Ionic liquids for metal extraction from chalcopyrite: solid, liquid and gas phase studies

2017 ◽  
Vol 19 (32) ◽  
pp. 21556-21564 ◽  
Author(s):  
O. Kuzmina ◽  
E. Symianakis ◽  
D. Godfrey ◽  
T. Albrecht ◽  
T. Welton

Non-oxidative leaching in ionic liquids revealed novel dependencies between the evolution of gas species, passivation layers and metal extraction efficiency.

2018 ◽  
Vol 2018 ◽  
pp. 1-5 ◽  
Author(s):  
Rui Lv ◽  
Shuya Cui ◽  
Yangmei Zou ◽  
Li Zheng

Two thermoregulated dicationic ionic liquids were synthesized and applied for effective extraction of the common dye malachite green oxalate (MG). The extraction parameters such as amount of ionic liquids, pH of water phase, extraction time, cooling time, and centrifugal time on the extraction efficiency were investigated systematically. It revealed that the dye has been successfully extracted into the ionic liquids, with high extraction efficiency higher than 98%, and recovery of 98.2%–100.8%, respectively. Furthermore, these ionic liquids can be recycled easily after elution. The reusable yields were 87.1% and 88.7%. The extraction of the dye into the thermoregulated ionic liquid provides a method of minimizing pollution of waste water potentially.


Author(s):  
Chi M. Phan ◽  
Son A. Hoang ◽  
Son H. Vu ◽  
Hoang M. Nguyen ◽  
Cuong V. Nguyen ◽  
...  

Abstract Background Cashew nut shell is a by-product of cashew (Anacardium occidentale) production, which is abundant in many developing countries. Cashew nut shell liquor (CNSL) contains a functional chemical, cardanol, which can be converted into a hydroxyoxime. The hydroxyoximes are expensive reagents for metal extraction. Methods CNSL-based oxime was synthesized and used to extract Ni, Co, and Mn from aqueous solutions. The extraction potential was compared against a commercial extractant (LIX 860N). Results All metals were successfully extracted with pH0.5 between 4 and 6. The loaded organic phase was subsequently stripped with an acidic solution. The extraction efficiency and pH0.5 of the CNSL-based extractant were similar to a commercial phenol-oxime extractant. The metals were stripped from the loaded organic phase with a recovery rate of 95% at a pH of 1. Conclusions Cashew-based cardanol can be used to economically produce an oxime in a simple process. The naturally-based oxime has the economic potential to sustainably recover valuable metals from spent lithium-ion batteries. Graphic abstract


2021 ◽  
Vol 164 ◽  
pp. 106825
Author(s):  
Xiaoyu Tang ◽  
Shihao He ◽  
Facheng Qiu ◽  
Xianfeng Qin ◽  
Xuejun Quan ◽  
...  

RSC Advances ◽  
2013 ◽  
Vol 3 (27) ◽  
pp. 10736 ◽  
Author(s):  
Michal Sypula ◽  
Ali Ouadi ◽  
Clotilde Gaillard ◽  
Isabelle Billard

2013 ◽  
Vol 2013 ◽  
pp. 1-7 ◽  
Author(s):  
Ying Li ◽  
Ning Tang ◽  
Fuyuhiko Inagaki ◽  
Chisato Mukai ◽  
Kazuichi Hayakawa

1,3-Dialkylimidazolium-based ionic liquids were chemically synthesized and bonded on the surface of magnetic nanoparticles (MNPs) with easy one-step reaction. The obtained six kinds of ionic liquid modified MNPs were characterized with transmission electron microscopy, thermogravimetric analysis, magnetization, and FTIR, which owned the high adsorption capacity due to the nanometer size and high-density modification with ionic liquids. Functionality of MNPs with ionic liquids greatly influenced the solubility of the MNPs with organic solvents depending on the alkyl chain length and the anions of the ionic liquids. Moreover, the obtained MNPs showed the specific extraction efficiency to organic pollutant, polycyclic aromatic hydrocarbons, while superparamagnetic property of the MNPs facilitated the convenient separation of MNPs from the bulks water samples.


2014 ◽  
Vol 31 (4) ◽  
pp. 042001 ◽  
Author(s):  
Natacha Altamirano ◽  
David Kubizňák ◽  
Robert B Mann ◽  
Zeinab Sherkatghanad

2009 ◽  
Vol 113 (11) ◽  
pp. 3491-3498 ◽  
Author(s):  
João P. Leal ◽  
Manuel E. Minas da Piedade ◽  
José N. Canongia Lopes ◽  
Alina A. Tomaszowska ◽  
José M. S. S. Esperança ◽  
...  

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