Self-assembly of stable luminescent lanthanide supramolecular M4L6 cages with sensing properties toward nitroaromatics

2017 ◽  
Vol 53 (16) ◽  
pp. 2459-2462 ◽  
Author(s):  
Cui-Lian Liu ◽  
Li-Peng Zhou ◽  
Debakanta Tripathy ◽  
Qing-Fu Sun

We report here the first example of concentration-triggered helicate-to-tetrahedron transformation in supramolecular lanthanide edifices, along with their highly efficient and selective luminescence sensing properties toward PA at the ppb level.

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