A redox-responsive selenium-containing pillar[5]arene-based macrocyclic amphiphile: synthesis, controllable self-assembly in water, and application in controlled release

2017 ◽  
Vol 53 (59) ◽  
pp. 8364-8367 ◽  
Author(s):  
Yujuan Zhou ◽  
Kecheng Jie ◽  
Feihe Huang

A selenium-containing pillar[5]arene-based macrocyclic amphiphile was prepared. This amphiphile self-assembled in water to form vesicles with redox responsiveness. Then, these pillar[5]arene-based vesicles were used in the controlled release of DOX.

2015 ◽  
Vol 6 (10) ◽  
pp. 1817-1829 ◽  
Author(s):  
Lichao Liu ◽  
Leilei Rui ◽  
Yun Gao ◽  
Weian Zhang

The synthesis and self-assembly of ferrocene-containing block copolymers PEG-b-PMAEFc, and the encapsulation and redox-responsive release of a model molecule (rhodamine B) upon external redox stimuli (H2O2).


2016 ◽  
Vol 7 (30) ◽  
pp. 4901-4911 ◽  
Author(s):  
Hua Yuan ◽  
Hai Chi ◽  
Weizhong Yuan

The micelles/aggregates that were self-assembled from a star-shaped copolymer presented redox-responsive behaviour and LCST–UCST thermoresponsive transition.


2020 ◽  
Vol 44 (25) ◽  
pp. 10229-10238 ◽  
Author(s):  
Chenming Ji ◽  
Yinlu Deng ◽  
Hua Yuan ◽  
Yongzhen Wu ◽  
Weizhong Yuan

The micelles self-assembled from P(NIPAM-co-AA-co-NIA) copolymers presented hypoxia and temperature dual-stimuli-responsive properties and a controlled release of drug was achieved using them.


MRS Advances ◽  
2020 ◽  
Vol 5 (64) ◽  
pp. 3507-3520
Author(s):  
Chunhui Dai ◽  
Kriti Agarwal ◽  
Jeong-Hyun Cho

AbstractNanoscale self-assembly, as a technique to transform two-dimensional (2D) planar patterns into three-dimensional (3D) nanoscale architectures, has achieved tremendous success in the past decade. However, an assembly process at nanoscale is easily affected by small unavoidable variations in sample conditions and reaction environment, resulting in a low yield. Recently, in-situ monitored self-assembly based on ion and electron irradiation has stood out as a promising candidate to overcome this limitation. The usage of ion and electron beam allows stress generation and real-time observation simultaneously, which significantly enhances the controllability of self-assembly. This enables the realization of various complex 3D nanostructures with a high yield. The additional dimension of the self-assembled 3D nanostructures opens the possibility to explore novel properties that cannot be demonstrated in 2D planar patterns. Here, we present a rapid review on the recent achievements and challenges in nanoscale self-assembly using electron and ion beam techniques, followed by a discussion of the novel optical properties achieved in the self-assembled 3D nanostructures.


2020 ◽  
Author(s):  
Daniel B. Straus ◽  
Robert J. Cava

The design of new chiral materials usually requires stereoselective organic synthesis to create molecules with chiral centers. Less commonly, achiral molecules can self-assemble into chiral materials, despite the absence of intrinsic molecular chirality. Here, we demonstrate the assembly of high-symmetry molecules into a chiral van der Waals structure by synthesizing crystals of C<sub>60</sub>(SnI<sub>4</sub>)<sub>2</sub> from icosahedral buckminsterfullerene (C<sub>60</sub>) and tetrahedral SnI4 molecules through spontaneous self-assembly. The SnI<sub>4</sub> tetrahedra template the Sn atoms into a chiral cubic three-connected net of the SrSi<sub>2</sub> type that is held together by van der Waals forces. Our results represent the remarkable emergence of a self-assembled chiral material from two of the most highly symmetric molecules, demonstrating that almost any molecular, nanocrystalline, or engineered precursor can be considered when designing chiral assemblies.


2021 ◽  
Vol 11 (7) ◽  
pp. 3254
Author(s):  
Marco Pisco ◽  
Francesco Galeotti

The realization of advanced optical fiber probes demands the integration of materials and structures on optical fibers with micro- and nanoscale definition. Although researchers often choose complex nanofabrication tools to implement their designs, the migration from proof-of-principle devices to mass production lab-on-fiber devices requires the development of sustainable and reliable technology for cost-effective production. To make it possible, continuous efforts are devoted to applying bottom-up nanofabrication based on self-assembly to decorate the optical fiber with highly ordered photonic structures. The main challenges still pertain to “order” attainment and the limited number of implementable geometries. In this review, we try to shed light on the importance of self-assembled ordered patterns for lab-on-fiber technology. After a brief presentation of the light manipulation possibilities concerned with ordered structures, and of the new prospects offered by aperiodically ordered structures, we briefly recall how the bottom-up approach can be applied to create ordered patterns on the optical fiber. Then, we present un-attempted methodologies, which can enlarge the set of achievable structures, and can potentially improve the yielding rate in finely ordered self-assembled optical fiber probes by eliminating undesired defects and increasing the order by post-processing treatments. Finally, we discuss the available tools to quantify the degree of order in the obtained photonic structures, by suggesting the use of key performance figures of merit in order to systematically evaluate to what extent the pattern is really “ordered”. We hope such a collection of articles and discussion herein could inspire new directions and hint at best practices to fully exploit the benefits inherent to self-organization phenomena leading to ordered systems.


2009 ◽  
Vol 143 ◽  
pp. 345 ◽  
Author(s):  
Aurelie M. Brizard ◽  
Marc C. A. Stuart ◽  
Jan H. van Esch

2021 ◽  
Vol 9 (9) ◽  
pp. 2179-2188
Author(s):  
Peng-Hao Hsu ◽  
Adah Almutairi

This perspective focuses on the development of redox-responsive polymeric nanomaterials for controlled payload release within the last four years.


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