Ni(ii)–N′NN′ pincer complexes catalyzed dehydrogenation of primary alcohols to carboxylic acids and H2accompanied by alcohol etherification

2017 ◽  
Vol 7 (12) ◽  
pp. 2506-2511 ◽  
Author(s):  
Zengjin Dai ◽  
Qin Luo ◽  
Huan Jiang ◽  
Qi Luo ◽  
Hua Li ◽  
...  
Keyword(s):  
Carboxylic Acids ◽  
Pincer Complexes ◽  
Primary Alcohols

Ni(L)catalyzed acceptorless dehydrogenation of alcohol/alkoxide to carboxylate with H2liberation.

ChemInform Abstract: Superoxide (O2-.)-Initiated Oxidation of Primary Alcohols to Carboxylic Acids.

ChemInform ◽  
2010 ◽  
Vol 22 (44) ◽  
pp. no-no
Author(s):  
M. SINGH ◽  
K. N. SINGH ◽  
S. DWIVEDI ◽  
R. A. MISRA
Keyword(s):  
Carboxylic Acids ◽  
Primary Alcohols

An Improved and Practical Sharpless Oxidation of Primary Alcohols to the Carboxylic Acids

1999 ◽  
Vol 29 (17) ◽  
pp. 2937-2942 ◽  
Author(s):  
Mahavir Prashad ◽  
Yansong Lu ◽  
Hong-Yong Kim ◽  
Bin Hu ◽  
Oljan Repic ◽  
...  
Keyword(s):  
Carboxylic Acids ◽  
Primary Alcohols

Direct Oxidation of Primary Alcohols to Carboxylic Acids

Synthesis ◽  
2020 ◽  
Author(s):  
Travis J. Williams ◽  
Valeriy Cherepakhin
Keyword(s):  
Carboxylic Acids ◽  
Direct Synthesis ◽  
Primary Alcohol ◽  
Alcohol Oxidation ◽  
Atom Economy ◽  
Primary Alcohols ◽  
Direct Oxidation ◽  
Metal Compounds ◽  
New Methods ◽  
Active Research

AbstractOxidation of primary alcohols to carboxylic acids is a fundamental transformation in organic chemistry, yet despite its simplicity, extensive use, and relationship to pH, it remains a subject of active research for synthetic organic chemists. Since 2013, a great number of new methods have emerged that utilize transition-metal compounds as catalysts for acceptorless dehydrogenation of alcohols to carboxylates. The interest in this reaction is explained by its atom economy, which is in accord with the principles of sustainability and green chemistry. Therefore, the methods for the direct synthesis of carboxylic acids from alcohols is ripe for a modern survey, which we provide in this review.1 Introduction2 Thermodynamics of Primary Alcohol Oxidation3 Oxometalate Oxidation4 Transfer Dehydrogenation5 Acceptorless Dehydrogenation6 Electrochemical Methods7 Outlook

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