comparison with the medium reduces but does not eliminate the manifestation of this effect. It is experimentally established, that with each cycle of heating of measuring system up to 37°C followed by cooling the volume of gas phase in the electrolyte (KCl; 60 g/L; 400 μL) increased by 0.6 μL approximately. Thus, during just several cycles it can dramatically degrade the characteristics of the sensor. A method was developed in which the oxygen sensor is heated in contact with the liquid, (depleted of dissolved gases), allowing complete exclusion of the above-mentioned effect.


RSC Advances ◽  
2014 ◽  
Vol 4 (95) ◽  
pp. 52903-52910 ◽  
Author(s):  
Chen-Shiun Chou ◽  
Yung-Chen Wu ◽  
Che-Hsin Lin

This paper presents a novel ultraviolet (UV) irradiation assisted nanostructured ZnO film for high performance oxygen sensing under a low working temperature.


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