scholarly journals Six new coordination compounds based on rigid 5-(3-carboxy-phenyl)-pyridine-2-carboxylic acid: synthesis, structural variations and properties

RSC Advances ◽  
2017 ◽  
Vol 7 (12) ◽  
pp. 7217-7226 ◽  
Author(s):  
Jiang-Feng Song ◽  
Ying-Ying Jia ◽  
Rui-Sha Zhou ◽  
Si-Zhe Li ◽  
Xiao-Min Qiu ◽  
...  
Keyword(s):  
Carboxylic Acid ◽  
Coordination Compounds ◽  
Three Dimensional ◽  
Acid Synthesis ◽  
Structural Chemistry ◽  
Two Dimensional ◽  
Structural Variations ◽  
One Dimensional

Compounds 1–6 have rich structural chemistry ranging from mononuclear (1 and 2), one-dimensional (3 and 4), two-dimensional (5) to three-dimensional (6) structures.

Salts of 3,5-dinitrobenzoic acid with organic diamines: hydrogen-bonded supramolecular structures in one, two and three dimensions

2001 ◽  
Vol 57 (2) ◽  
pp. 201-212 ◽  
Author(s):  
Colin J. Burchell ◽  
Christopher Glidewell ◽  
Alan J. Lough ◽  
George Ferguson
Keyword(s):  
Carboxylic Acid ◽  
Hydrogen Bonds ◽  
Secondary Amine ◽  
Tertiary Amine ◽  
Primary Amine ◽  
Three Dimensional ◽  
Supramolecular Structures ◽  
Three Dimensions ◽  
Two Dimensional ◽  
One Dimensional

The trigonally trisubstituted carboxylic acid 3,5-dinitrobenzoic acid, (O2N)2C6H3COOH, forms 2:1 salts with a range of organic diamines L, with the general composition [LH2]2+·[{(O2N)2C6H3COO}−]2. When L is a bis-tertiary amine the hard N—H...O hydrogen bonds generate finite three-component aggregates, anion...cation...anion, and these aggregates are further linked by soft C—H...O hydrogen bonds to form one-dimensional molecular ladders when L is N,N,N′,N′′-tetramethyl-1,2-diaminoethane and chains of rings when L is 4,4′-dipyridylethane or 4,4′-dipyridylethene; two-dimensional sheets are formed when L is 1,4-diazabicyclo[2.2.2]octane and a three-dimensional framework is formed when L is N,N′-dimethylpiperazine. When L is the bis-secondary amine piperazine, the hard N—H...O and soft C—H...O hydrogen bonds each generate continuous motifs in the form of distinct chains of rings, the combination of which generates sheets, while when L is the bis-primary amine 1,2-diaminoethane the hard N—H...O hydrogen bonds alone generate a three-dimensional framework.

Transformations of two-dimensional layered zinc phosphates to three-dimensional and one-dimensional structures

2002 ◽  
Vol 12 (4) ◽  
pp. 1044-1052 ◽  
Author(s):  
Amitava Choudhury ◽  
S. Neeraj ◽  
Srinivasan Natarajan ◽  
C. N. R. Rao
Keyword(s):  
Three Dimensional ◽  
Two Dimensional ◽  
One Dimensional ◽  
Zinc Phosphates

Mine Impact Burial Prediction From One to Three Dimensions

2008 ◽  
Vol 62 (1) ◽  
Author(s):  
Peter C. Chu
Keyword(s):  
Three Dimensional ◽  
Time History ◽  
Three Dimensions ◽  
Vertical Position ◽  
Burial Depth ◽  
Prediction Errors ◽  
Two Dimensional ◽  
Dimensional Model ◽  
One Dimensional ◽  
Dimensional Models

The Navy’s mine impact burial prediction model creates a time history of a cylindrical or a noncylindrical mine as it falls through air, water, and sediment. The output of the model is the predicted mine trajectory in air and water columns, burial depth/orientation in sediment, as well as height, area, and volume protruding. Model inputs consist of parameters of environment, mine characteristics, and initial release. This paper reviews near three decades’ effort on model development from one to three dimensions: (1) one-dimensional models predict the vertical position of the mine’s center of mass (COM) with the assumption of constant falling angle, (2) two-dimensional models predict the COM position in the (x,z) plane and the rotation around the y-axis, and (3) three-dimensional models predict the COM position in the (x,y,z) space and the rotation around the x-, y-, and z-axes. These models are verified using the data collected from mine impact burial experiments. The one-dimensional model only solves one momentum equation (in the z-direction). It cannot predict the mine trajectory and burial depth well. The two-dimensional model restricts the mine motion in the (x,z) plane (which requires motionless for the environmental fluids) and uses incorrect drag coefficients and inaccurate sediment dynamics. The prediction errors are large in the mine trajectory and burial depth prediction (six to ten times larger than the observed depth in sand bottom of the Monterey Bay). The three-dimensional model predicts the trajectory and burial depth relatively well for cylindrical, near-cylindrical mines, and operational mines such as Manta and Rockan mines.

Theory of ultrasonic attenuation in one and two dimensional metals

1976 ◽  
Vol 54 (14) ◽  
pp. 1454-1460 ◽  
Author(s):  
T. Tiedje ◽  
R. R. Haering
Keyword(s):  
Ultrasonic Attenuation ◽  
Three Dimensional ◽  
Electronic Systems ◽  
Two Dimensional ◽  
Temperature Dependent ◽  
One Dimensional ◽  
The Difference

The theory of ultrasonic attenuation in metals is extended so that it applies to quasi one and two dimensional electronic systems. It is shown that the attenuation in such systems differs significantly from the well-known results for three dimensional systems. The difference is particularly marked for one dimensional systems, for which the attenuation is shown to be strongly temperature dependent.

scholarly journals Quasi-two-dimensional approximation for numerical simulation of flows in engine ducts

2019 ◽  
Author(s):  
V. Vlasenko ◽  
A. Shiryaeva
Keyword(s):  
High Speed ◽  
Fuel Injection ◽  
Three Dimensional ◽  
Preliminary Design ◽  
Two Dimensional ◽  
Combustion Chambers ◽  
New Approach ◽  
One Dimensional ◽  
Dimensional Approximation ◽  
3D Flows

New quasi-two-dimensional (2.5D) approach to description of three-dimensional (3D) flows in ducts is proposed. It generalizes quasi-one-dimensional (quasi-1D, 1.5D) theories. Calculations are performed in the (x; y) plane, but variable width of duct in the z direction is taken into account. Derivation of 2.5D approximation equations is given. Tests for verification of 2.5D calculations are proposed. Parametrical 2.5D calculations of flow with hydrogen combustion in an elliptical combustor of a high-speed aircraft, investigated within HEXAFLY-INT international project, are described. Optimal scheme of fuel injection is found and explained. For one regime, 2.5D and 3D calculations are compared. The new approach is recommended for use during preliminary design of combustion chambers.

Modeling of a Beam and a Rotor with an Edge Crack Using Dissimilar Elements

2003 ◽  
Vol 9 (10) ◽  
pp. 1159-1187 ◽  
Author(s):  
A. Nandi ◽  
S. Neogy
Keyword(s):  
Finite Elements ◽  
Stress Field ◽  
Edge Crack ◽  
Three Dimensional ◽  
Transition Element ◽  
Two Dimensional ◽  
Cracked Beam ◽  
One Dimensional ◽  
Beam Elements ◽  
Dimensional Plane

Vibration-based diagnostic methods are used for the detection of the presence of cracks in beams and other structures. To simulate such a beam with an edge crack, it is necessary to model the beam using finite elements. Cracked beam finite elements, being one-dimensional, cannot model the stress field near the crack tip, which is not one-dimensional. The change in neutral axis is also not modeled properly by cracked beam elements. Modeling of such beams using two-dimensional plane elements is a better approximation. The best alternative would be to use three-dimensional solid finite elements. At a sufficient distance away from the crack, the stress field again becomes more or less one-dimensional. Therefore, two-dimensional plane elements or three-dimensional solid elements can be used near the crack and one-dimensional beam elements can be used away from the crack. This considerably reduces the required computational effort. In the present work, such a coupling of dissimilar elements is proposed and the required transition element is formulated. A guideline is proposed for selecting the proper dimensions of the transition element so that accurate results are obtained. Elastic deformation, natural frequency and dynamic response of beams are computed using dissimilar elements. The finite element analysis of cracked rotating shafts is complicated because of the fact that elastic deformations are superposed on the rigid-body motion (rotation about an axis). A combination of three-dimensional solid elements and beam elements in a rotating reference is proposed here to model such rotors.

Preliminary Ship Design Using One and Two-Dimensional Models

1999 ◽  
Vol 36 (02) ◽  
pp. 102-112
Author(s):  
Michael D. A. Mackney ◽  
Carl T. F. Ross
Keyword(s):  
Finite Element ◽  
Dimensional Analysis ◽  
Three Dimensional ◽  
Two Dimensional ◽  
One Dimensional ◽  
Dimensional Finite Element ◽  
Dimensional Models ◽  
Support Conditions ◽  
The One ◽  
Three Dimensional Finite Element

Computational studies of hull-superstructure interaction were carried out using one-, two-and three-dimensional finite element analyses. Simplification of the original three-dimensional cases to one- and two-dimensional ones was undertaken to reduce the data preparation and computer solution times in an extensive parametric study. Both the one- and two-dimensional models were evaluated from numerical and experimental studies of the three-dimensional arrangements of hull and superstructure. One-dimensional analysis used a simple beam finite element with appropriately changed sections properties at stations where superstructures existed. Two-dimensional analysis used a four node, first order quadrilateral, isoparametric plane elasticity finite element, with a corresponding increase in the grid domain where the superstructure existed. Changes in the thickness property reflected deck stiffness. This model was essentially a multi-flanged beam with the shear webs representing the hull and superstructure sides, and the flanges representing the decks One-dimensional models consistently and uniformly underestimated the three-dimensional behaviour, but were fast to create and run. Two-dimensional models were also consistent in their assessment, and considerably closer in predicting the actual behaviours. These models took longer to create than the one-dimensional, but ran in very much less time than the refined three-dimensional finite element models Parametric insights were accomplished quickly and effectively with the simplest model and processor, but two-dimensional analyses achieved closer absolute measure of the displacement behaviours. Although only static analysis with simple loading and support conditions were presented, it is believed that similar benefits would be found for other loadings and support conditions. Other engineering components and structures may benefit from similarly judged simplification using one- and two-dimensional models to reduce the time and cost of preliminary design.

scholarly journals Different Benzendicarboxylate-Directed Structural Variations and Properties of Four New Porous Cd(II)-Pyridyl-Triazole Coordination Polymers

2020 ◽  
Vol 8 ◽  
Author(s):  
Ying Zhao ◽  
Jin Jing ◽  
Ning Yan ◽  
Min-Le Han ◽  
Guo-Ping Yang ◽  
...  
Keyword(s):  
Solid State ◽  
Coordination Polymers ◽  
Three Dimensional ◽  
Two Dimensional ◽  
Gas Sorption ◽  
Structural Variations ◽  
Benzenedicarboxylic Acid ◽  
Topological Framework ◽  
The Stability

Four new different porous crystalline Cd(II)-based coordination polymers (CPs), i. e., [Cd(mdpt)2]·2H2O (1), [Cd2(mdpt)2(m-bdc)(H2O)2] (2), [Cd(Hmdpt)(p-bdc)]·2H2O (3), and [Cd3(mdpt)2(bpdc)2]·2.5NMP (4), were obtained successfully by the assembly of Cd(II) ions and bitopic 3-(3-methyl-2-pyridyl)-5-(4-pyridyl)-1,2,4-triazole (Hmdpt) in the presence of various benzendicarboxylate ligands, i.e., 1,3/1,4-benzenedicarboxylic acid (m-H2bdc, p-H2bdc) and biphenyl-4,4′-bicarboxylate (H2bpdc). Herein, complex 1 is a porous 2-fold interpenetrated four-connected 3D NbO topological framework based on the mdpt− ligand; 2 reveals a two-dimensional (2D) hcb network. Interestingly, 3 presents a three-dimensional (3D) rare interpenetrated double-insertion supramolecular net via 2D ···ABAB··· layers and can be viewed as an fsh topological net, while complex 4 displays a 3D sqc117 framework. Then, the different gas sorption performances were carried out carefully for complexes 1 and 4, the results of which showed 4 has preferable sorption than that of 1 and can be the potential CO2 storage and separation material. Furthermore, the stability and luminescence of four complexes were performed carefully in the solid state.

Sign in / Sign up

Export Citation Format

Share Document