Tunable differentiation of tertiary C–H bonds in intramolecular transition metal-catalyzed nitrene transfer reactions

2017 ◽  
Vol 53 (31) ◽  
pp. 4346-4349 ◽  
Author(s):  
Joshua R. Corbin ◽  
Jennifer M. Schomaker
Keyword(s):  
Transition Metal ◽  
Transfer Reactions ◽  
Direct Amination ◽  
Efficient Strategy ◽  
Nitrene Transfer ◽  
Transition Metal Catalyzed ◽  
Metal Catalyzed

Metal-catalyzed nitrene transfer reactions are an appealing and efficient strategy for accessing tetrasubstituted amines through the direct amination of tertiary C–H bonds.

scholarly journals Investigation of transition metal-catalyzed nitrene transfer reactions in water

2018 ◽  
Vol 26 (19) ◽  
pp. 5270-5273 ◽  
Author(s):  
Juliet M. Alderson ◽  
Joshua R. Corbin ◽  
Jennifer M. Schomaker
Keyword(s):  
Transition Metal ◽  
Transfer Reactions ◽  
Nitrene Transfer ◽  
Transition Metal Catalyzed ◽  
Metal Catalyzed

Transition metal-catalyzed iodine(iii)-mediated nitrene transfer reactions: efficient tools for challenging syntheses

2017 ◽  
Vol 53 (3) ◽  
pp. 493-508 ◽  
Author(s):  
B. Darses ◽  
R. Rodrigues ◽  
L. Neuville ◽  
M. Mazurais ◽  
P. Dauban
Keyword(s):  
Transition Metal ◽  
Natural Product ◽  
Natural Product Synthesis ◽  
Synthetic Methods ◽  
Transfer Reactions ◽  
Nitrene Transfer ◽  
Transition Metal Catalyzed ◽  
Metal Catalyzed

The main synthetic applications of catalytic C(sp3)–H amination and alkene aziridination reactions are discussed in the context of natural product synthesis. The examples highlight that these synthetic methods now firmly belong in the organic chemist's toolbox.

scholarly journals Enantioselective synthesis of gem-diarylalkanes by transition metal-catalyzed asymmetric arylations (TMCAAr)

2018 ◽  
Vol 9 (3) ◽  
pp. 546-559 ◽  
Author(s):  
Tao Jia ◽  
Peng Cao ◽  
Jian Liao
Keyword(s):  
Transition Metal ◽  
Enantioselective Synthesis ◽  
Transfer Reactions ◽  
Stereogenic Centers ◽  
Transition Metal Catalyzed ◽  
Metal Catalyzed ◽  
Quaternary Stereogenic Centers ◽  
Aryl Transfer

To date, enantiomerically enriched molecules containing gem(1,1)-diaryl containing tertiary or quaternary stereogenic centers have been readily accessed by transition metal-catalyzed enantioselective or stereoconvergent aryl transfer reactions.

Mechanistic aspects of transition metal-catalyzed hydrogen transfer reactions

2006 ◽  
Vol 35 (3) ◽  
pp. 237 ◽  
Author(s):  
Joseph S. M. Samec ◽  
Jan-E. Bäckvall ◽  
Pher G. Andersson ◽  
Peter Brandt
Keyword(s):  
Transition Metal ◽  
Hydrogen Transfer ◽  
Transfer Reactions ◽  
Transition Metal Catalyzed ◽  
Metal Catalyzed ◽  
Hydrogen Transfer Reactions
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