Judicious engineering of a metal-free perylene dye for high-efficiency dye sensitized solar cells: the control of excited state and charge carrier dynamics

2017 ◽  
Vol 5 (7) ◽  
pp. 3514-3522 ◽  
Author(s):  
Lin Yang ◽  
Shu Chen ◽  
Jing Zhang ◽  
Junting Wang ◽  
Min Zhang ◽  
...  

A donor–acceptor perylene dye constructed with a bulky perylene based electron donor has achieved a high power conversion efficiency of 11.5% under the air mass 1.5 global conditions.

2017 ◽  
Vol 19 (3) ◽  
pp. 2549-2556 ◽  
Author(s):  
Yang Li ◽  
Junting Wang ◽  
Yi Yuan ◽  
Min Zhang ◽  
Xiandui Dong ◽  
...  

Two perylene dyes characteristic of electron-donors phenanthrocarbazole (PC) and carbazyl functionalized PC are selected to study the complicated dynamics of excited states and charge carriers, which underlie the photovoltaic parameters of dye-sensitized solar cells (DSCs).


RSC Advances ◽  
2018 ◽  
Vol 8 (35) ◽  
pp. 19465-19469
Author(s):  
Hashem Shahroosvand ◽  
Saeid Abaspour ◽  
Babak Pashaei ◽  
Babak Nemati Bideh

With respect to N3, S3 which contained a phenTz (1,10-phenanthroline 5-tetrazole) ancillary ligand showed outstanding improvements in molar extinction coefficient (ε) as well as increases in power conversion efficiency (PCE) and incident photon-to-electron conversion efficiency (IPCE).


Energies ◽  
2021 ◽  
Vol 15 (1) ◽  
pp. 219
Author(s):  
Ji-Hye Kim ◽  
Dong-Hyuk Kim ◽  
Ju-Hee So ◽  
Hyung-Jun Koo

Due to their low cost, facile fabrication, and high-power conversion efficiency (PCE), dye-sensitized solar cells (DSSCs) have attracted much attention. Ruthenium (Ru) complex dyes and organic solvent-based electrolytes are typically used in high-efficiency DSSCs. However, Ru dyes are expensive and require a complex synthesis process. Organic solvents are toxic, environmentally hazardous, and explosive, and can cause leakage problems due to their low surface tension. This review summarizes and discusses previous works to replace them with natural dyes and water-based electrolytes to fabricate low-cost, safe, biocompatible, and environmentally friendly DSSCs. Although the performance of “eco-friendly DSSCs” remains less than 1%, continuous efforts to improve the PCE can accelerate the development of more practical devices, such as designing novel redox couples and photosensitizers, interfacial engineering of photoanodes and electrolytes, and biomimetic approaches inspired by natural systems.


2019 ◽  
Vol 18 (6) ◽  
pp. 1389-1397 ◽  
Author(s):  
Won-Chun Oh ◽  
Kwang Youn Cho ◽  
Chong Hun Jung ◽  
Yonrapach Areerob

Currently, the development of sensitized solar cells (DSSCs) with high power conversion efficiency and low cost is a major challenge in the academic and industrial fields.


Author(s):  
Canpu Yang ◽  
Peng Song ◽  
Reda El-Shishtawy ◽  
Fengcai Ma ◽  
Yuanzuo Li

To explore high efficiency dye-sensitized solar cells (DSSCs), two experimentally derived (single fence and double fence porphyrins) and two theoretically designed zinc porphyrin molecules with D-D-π-A-A configurations were studied. Density...


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