Transition-Metal-Catalyzed Group Transfer Reactions for Selective C−H Bond Functionalization of Artemisinin

2007 ◽  
Vol 9 (21) ◽  
pp. 4107-4110 ◽  
Author(s):  
Yungen Liu ◽  
Wenbo Xiao ◽  
Man-Kin Wong ◽  
Chi-Ming Che
Keyword(s):  
Transition Metal ◽  
Transfer Reactions ◽  
Bond Functionalization ◽  
Group Transfer ◽  
Transition Metal Catalyzed ◽  
Metal Catalyzed

scholarly journals Advances in the Synthesis of Fluorinated Scaffolds by Transition Metal-Catalyzed C–H Bond Activation

2020 ◽  
Vol 74 (11) ◽  
pp. 871-877
Author(s):  
Sara Mazeh ◽  
Maria Ivana Lapuh ◽  
Tatiana Besset
Keyword(s):  
Transition Metal ◽  
Fluorine Atom ◽  
Bond Activation ◽  
Value Added ◽  
Bond Functionalization ◽  
Present Account ◽  
Transition Metal Catalyzed ◽  
Metal Catalyzed

Thanks to the unique features of the fluorine atom and the fluorinated groups, fluorine-containing molecules are essential. Therefore, the search for new fluorinated groups as well as straightforward and original methodologies for their installation is of prime importance. Especially, the combination of organofluorine chemistry with transition metal-catalyzed C–H bond functionalization reactions offered straightforward tools to access original fluorinated scaffolds. In this context, over the last years, our group focused on the development of original methodologies to synthesize fluorine-containing molecules with a special attention to emergent fluorinated groups. The present account highlights our recent contributions to the synthesis of highly value-added fluorine-containing compounds by transition metal-catalyzed C–H bond activation.

scholarly journals Enantioselective synthesis of gem-diarylalkanes by transition metal-catalyzed asymmetric arylations (TMCAAr)

2018 ◽  
Vol 9 (3) ◽  
pp. 546-559 ◽  
Author(s):  
Tao Jia ◽  
Peng Cao ◽  
Jian Liao
Keyword(s):  
Transition Metal ◽  
Enantioselective Synthesis ◽  
Transfer Reactions ◽  
Stereogenic Centers ◽  
Transition Metal Catalyzed ◽  
Metal Catalyzed ◽  
Quaternary Stereogenic Centers ◽  
Aryl Transfer

To date, enantiomerically enriched molecules containing gem(1,1)-diaryl containing tertiary or quaternary stereogenic centers have been readily accessed by transition metal-catalyzed enantioselective or stereoconvergent aryl transfer reactions.

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