Hierarchically structured metal–organic frameworks assembled by hydroxy double salt–template synergy with high space–time yields

CrystEngComm ◽  
2018 ◽  
Vol 20 (8) ◽  
pp. 1057-1064 ◽  
Author(s):  
Chongxiong Duan ◽  
Feier Li ◽  
Libo Li ◽  
Hang Zhang ◽  
Xiujun Wang ◽  
...  

A simple, green, and versatile method to rapidly synthesize hierarchically structured metal–organic frameworks at room temperature using a cooperative template strategy.

CrystEngComm ◽  
2020 ◽  
Vol 22 (15) ◽  
pp. 2675-2680 ◽  
Author(s):  
Chongxiong Duan ◽  
Yi Yu ◽  
Feier Li ◽  
Ying Wu ◽  
Hongxia Xi

We developed a facile and general approach to rapidly synthesize four hierarchically porous MOFs (HKUST-1, ZIF-8, ZIF-61, and ZIF-90) under ambient conditions.


2015 ◽  
Vol 3 (41) ◽  
pp. 20819-20826 ◽  
Author(s):  
L. Garzón-Tovar ◽  
A. Carné-Sánchez ◽  
C. Carbonell ◽  
I. Imaz ◽  
D. Maspoch

The stepwise optimisation of the room temperature, water-based synthesis of several porous CPO-27/MOF-74 materials allows fabricating them with BET surfaces areas up to 1603 m2 g−1 and space-time-yields as high as 18 720 kg m−3 per day.


CrystEngComm ◽  
2019 ◽  
Vol 21 (1) ◽  
pp. 165-171 ◽  
Author(s):  
Yongwei Chen ◽  
Houxiao Wu ◽  
Qiangqiang Xiao ◽  
Daofei Lv ◽  
Feier Li ◽  
...  

Given the fact that solvothermal synthesis is the most common synthetic method to obtain metal–organic frameworks (MOFs) on a gram scale, it still remains a great challenge to produce MOFs in a scalable and sustainable synthetic process.


2019 ◽  
Vol 1 (3) ◽  
pp. 1062-1069 ◽  
Author(s):  
Chongxiong Duan ◽  
Hang Zhang ◽  
Minhui Yang ◽  
Feier Li ◽  
Yi Yu ◽  
...  

Hierarchically porous MOF materials were rapidly synthesized in a (Cu, Zn) hydroxy double salt (HDS) solution using a novel surfactant as template at room temperature and ambient pressure, and their growth mechanism was disclosed via mesodynamics (MesoDyn) simulation.


2018 ◽  
Vol 57 (28) ◽  
pp. 9136-9143 ◽  
Author(s):  
Feier Li ◽  
Chongxiong Duan ◽  
Hang Zhang ◽  
Xin Yan ◽  
Jinqing Li ◽  
...  

2017 ◽  
Vol 7 (12) ◽  
pp. 2445-2449 ◽  
Author(s):  
Amarajothi Dhakshinamoorthy ◽  
Andrea Santiago-Portillo ◽  
Patricia Concepción ◽  
José R. Herance ◽  
Sergio Navalón ◽  
...  

Commercial Al(OH)(BDC) (BDC: 1,4-benzenedicarboxylic acid) is a suitable heterogeneous catalyst for the silylation of benzylic and aliphatic alcohols by hexamethyldisilazane in toluene at room temperature.


2018 ◽  
Vol 117 ◽  
pp. 79-84 ◽  
Author(s):  
Hiep Q. Ha ◽  
Huong T.D. Nguyen ◽  
Trang H.M. Pham ◽  
Vu T. Pham ◽  
Thanh Truong

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