Front Cover: Catalytic C-Alkylation of Pyrroles with Primary Alcohols: Hans Fischer's Alkali and a New Method with Iridium P,N,P-Pincer Complexes (Eur. J. Org. Chem. 14/2018)

2018 ◽  
Vol 2018 (14) ◽  
pp. 1614-1614
Author(s):  
Sebastian Koller ◽  
Max Blazejak ◽  
Lukas Hintermann
Keyword(s):  
New Method ◽  
Pincer Complexes ◽  
Primary Alcohols ◽  
Front Cover

Research Progress of N-Alkylation of Alcohol and Amine by "Hydrogen Reaction"

2021 ◽  
Vol 871 ◽  
pp. 312-317
Author(s):  
Si Min Feng ◽  
Qing Liu
Keyword(s):  
Natural Products ◽  
Heterocyclic Compounds ◽  
Amino Alcohols ◽  
New Method ◽  
Research Progress ◽  
Primary Alcohols ◽  
Ammonia Gas ◽  
Fine Chemical ◽  
Chemical Products ◽  
Amine Compounds

Amine compounds are widely found in natural products, pharmaceuticals and fine chemical products. Therefore, it is of great significance to develop methods for synthesizing amine compounds. Therefore, in recent years, a new method of synthesizing amines has been developed, namely "hydrogen borrowing reaction". This article reviews the alkylation of primary alcohols and amines, the cyclization of amino alcohols to form N-heterocyclic compounds, the reaction of diols and amines to form N-heterocyclic compounds, the reaction of alcohols and sulfonamides, and the reaction of alcohols and amines containing N heteroatoms , Alcohol and ammonia gas and ammonia to produce amine by hydrogen reaction research progress.

Ni(ii)–N′NN′ pincer complexes catalyzed dehydrogenation of primary alcohols to carboxylic acids and H2accompanied by alcohol etherification

2017 ◽  
Vol 7 (12) ◽  
pp. 2506-2511 ◽  
Author(s):  
Zengjin Dai ◽  
Qin Luo ◽  
Huan Jiang ◽  
Qi Luo ◽  
Hua Li ◽  
...  
Keyword(s):  
Carboxylic Acids ◽  
Pincer Complexes ◽  
Primary Alcohols

Ni(L)catalyzed acceptorless dehydrogenation of alcohol/alkoxide to carboxylate with H2liberation.

scholarly journals Front Cover: Metal‐ligand cooperative activation of HX (X=H, Br, OR) bond on Mn based pincer complexes (14/2021)

2021 ◽  
Vol 647 (14) ◽  
pp. 1397-1397
Author(s):  
Annika M. Krieger ◽  
Vivek Sinha ◽  
Adarsh V. Kalikadien ◽  
Evgeny A. Pidko
Keyword(s):  
Pincer Complexes ◽  
Front Cover ◽  
Cooperative Activation ◽  
Metal Ligand

ChemInform Abstract: Co(II) PCP Pincer Complexes as Catalysts for the Alkylation of Aromatic Amines with Primary Alcohols.

ChemInform ◽  
2016 ◽  
Vol 47 (48) ◽  
Author(s):  
Matthias Mastalir ◽  
Gerald Tomsu ◽  
Ernst Pittenauer ◽  
Guenter Allmaier ◽  
Karl Kirchner
Keyword(s):  
Aromatic Amines ◽  
Pincer Complexes ◽  
Primary Alcohols ◽  
Pcp Pincer

Co(II) PCP Pincer Complexes as Catalysts for the Alkylation of Aromatic Amines with Primary Alcohols

2016 ◽  
Vol 18 (14) ◽  
pp. 3462-3465 ◽  
Author(s):  
Matthias Mastalir ◽  
Gerald Tomsu ◽  
Ernst Pittenauer ◽  
Günter Allmaier ◽  
Karl Kirchner
Keyword(s):  
Aromatic Amines ◽  
Pincer Complexes ◽  
Primary Alcohols ◽  
Pcp Pincer

scholarly journals Reversible catalytic dehydrogenation of alcohols for energy storage

2015 ◽  
Vol 112 (6) ◽  
pp. 1687-1692 ◽  
Author(s):  
Peter J. Bonitatibus ◽  
Sumit Chakraborty ◽  
Mark D. Doherty ◽  
Oltea Siclovan ◽  
William D. Jones ◽  
...  
Keyword(s):  
Energy Storage ◽  
Fuel Cell ◽  
Homogeneous Catalysis ◽  
Partial Oxidation ◽  
Catalytic Reaction ◽  
Pincer Complexes ◽  
Catalytic Dehydrogenation ◽  
Secondary Alcohols ◽  
Iridium Complexes ◽  
Primary Alcohols

Reversibility of a dehydrogenation/hydrogenation catalytic reaction has been an elusive target for homogeneous catalysis. In this report, reversible acceptorless dehydrogenation of secondary alcohols and diols on iron pincer complexes and reversible oxidative dehydrogenation of primary alcohols/reduction of aldehydes with separate transfer of protons and electrons on iridium complexes are shown. This reactivity suggests a strategy for the development of reversible fuel cell electrocatalysts for partial oxidation (dehydrogenation) of hydroxyl-containing fuels.

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