Phase equilibrium and physical properties of biobased ionic liquid mixtures

2018 ◽  
Vol 20 (9) ◽  
pp. 6469-6479 ◽  
Author(s):  
Ariel A. C. Toledo Hijo ◽  
Guilherme J. Maximo ◽  
Rosiane L. Cunha ◽  
Felipe H. S. Fonseca ◽  
Lisandro P. Cardoso ◽  
...  
Keyword(s):  
Ionic Liquid ◽  
Phase Equilibrium ◽  
Liquid Crystals ◽  
Physical Properties ◽  
Liquid Mixtures ◽  
Protic Ionic Liquid ◽  
Natural Sources ◽  
Ionic Liquid Crystals

Protic ionic liquid crystals (PILCs) obtained from natural sources are promising compounds due to their peculiar properties and sustainable appeal.

scholarly journals Fatty Acid-Derived Ionic Liquid Lubricant. Protic Ionic Liquid Crystals as Protic Ionic Liquid Additives

Coatings ◽  
2019 ◽  
Vol 9 (11) ◽  
pp. 710 ◽  
Author(s):  
María-Dolores Avilés ◽  
Ramón Pamies ◽  
José Sanes ◽  
Francisco-José Carrión ◽  
María-Dolores Bermúdez
Keyword(s):  
Ionic Liquid ◽  
Ionic Liquids ◽  
Liquid Crystal ◽  
Fatty Acid ◽  
Liquid Crystals ◽  
Water Evaporation ◽  
Protic Ionic Liquid ◽  
X Ray ◽  
Sliding Surfaces ◽  
Ionic Liquid Crystals

Fatty acids are natural products which have been studied as green lubricants. Ionic liquids are considered efficient friction reducing and wear preventing lubricants and lubricant additives. Fatty acid-derived ionic liquids have shown potential as neat lubricant and additives. Protic ionic liquid crystals (PILCs) are protic ionic liquids (PILs) where cations and anions form ordered mesophases that show liquid crystalline behavior. The adsorption of carboxylate units on sliding surfaces can enhance the lubricant performance. Ionic liquid crystal lubricants with longer alkyl chains can separate sliding surfaces more efficiently. However, they are usually solid at room temperature and, when used as additives in water, transitions to high friction coefficients and wear rates, with tribocorrosion processes occur when water evaporation takes place at the interface. In order to avoid these inconveniences, in the present work, a protic ammonium palmitate (DPA) ionic liquid crystal has been added in 1 wt.% proportion to a short chain citrate ionic liquid (DCi) with the same protic ammonium cation. A spin coated layer of (DCi + DPA) was deposited on AISI316L steel surface before the sliding test against sapphire ball. Synergy between DCi PIL and DPA PILC additive reduces friction coefficient and wear rate, without tribocorrosion processes, as shown by scanning electron microscopy (SEM)/energy dispersive X-ray microanalysis (EDX) and X-ray photoelectron spectroscopy (XPS) results.

Phase Behavior and Physical Properties of New Biobased Ionic Liquid Crystals

2017 ◽  
Vol 121 (14) ◽  
pp. 3177-3189 ◽  
Author(s):  
Ariel A. C. Toledo Hijo ◽  
Guilherme J. Maximo ◽  
Mariana C. Costa ◽  
Rosiane L. Cunha ◽  
Jorge F. B. Pereira ◽  
...  
Keyword(s):  
Ionic Liquid ◽  
Liquid Crystals ◽  
Physical Properties ◽  
Phase Behavior ◽  
Ionic Liquid Crystals

scholarly journals Lipidic Protic Ionic Liquid Crystals

2013 ◽  
Vol 2 (4) ◽  
pp. 672-682 ◽  
Author(s):  
Guilherme J. Maximo ◽  
Ricardo J. B. N. Santos ◽  
José A. Lopes-da-Silva ◽  
Mariana C. Costa ◽  
Antonio J. A. Meirelles ◽  
...  
Keyword(s):  
Ionic Liquid ◽  
Liquid Crystals ◽  
Protic Ionic Liquid ◽  
Ionic Liquid Crystals

scholarly journals Ion conformation and orientational order in a dicationic ionic liquid crystal studied by solid-state nuclear magnetic resonance spectroscopy

2021 ◽  
Vol 11 (1) ◽  
Author(s):  
Debashis Majhi ◽  
Sergey V. Dvinskikh
Keyword(s):  
Ionic Liquid ◽  
Ionic Liquids ◽  
Liquid Crystals ◽  
Bond Order ◽  
Van Der Waals ◽  
Orientational Order ◽  
Smectic Phase ◽  
Side Chains ◽  
Dicationic Ionic Liquid ◽  
Ionic Liquid Crystals

AbstractIonic liquids crystals belong to a special class of ionic liquids that exhibit thermotropic liquid-crystalline behavior. Recently, dicationic ionic liquid crystals have been reported with a cation containing two single-charged ions covalently linked by a spacer. In ionic liquid crystals, electrostatic and hydrogen bonding interactions in ionic sublayer and van der Waals interaction in hydrophobic domains are the main forces contributing to the mesophase stabilization and determining the molecular orientational order and conformation. How these properties in dicationic materials are compared to those in conventional monocationic analogs? We address this question using a combination of advanced NMR methods and DFT analysis. Dicationic salt 3,3′-(1,6-hexanediyl)bis(1-dodecylimidazolium)dibromide was studied. Local bond order parameters of flexible alkyl side chains, linker chain, and alignment of rigid polar groups were analyzed. The dynamic spacer effectively “decouples” the motion of two ionic moieties. Hence, local order and alignment in dicationic mesophase were similar to those in analogous single-chain monocationic salts. Bond order parameters in the side chains in the dicationic smectic phase were found consistently lower compared to double-chain monocationic analogs, suggesting decreasing contribution of van der Waals forces. Overall dication reorientation in the smectic phase was characterized by low values of orientational order parameter S. With increased interaction energy in the polar domain the layered structure is stabilized despite less ordered dications. The results emphasized the trends in the orientational order in ionic liquid crystals and contributed to a better understanding of interparticle interactions driving smectic assembly in this and analogous ionic mesogens.

Molecular dynamics and electrical conductivity of Guanidinium based ionic liquid crystals: Influence of cation headgroup configuration

2021 ◽  
Vol 330 ◽  
pp. 115666
Author(s):  
Mohamed A. Kolmangadi ◽  
Arda Yildirim ◽  
Kathrin Sentker ◽  
Martin Butschies ◽  
Andrea Bühlmeyer ◽  
...  
Keyword(s):  
Molecular Dynamics ◽  
Electrical Conductivity ◽  
Ionic Liquid ◽  
Liquid Crystals ◽  
Ionic Liquid Crystals

Liquid-crystalline behaviour and electrorheological effect of phthalocyanine-based ionic liquid crystals

2020 ◽  
pp. 1-10
Author(s):  
Aikebaier Reheman ◽  
Shuangying Hu ◽  
Lianjun Cao ◽  
Danhua Xie ◽  
Guiyang Yan ◽  
...  
Keyword(s):  
Ionic Liquid ◽  
Liquid Crystals ◽  
Liquid Crystalline ◽  
Electrorheological Effect ◽  
Ionic Liquid Crystals

Intramolecular Diels Alder reactions in highly organized imidazolium salt-based ionic liquid crystals

RSC Advances ◽  
2015 ◽  
Vol 5 (1) ◽  
pp. 635-639 ◽  
Author(s):  
Tien Dat Do ◽  
Andreea R. Schmitzer
Keyword(s):  
Ionic Liquid ◽  
Liquid Crystals ◽  
Diels Alder ◽  
Imidazolium Salts ◽  
Imidazolium Salt ◽  
New Family ◽  
Ionic Liquid Crystals

This paper describes the development of a new family of ionic liquid crystals based on imidazolium salts and their applications as media for intramolecular Diels Alder reactions.

A study of dendritic ionic liquid crystals: Using (S)-4-citronellyloxybenzoic acid and polypropylene imine dendrimers

2016 ◽  
Vol 216 ◽  
pp. 209-215 ◽  
Author(s):  
Harun Nezih Türkçü ◽  
Hale Ocak ◽  
Mustafa U. Gürbüz ◽  
Fatih Çakar ◽  
Belkiz Bilgin-Eran ◽  
...  
Keyword(s):  
Ionic Liquid ◽  
Liquid Crystals ◽  
Ionic Liquid Crystals
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