Exploring viscosity, polarity and temperature sensitivity of BODIPY-based molecular rotors

2017 ◽  
Vol 19 (37) ◽  
pp. 25252-25259 ◽  
Author(s):  
Aurimas Vyšniauskas ◽  
Ismael López-Duarte ◽  
Nicolas Duchemin ◽  
Thanh-Truc Vu ◽  
Yilei Wu ◽  
...  
Keyword(s):  
Temperature Sensitivity ◽  
Solvent Polarity ◽  
Molecular Rotors

The sensitivity of structurally similar BODIPY-based molecular rotors to viscosity, temperature and solvent polarity was investigated.

The effect of solvent polarity and macromolecular crowding on the viscosity sensitivity of a molecular rotor BODIPY-C10

2020 ◽  
Vol 22 (16) ◽  
pp. 8296-8303
Author(s):  
Artūras Polita ◽  
Stepas Toliautas ◽  
Rokas Žvirblis ◽  
Aurimas Vyšniauskas
Keyword(s):  
Biological Systems ◽  
Macromolecular Crowding ◽  
Solvent Polarity ◽  
Fluorescent Sensors ◽  
Molecular Rotors ◽  
Live Cells ◽  
Molecular Rotor ◽  
Effect Of Solvent ◽  
Key Parameter

Viscosity is the key parameter of many biological systems such as live cells. It can be conveniently measured with ‘molecular rotors’ – fluorescent sensors of microviscosity. Here, we investigate one of the most applied molecular rotors BODIPY-C10.

Ultrafast dynamics and solvent-dependent deactivation kinetics of BODIPY molecular rotors

2017 ◽  
Vol 19 (30) ◽  
pp. 19998-20007 ◽  
Author(s):  
Tomislav Suhina ◽  
Saeed Amirjalayer ◽  
Sander Woutersen ◽  
Daniel Bonn ◽  
Albert M. Brouwer
Keyword(s):  
Excited State ◽  
Ground State ◽  
Solvent Polarity ◽  
Molecular Rotors ◽  
Conical Intersection ◽  
Ultrafast Dynamics ◽  
Molecular Rotor ◽  
Deactivation Kinetics ◽  
Viscous Solvents ◽  
Kinetics Of

The fluorescent excited state of a molecular rotor based on the meso-substituted boron-dipyrromethane (BODIPY) core decays rapidly to the ground state via a conical intersection. The fluorescence is strongly increased in viscous solvents, but solvent polarity has only a small effect.

Soil C mineralization and temperature sensitivity in alpine grasslands of the Qinghai-Xizang Plateau

2014 ◽  
Vol 37 (11) ◽  
pp. 988-997 ◽  
Author(s):  
Li XU ◽  
Shu-Xia YU ◽  
Nian-Peng HE ◽  
Xue-Fa WEN ◽  
Pei-Li SHI ◽  
...  
Keyword(s):  
Temperature Sensitivity ◽  
C Mineralization ◽  
Alpine Grasslands ◽  
Soil C ◽  
Xizang Plateau

Study of Photocatalytic Dergradation, Kinetics and Microbial Activities of Copper (ii) Soya Urea Complex in Non Aqueous Media

2020 ◽  
Vol 17 ◽  
Author(s):  
Vandana Sukhadia ◽  
Rashmi Sharma ◽  
Asha Meena
Keyword(s):  
Staphylococcus Aureus ◽  
Photocatalytic Degradation ◽  
Degradation Kinetics ◽  
Waste Water Treatment ◽  
Aqueous Media ◽  
Research Work ◽  
Solvent Polarity ◽  
Urea Complex ◽  
Pseudo First Order Reaction ◽  
Aqueous Solvent

Aims: The aim of this research work is to synthesise, study and analyse photocatalytic degradation, kinetics and microbial activity of new surfactant Copper (II) soya urea complex(CSU). Background: Photocatalytic degradation has attracted the attention of scientific community throughout the world due to its multiple applications in environment, energy, waste water treatment, pollution control, green chemistry, etc. Copper (II) soya urea complex has been synthesized and characterized through FT-IR, NMR, ESR studies. Objective: Present work deals with the study of photocatalytic degradation of Copper (II) soya urea complex by using ZnO as semiconductor. This study employs a semiconductor catalyst using non polar and non aqueous solvent in photocatalytic degradation. Reaction rate is chosen as the photocatalytic activity, which has been governed by several factors. Antibacterial activities of Copper (II) complex have also been studied against Staphylococcus aureus. Method: Optical density (O.D.) was measured after different time intervals spectrophotometrically to measure the degradation of complex. Mueller-Hinton agar medium was used for antimicrobial activity of synthesized compound at different concentrations by disk/ well diffusion susceptibility testing. Result: Plot of 2+log O.D. (absorbance) versus time was plotted and found linear. The heterogeneous photocatalysis followed pseudo-first-order reaction kinetics.The present study suggests that Copper (II) soya urea (CSU) complex shows antibacterial activity against Staphylococcus aureus at different concentrations. Conclusion: The results were used to determine the rate of photocatalytic degradation of CSU complex .It has been found that rate of degradation varies with different parameters like concentration of complex, amount of catalyst, light intensity, solvent polarity etc. CSU complex derived from soyabean oil has been shown an inhibitory effect on the growth of S. aureus which may causes skin disease.

Photocatalytic Degradation and Antibacterial Study of Copper(II) Mustard Thiourea Complex

2020 ◽  
Vol 10 (3) ◽  
pp. 229-242
Author(s):  
Vandana Sukhadia ◽  
Rashmi Sharma ◽  
Asha Meena
Keyword(s):  
Photocatalytic Degradation ◽  
Skin Diseases ◽  
Polar Solvent ◽  
Degradation Kinetics ◽  
Research Work ◽  
Solvent Polarity ◽  
Inhibitory Effect ◽  
Mustard Oil ◽  
Urea Complex ◽  
Pseudo First Order Reaction

Aims: The aim of this research work is to synthesise, study and analyse photocatalytic degradation, kinetics. Background: Copper(II) mustard thio urea complex has been synthesized and characterized through FT-IR, NMR, ESR studies. Objective: Photocatalytic degradation of copper(II) mustard thio urea complex was studied in the presence of ZnO as a catalyst in the solution form, using a non polar solvent benzene and a polar solvent methanol with different compositions. Antibacterial activities of copper(II) complex have also been studied against Staphylococcus aureus. Method: O.D. was measured after different time intervals spectrophotometrically to measure the degradation of the complex. Result: Plot of 2+ log O.D. (absorbance) versus time was plotted and found to be linear. The heterogeneous photocatalysis followed pseudo-first-order reaction kinetics. The present study suggests that the CMT complex shows antibacterial activity at different concentrations. Conclusion: The rate of photocatalytic degradation of CMT complex was studied and analyzed. It has been found that the rate of degradation varies with different parameters like the concentration of complex, the amount of catalyst, light intensity, solvent polarity etc. The CMT complex derived from natural mustard oil has shown an inhibitory effect on the growth of S. aureus which may cause skin diseases.

Influence of solvent polarity on the dual fluorescence of p-N,N-dimethylaminobenzonitrile: An AM1 theoretical study

1990 ◽  
Vol 55 (8) ◽  
pp. 1891-1895 ◽  
Author(s):  
Peter Ertl
Keyword(s):  
Excited State ◽  
Theoretical Study ◽  
Solvent Polarity ◽  
Semiempirical Method ◽  
Dual Fluorescence ◽  
Long Wavelength ◽  
Polar Media ◽  
Wavelength Emission ◽  
Ground State Geometry ◽  
Influence Of Solvent

Twisting of the NMe2 group in p-N,N-dimethylaminobenzonitrile (DMABN) was investigated using AM1 semiempirical method with configuration interaction. Effect of polar media was considered by placing + and - charge centers ("sparkles") at appropriate places opposite the molecule. Optimized ground state geometry of DMABN is slightly twisted with the lowest vertical excited state of 1B character. As the polarity of media increases and/or the - NMe2 group twists, the symmetric 1A excited state having considerable charge separation becomes energetically favorable. Anomalous long-wavelength emission of DMABN comes from this state.

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