Synthesis and characterization of a family of thioether-dithiolate-bridged heteronuclear iron complexes

2017 ◽  
Vol 46 (21) ◽  
pp. 7030-7038 ◽  
Author(s):  
Yahui Zhang ◽  
Dawei Yang ◽  
Ying Li ◽  
Baomin Wang ◽  
Xiangyu Zhao ◽  
...  
Keyword(s):  
Iron Complexes ◽  
Synthesis And Characterization ◽  
Spectroscopy Studies

Five heterotrinuclear complexes and one heterobinuclear complex are successfully synthesized. These complexes are all well characterized by various spectroscopy studies.

scholarly journals A Facially Coordinating Tris-Benzimidazole Ligand for Nonheme Iron Enzyme Models

2020 ◽  
Author(s):  
David Lacy ◽  
Parami Gunasekera ◽  
Preshit Abhyankar ◽  
Samantha N. Macmillan
Keyword(s):  
Structural Models ◽  
Iron Complexes ◽  
Nonheme Iron ◽  
Synthesis And Characterization ◽  
Enzyme Models

This work describes the synthesis and characterization of new ligands and iron complexes for mononuclear nonheme iron oxygenase structural models.

Synthesis and Characterization of Iron Complexes with Monoanionic and DianionicN,N‘,N‘ ‘-Trialkylguanidinate Ligands

2002 ◽  
Vol 41 (16) ◽  
pp. 4149-4157 ◽  
Author(s):  
Stephen R. Foley ◽  
Glenn P. A. Yap ◽  
Darrin S. Richeson
Keyword(s):  
Iron Complexes ◽  
Synthesis And Characterization

Synthesis and characterization of conducting polypyrrole-containing iron complexes

1987 ◽  
Vol 48 (7) ◽  
pp. 635-640 ◽  
Author(s):  
J. Przyłuski ◽  
M. Zagórska ◽  
A. Proń ◽  
Z. Kucharski ◽  
J. Suwalski
Keyword(s):  
Iron Complexes ◽  
Synthesis And Characterization ◽  
Conducting Polypyrrole

Synthesis and Characterization of Diethynylated Tricarbonyl(cyclobutadiene)iron Complexes: The ortho-Lithiation Concept

1994 ◽  
Vol 13 (12) ◽  
pp. 4649-4651 ◽  
Author(s):  
Jutta E. C. Wiegelmann ◽  
Uwe H. F. Bunz ◽  
Patricia Schiel
Keyword(s):  
Iron Complexes ◽  
Synthesis And Characterization

scholarly journals Synthesis and characterization of [Fe(NCCH3)6][cis-Fe(InX3)2(CO)4] (X = Cl, Br, I) containing two terminal indium fragments

2016 ◽  
Vol 45 (4) ◽  
pp. 1327-1330 ◽  
Author(s):  
Masumi Itazaki ◽  
Masaki Ito ◽  
Satoru Nakashima ◽  
Hiroshi Nakazawa
Keyword(s):  
Ir Spectroscopy ◽  
Iron Complexes ◽  
Synthesis And Characterization ◽  
Covalent Bonds ◽  
Bonding Mode ◽  
Anionic Part

The first example of iron complexes containing two Fe–In covalent bonds, [Fe(NCCH3)6][cis-Fe(InX3)2(CO)4] (X = Cl:1, Br:2, I:3), were synthesized and the bonding mode of the Fe–In bonds in the anionic part was investigated using57Fe Mössbauer and IR spectroscopy.

scholarly journals Synthesis and Characterization of Bidentate Isonitrile Iron Complexes

2021 ◽  
Author(s):  
Marion Till ◽  
John A. Kelly ◽  
Christoph G. P. Ziegler ◽  
Robert Wolf ◽  
Tianao Guo ◽  
...  
Keyword(s):  
New Species ◽  
Ir Spectroscopy ◽  
Iron Complexes ◽  
Molecular Structures ◽  
Synthesis And Characterization ◽  
Carbonyl Complexes ◽  
Subsequent Reduction ◽  
X Ray ◽  
X Ray Crystallography

Divalent iron complexes trans-[FeBr2(BINC)2], [Cp*FeCl(BINC)] (Cp* = Me5C5) and [FeBr2(CNAr3NC)2] with chelat-ing bis(isonitrile) ligands BINC (bis(2-isocyanophenyl)phenylphosphonate) and CNAr3NC (2,2’’-diisocyano-3,5,3’’,5’’tetramethyl-1,1’:3’,1’’-terphenyl) have been prepared and characterized. Their subsequent reduction yields di- and trinuclear compounds [Fe3(BINC)6], [Cp*Fe(BINC)]2, [Fe(CNAr3NC)2]2 and [K(Et2O)]2[Fe(CNAr3NC)2]2. The molecular structures of all new species were determined by X-ray crystallography. The molecular structures are compared to related iron carbonyl complexes. The complexes were further characterized by NMR and IR spectroscopy, and the electrochemical properties of selected compounds were analyzed by UV-Vis-NIR spectroelectrochemistry. <br>

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