meso-Tetrakis[4-(methoxycarbonyl)phenyl]porphyrinatopalladium(ii) supported on graphene oxide nanosheets (Pd(ii)-TMCPP-GO): synthesis and catalytic activity

RSC Advances ◽  
2016 ◽  
Vol 6 (110) ◽  
pp. 108755-108767 ◽  
Author(s):  
Reza Fareghi-Alamdari ◽  
Mohsen Golestanzadeh ◽  
Omid Bagheri
Keyword(s):  
Graphene Oxide ◽  
Catalytic Activity ◽  
Palladium Complex ◽  
Suzuki Reaction ◽  
Graphene Oxide Nanosheets

In this study, meso-tetrakis[4-(methoxycarbonyl)phenyl]porphynatopalladium(ii) as a macrocyclic palladium complex was covalently grafted to the surface of graphene oxide (Pd-TMCPP-GO). The prepared catalyst was checked in Suzuki reaction.

N-Heterocyclic carbene palladium complex supported on ionic liquid-modified graphene oxide as an efficient and recyclable catalyst for Suzuki reaction

RSC Advances ◽  
2014 ◽  
Vol 4 (28) ◽  
pp. 14586-14591 ◽  
Author(s):  
Siyavash Kazemi Movahed ◽  
Rahele Esmatpoursalmani ◽  
Ayoob Bazgir
Keyword(s):  
Ionic Liquid ◽  
Graphene Oxide ◽  
Catalytic Activity ◽  
Palladium Complex ◽  
Suzuki Reaction ◽  
Recyclable Catalyst ◽  
High Catalytic Activity ◽  
Modified Graphene Oxide ◽  
Modified Graphene ◽  
Silylation Reaction

An N-heterocyclic carbene Pd complex immobilized on GO with an ionic liquid framework synthesized by the modification of GO through a silylation reaction displayed a high catalytic activity in the Suzuki reaction.

scholarly journals Magnetization of graphene oxide nanosheets using nickel magnetic nanoparticles as a novel support for the fabrication of copper as a practical, selective, and reusable nanocatalyst in C–C and C–O coupling reactions

RSC Advances ◽  
2021 ◽  
Vol 11 (42) ◽  
pp. 25867-25879
Author(s):  
Parisa Moradi ◽  
Maryam Hajjami
Keyword(s):  
Graphene Oxide ◽  
Catalytic Activity ◽  
Magnetic Nanoparticles ◽  
Coupling Reactions ◽  
Graphene Oxide Nanosheets ◽  
Magnetic Graphene Oxide ◽  
Diaryl Ethers ◽  
Magnetic Graphene

Catalytic activity of supported copper on magnetic graphene oxide was investigated as a selective and reusable nanocatalyst in the synthesis of diaryl ethers and biphenyls.

Enhanced electrocatalytic activity of cobalt phthalocyanines when “clicked” to graphene oxide nanosheets

2019 ◽  
Vol 23 (07n08) ◽  
pp. 828-840 ◽  
Author(s):  
Lekhetho S. Mpeta ◽  
Tebello Nyokong
Keyword(s):  
Graphene Oxide ◽  
Catalytic Activity ◽  
Benzene Ring ◽  
Electrocatalytic Activity ◽  
Electrochemical Sensors ◽  
Limit Of Detection ◽  
Oxidation Potential ◽  
Graphene Oxide Nanosheets ◽  
Ring Complex ◽  
Good Catalytic Activity

Alkyne-terminated Co phthalocyanine (CoPc) derivatives are linked to reduced graphene oxide nanosheets (GONS) via click chemistry and the conjugates are used for the electrocatalytic oxidation of 2-mercaptoethanol. CoPc derivatives where the alkyne group is separated from the Pc ring by an aliphatic and benzene ring (complex 3) showed the best catalytic activity (in terms of oxidation potential) in comparison to when only aliphatic chains were employed without the benzene ring (complex 2) and when there were no substituents (complex 1). The anodic oxidation of 2-mercaptoethanol on 3-GONS (linked) occurred at the least positive oxidation potential (-0.22 V vs. Ag|AgCl). 3-GONS (linked) was found to have the highest sensitivity with the lowest limit of detection of 0.08 [Formula: see text]M. When the CoPc derivative and GONS were not linked but placed sequentially on the electrode, the electrocatalytic activity (in terms of LOD) was poorer than when linked. The electrodes modified with CoPc clicked to GONS are highly promising electrochemical sensors in terms of stability, sensitivity, good catalytic activity and ease of fabrication.

Preparation of PdxAuy bimetallic nanostructures with controllable morphologies supported on reduced graphene oxide nanosheets and wrapped in a polypyrrole layer

RSC Advances ◽  
2015 ◽  
Vol 5 (107) ◽  
pp. 87831-87837 ◽  
Author(s):  
Tongjie Yao ◽  
Quan Zuo ◽  
Hao Wang ◽  
Jie Wu ◽  
Xiao Zhang ◽  
...  
Keyword(s):  
Graphene Oxide ◽  
Catalytic Activity ◽  
Reduced Graphene Oxide ◽  
Graphene Oxide Nanosheets ◽  
Step Method ◽  
Reduced Graphene ◽  
One Step ◽  
Good Catalytic Activity ◽  
Alloy Nanostructures ◽  
Bimetallic Nanostructures

A one-step method to prepare reduced graphene oxide/PdxAuy/polypyrrole composites with good catalytic activity was introduced. The morphologies of alloy nanostructures could turn to be spherical, coral-like and porous cluster-like.

Ultrasmall Ru2P nanoparticles on graphene: a highly efficient hydrogen evolution reaction electrocatalyst in both acidic and alkaline media

2018 ◽  
Vol 54 (27) ◽  
pp. 3343-3346 ◽  
Author(s):  
Tingting Liu ◽  
Shuo Wang ◽  
Qiuju Zhang ◽  
Liang Chen ◽  
Weihua Hu ◽  
...  
Keyword(s):  
Graphene Oxide ◽  
Catalytic Activity ◽  
Reduced Graphene Oxide ◽  
Hydrogen Evolution ◽  
Hydrogen Evolution Reaction ◽  
Alkaline Media ◽  
Graphene Oxide Nanosheets ◽  
Reduced Graphene ◽  
Alkaline Conditions ◽  
Acidic And Alkaline Media

A Pt-free catalyst of ultrasmall Ru2P nanoparticles on reduced graphene oxide nanosheets (Ru2P/RGO-20) shows remarkable HER catalytic activity under acidic and alkaline conditions, respectively, both superior to those of commercial Pt/C.

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