Intriguing structural chemistry of neutral and anionic layered monoalkylphosphates: single-source precursors for high-yield ceramic phosphates

CrystEngComm ◽  
2017 ◽  
Vol 19 (36) ◽  
pp. 5390-5401 ◽  
Author(s):  
Gulzar A. Bhat ◽  
Alok Ch. Kalita ◽  
Ramaswamy Murugavel
Keyword(s):  
Thermal Instability ◽  
Structural Chemistry ◽  
High Yield ◽  
Metal Phosphate ◽  
Single Source ◽  
Single Source Precursors ◽  
Phosphate Monoesters ◽  
Simple Protocol

A simple protocol for multi-gram synthesis of unstable and normally inaccessible phosphate monoesters ROPO3H2 is reported, apart from demonstration of their thermal instability and utility as starting materials for metal phosphate single source precursors.

scholarly journals A High-Yield Synthesis of Chalcopyrite CuInS2Nanoparticles with Exceptional Size Control

2009 ◽  
Vol 2009 ◽  
pp. 1-7 ◽  
Author(s):  
Chivin Sun ◽  
Joseph S. Gardner ◽  
Endrit Shurdha ◽  
Kelsey R. Margulieux ◽  
Richard D. Westover ◽  
...  
Keyword(s):  
Microwave Irradiation ◽  
Size Control ◽  
High Yield ◽  
Single Source ◽  
Icp Oes ◽  
Single Source Precursors ◽  
H Nmr ◽  
High Yields ◽  
Size Controlled

We report high-yield and efficient size-controlled syntheses of Chalcopyrite CuInS2nanoparticles by decomposing molecular single source precursors (SSPs) via microwave irradiation in the presence of 1,2-ethanedithiol at reaction temperatures as low as 100°C and times as short as 30 minutes. The nanoparticles sizes were 1.8 nm to 10.8 nm as reaction temperatures were varied from 100°C to 200°C with the bandgaps from 2.71 eV to 1.28 eV with good size control and high yields (64%–95%). The resulting nanoparticles were analyzed by XRD, UV-Vis, ICP-OES, XPS, SEM, EDS, and HRTEM. Titration studies by1H NMR using SSP1with 1,2-ethanedithiol and benzyl mercaptan were conducted to elucidate the formation of Chalcopyrite CuInS2nanoparticles.

Solution state fluxionality and thermolysis reactions of bimetallic single source precursors for I-III-VI chalcopyrite materials

2018 ◽  
Vol 480 ◽  
pp. 189-196 ◽  
Author(s):  
Anh H.T. Nguyen ◽  
Jacob L. Tennant ◽  
Leah J. Maxton ◽  
Andrew W. Holland
Keyword(s):  
Single Source ◽  
Single Source Precursors ◽  
Solution State

Fluorinated Heterometallic β-Diketonates as Volatile Single-Source Precursors for the Synthesis of Low-Valent Mixed-Metal Fluorides

2011 ◽  
Vol 133 (4) ◽  
pp. 692-694 ◽  
Author(s):  
Anantharamulu Navulla ◽  
Alexander A. Tsirlin ◽  
Artem M. Abakumov ◽  
Roman V. Shpanchenko ◽  
Haitao Zhang ◽  
...  
Keyword(s):  
Single Source ◽  
Single Source Precursors ◽  
Mixed Metal ◽  
Metal Fluorides ◽  
Low Valent
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