scholarly journals Kinetics of metal extraction in ionic liquids: Eu3+/HNO3//TODGA/[C1C4im][Tf2N] as a case study

RSC Advances ◽  
2013 ◽  
Vol 3 (27) ◽  
pp. 10736 ◽  
Author(s):  
Michal Sypula ◽  
Ali Ouadi ◽  
Clotilde Gaillard ◽  
Isabelle Billard
Keyword(s):  
Ionic Liquids ◽  
Metal Extraction ◽  
Kinetics Of

scholarly journals Thermal Stability and Decomposition Kinetics of 1-Alkyl-2,3-Dimethylimidazolium Nitrate Ionic Liquids: TGA and DFT Study

Materials ◽  
2021 ◽  
Vol 14 (10) ◽  
pp. 2560
Author(s):  
Jianwen Meng ◽  
Yong Pan ◽  
Fan Yang ◽  
Yanjun Wang ◽  
Zhongyu Zheng ◽  
...  
Keyword(s):  
Thermal Stability ◽  
Density Functional Theory ◽  
Ionic Liquids ◽  
Density Functional ◽  
Density Functional Theory Calculations ◽  
Nitrogen Atmosphere ◽  
Decomposition Kinetics ◽  
Heating Rates ◽  
Functional Theory ◽  
Kinetics Of

The thermal stability and decomposition kinetics analysis of 1-alkyl-2,3-dimethylimidazole nitrate ionic liquids with different alkyl chains (ethyl, butyl, hexyl, octyl and decyl) were investigated by using isothermal and nonisothermal thermogravimetric analysis combined with thermoanalytical kinetics calculations (Kissinger, Friedman and Flynn-Wall-Ozawa) and density functional theory (DFT) calculations. Isothermal experiments were performed in a nitrogen atmosphere at 240, 250, 260 and 270 °C. In addition, the nonisothermal experiments were carried out in nitrogen and air atmospheres from 30 to 600 °C with heating rates of 5, 10, 15, 20 and 25 °C/min. The results of two heating modes, three activation energy calculations and density functional theory calculations consistently showed that the thermal stability of 1-alkyl-2,3-dimethylimidazolium nitrate ionic liquids decreases with the increasing length of the alkyl chain of the substituent on the cation, and then the thermal hazard increases. This study could provide some guidance for the safety design and use of imidazolium nitrate ionic liquids for engineering.

Computational analysis of the effect of [Tea][Ms] and [Tea][H2PO4] ionic liquids on the structure and stability of Aβ(17–42) amyloid fibrils

2021 ◽  
Vol 23 (11) ◽  
pp. 6695-6709
Author(s):  
D. Gobbo ◽  
A. Cavalli ◽  
P. Ballone ◽  
A. Benedetto
Keyword(s):  
Ionic Liquid ◽  
Hydrogen Bonding ◽  
Ionic Liquids ◽  
Liquid Water ◽  
Computational Analysis ◽  
Amyloid Fibrils ◽  
Aβ Peptides ◽  
Structure And Stability ◽  
Water Solutions ◽  
Kinetics Of

Tight coordination of peptides by organic anions driven by hydrogen bonding affects the fibrillation kinetics of Aβ peptides in ionic liquid/water solutions.

Leaching kinetics of copper and valuable metal extraction from copper-cadmium residues of zinc hydrometallurgy by oxidation acid leaching

2021 ◽  
Vol 0 (0) ◽  
Author(s):  
Jihao Guo ◽  
Hongao Xu ◽  
Bo Li ◽  
Yonggang Wei ◽  
Hua Wang
Keyword(s):  
Hydrogen Peroxide ◽  
Acid Concentration ◽  
Acid Leaching ◽  
Metal Extraction ◽  
Agitation Rate ◽  
Leaching Kinetics ◽  
Solid Ratio ◽  
Zinc Hydrometallurgy ◽  
Kinetics Of ◽  
Leaching Efficiency

Abstract Multiple purification of zinc sulfate solution is an important process for zinc hydrometallurgy, and large quantities of copper-cadmium residues are generated as byproducts in this process. Copper-cadmium residues contain a large number of valuable metals that must be recovered. A comprehensive extraction process has been proposed using sulfuric acid as the leaching reagent and hydrogen peroxide as the oxidizing reagent. The effects of acid concentration, leaching temperature, leaching time, liquid-to-solid ratio, hydrogen peroxide dosage and stirring speed on the leaching efficiency were investigated. The optimum conditions were determined as an acid concentration of 150 g/L, liquid-to-solid ratio of 4:1, hydrogen peroxide amount of 20 mL, time of 60 min, temperature of 30 °C, particle size of −d75 μm, and agitation rate of 300 r/min. It was concluded that the leaching efficiency of copper and cadmium reached 97%, but because of the existence of zinc sulfide in the residues, a lower leaching efficiency of zinc was obtained. Furthermore, the leaching kinetics of copper was also studied based on the shrinking core model. The activation energy for copper leaching was 5.06 kJ/mol, and the leaching process was controlled by the diffusion through the product layer.

Simulation of Deformation Behavior and Microstructure Evolution during Hot Forging of TC11 Titanium Alloy

2018 ◽  
Vol 385 ◽  
pp. 449-454 ◽  
Author(s):  
Artem Alimov ◽  
Dmitry Zabelyan ◽  
Igor Burlakov ◽  
Igor Korotkov ◽  
Yuri Gladkov
Keyword(s):  
Titanium Alloy ◽  
Microstructure Evolution ◽  
Technology Development ◽  
Hot Forging ◽  
Industrial Case Study ◽  
Aerospace Applications ◽  
Heating And Cooling ◽  
Tc11 Titanium Alloy ◽  
Kinetics Of

Finite element method is the most powerful tool for development and optimization of the metal forming processes. Analysis of titanium alloy critical parts should include the prediction of microstructure since their mechanical and technological properties essentially depend on the type and parameters of the microstructure. The technological process of parts production for aerospace applications is multi-operational and consists of deformation, heating and cooling stages. Therefore, it is necessary to simulate the microstructure evolution to obtain high quality parts. In presented paper FE simulation coupled with microstructure evolution during hot forging of TC11 titanium alloy has been performed by QForm FEM code. Constitutive relationships, friction conditions and microstructure evolution model have been established using the experiments. The kinetics of phase transformations has been described by the Johnson-Mehl-Avrami-Kolmogorov (JMAK) phenomenological model. The approach is illustrated by industrial case study that proved its practical applicability and economic advantages for technology development of titanium alloy critical parts.

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