Synthesis and Characterization of Diethynylated Tricarbonyl(cyclobutadiene)iron Complexes: The ortho-Lithiation Concept

1994 ◽  
Vol 13 (12) ◽  
pp. 4649-4651 ◽  
Author(s):  
Jutta E. C. Wiegelmann ◽  
Uwe H. F. Bunz ◽  
Patricia Schiel
2020 ◽  
Author(s):  
David Lacy ◽  
Parami Gunasekera ◽  
Preshit Abhyankar ◽  
Samantha N. Macmillan

This work describes the synthesis and characterization of new ligands and iron complexes for mononuclear nonheme iron oxygenase structural models.


2002 ◽  
Vol 41 (16) ◽  
pp. 4149-4157 ◽  
Author(s):  
Stephen R. Foley ◽  
Glenn P. A. Yap ◽  
Darrin S. Richeson

2017 ◽  
Vol 46 (21) ◽  
pp. 7030-7038 ◽  
Author(s):  
Yahui Zhang ◽  
Dawei Yang ◽  
Ying Li ◽  
Baomin Wang ◽  
Xiangyu Zhao ◽  
...  

Five heterotrinuclear complexes and one heterobinuclear complex are successfully synthesized. These complexes are all well characterized by various spectroscopy studies.


1987 ◽  
Vol 48 (7) ◽  
pp. 635-640 ◽  
Author(s):  
J. Przyłuski ◽  
M. Zagórska ◽  
A. Proń ◽  
Z. Kucharski ◽  
J. Suwalski

2016 ◽  
Vol 45 (4) ◽  
pp. 1327-1330 ◽  
Author(s):  
Masumi Itazaki ◽  
Masaki Ito ◽  
Satoru Nakashima ◽  
Hiroshi Nakazawa

The first example of iron complexes containing two Fe–In covalent bonds, [Fe(NCCH3)6][cis-Fe(InX3)2(CO)4] (X = Cl:1, Br:2, I:3), were synthesized and the bonding mode of the Fe–In bonds in the anionic part was investigated using57Fe Mössbauer and IR spectroscopy.


2021 ◽  
Author(s):  
Marion Till ◽  
John A. Kelly ◽  
Christoph G. P. Ziegler ◽  
Robert Wolf ◽  
Tianao Guo ◽  
...  

Divalent iron complexes trans-[FeBr2(BINC)2], [Cp*FeCl(BINC)] (Cp* = Me5C5) and [FeBr2(CNAr3NC)2] with chelat-ing bis(isonitrile) ligands BINC (bis(2-isocyanophenyl)phenylphosphonate) and CNAr3NC (2,2’’-diisocyano-3,5,3’’,5’’tetramethyl-1,1’:3’,1’’-terphenyl) have been prepared and characterized. Their subsequent reduction yields di- and trinuclear compounds [Fe3(BINC)6], [Cp*Fe(BINC)]2, [Fe(CNAr3NC)2]2 and [K(Et2O)]2[Fe(CNAr3NC)2]2. The molecular structures of all new species were determined by X-ray crystallography. The molecular structures are compared to related iron carbonyl complexes. The complexes were further characterized by NMR and IR spectroscopy, and the electrochemical properties of selected compounds were analyzed by UV-Vis-NIR spectroelectrochemistry. <br>


Sign in / Sign up

Export Citation Format

Share Document