Mutual diffusion governed by kinetics and thermodynamics in the partially miscible mixture methanol + cyclohexane

2017 ◽  
Vol 19 (47) ◽  
pp. 31856-31873 ◽  
Author(s):  
Tatjana Janzen ◽  
Shi Zhang ◽  
Aliaksandr Mialdun ◽  
Gabriela Guevara-Carrion ◽  
Jadran Vrabec ◽  
...  
Keyword(s):  
Thermodynamic Properties ◽  
Diffusion Coefficients ◽  
Mutual Diffusion ◽  
Kinetics And Thermodynamics ◽  
Ideal Mixture ◽  
Partially Miscible

The interrelations between diffusion coefficients and thermodynamic properties in a strongly non-ideal mixture are studied by complementary approaches, considering the interactions between methanol cyclohexane.

Electrochemical and thermodynamic properties of U4+ and U3+ on Mo electrode in LiCl-KCl eutectic

2019 ◽  
Vol 107 (2) ◽  
pp. 95-104
Author(s):  
Ru-Shan Lin ◽  
You-Qun Wang ◽  
Zhao-Kai Meng ◽  
Hui Chen ◽  
Yan-Hong Jia ◽  
...  
Keyword(s):  
Free Energy ◽  
Thermodynamic Properties ◽  
Thermodynamic Functions ◽  
Electrochemical Behavior ◽  
Diffusion Coefficients ◽  
Electrochemical Techniques ◽  
Reduction Process ◽  
Standard Potential ◽  
Hcl Gas ◽  
Thermodynamic Functions Of Formation

Abstract In this study, UCl4 was prepared by the reaction of HCl gas with UO2 in the LiCl-KCl eutectic. Then, the electrochemical behavior of U4+ and U3+ on a Mo cathode was investigated by various electrochemical techniques. The reduction process of U4+ was regarded as two steps: U4++e=U3+; U3++3e=U. Diffusion coefficients of U4+ and U3+, the apparent standard potential of U4+/U3+, U3+/U as well as U4+/U in the LiCl-KCl molten salt on the Mo electrode was determined by numerous electrochemical methods. The thermodynamic functions of formation of Gibbs free energy of UCl4 and UCl3 are calculated as well.

Binary Mutual Diffusion Coefficients of Aqueous Solutions of α-Cyclodextrin, 2-Hydroxypropyl-α-cyclodextrin, and 2-Hydroxypropyl-β-cyclodextrin at Temperatures from (298.15 to 312.15) K

2007 ◽  
Vol 52 (2) ◽  
pp. 586-590 ◽  
Author(s):  
Ana C. F. Ribeiro ◽  
Artur J. M. Valente ◽  
Cecilia I. A. V. Santos ◽  
Pedro M. R. A. Prazeres ◽  
Victor M. M. Lobo ◽  
...  
Keyword(s):  
Aqueous Solutions ◽  
Diffusion Coefficients ◽  
Mutual Diffusion

Mutual Diffusion Coefficients of Water + Ethylene Glycol and Water + Glycerol Mixtures

1996 ◽  
Vol 41 (4) ◽  
pp. 876-879 ◽  
Author(s):  
G. Ternström ◽  
A. Sjöstrand ◽  
G. Aly ◽  
Å. Jernqvist
Keyword(s):  
Ethylene Glycol ◽  
Diffusion Coefficients ◽  
Mutual Diffusion ◽  
Water Glycerol
Sign in / Sign up

Export Citation Format

Share Document