scholarly journals Design and Exploration of Catalytic Activity of Two-Dimensional Surface-Engineered Graphene Oxide Nanosheets in the Transannulation of N-Heterocyclic Aldehydes or Ketones with Alkylamines

ACS Omega ◽  
2019 ◽  
Vol 4 (2) ◽  
pp. 3146-3158
Author(s):  
Rakesh K. Sharma ◽  
Aditi Sharma ◽  
Shivani Sharma ◽  
Sriparna Dutta ◽  
Sneha Yadav ◽  
...  
2021 ◽  
Vol 164 ◽  
pp. 105979
Author(s):  
Xin Gao ◽  
Hengwei Zhang ◽  
Erjun Guo ◽  
Fei Yao ◽  
Zengze Wang ◽  
...  

Author(s):  
Minju Park ◽  
Namhee Kim ◽  
Jiyoung Lee ◽  
Minsu Gu ◽  
Byeong-Su Kim

Even though many graphene derivatives that are atomically thin two-dimensional structures, such as graphene oxide (GO), have triggered enormous interest in the scientific and industrial communities owing to their easy...


RSC Advances ◽  
2021 ◽  
Vol 11 (42) ◽  
pp. 25867-25879
Author(s):  
Parisa Moradi ◽  
Maryam Hajjami

Catalytic activity of supported copper on magnetic graphene oxide was investigated as a selective and reusable nanocatalyst in the synthesis of diaryl ethers and biphenyls.


2019 ◽  
Vol 11 (26) ◽  
pp. 23558-23572 ◽  
Author(s):  
Xifeng Liu ◽  
A. Lee Miller ◽  
Sungjo Park ◽  
Matthew N. George ◽  
Brian E. Waletzki ◽  
...  

Science ◽  
2019 ◽  
Vol 366 (6469) ◽  
pp. 1095-1098 ◽  
Author(s):  
Jiandong Cai ◽  
Chen Li ◽  
Na Kong ◽  
Yi Lu ◽  
Geyu Lin ◽  
...  

The creation of nanostructures with precise chemistries on material surfaces is of importance in a wide variety of areas such as lithography, superhydrophobicity, and cell adhesion. We describe a platform for surface functionalization that involves the fabrication of cylindrical micellar brushes on a silicon wafer through seeded growth of crystallizable block copolymers at the termini of immobilized, surface-confined crystallite seeds. The density, length, and coronal chemistry of the micellar brushes can be precisely tuned, and post-growth decoration with nanoparticles enables applications in catalysis and antibacterial surface modification. The micellar brushes can also be grown on ultrathin two-dimensional materials such as graphene oxide nanosheets and further assembled into a membrane for the separation of oil-in-water emulsions and gold nanoparticles.


2019 ◽  
Vol 23 (07n08) ◽  
pp. 828-840 ◽  
Author(s):  
Lekhetho S. Mpeta ◽  
Tebello Nyokong

Alkyne-terminated Co phthalocyanine (CoPc) derivatives are linked to reduced graphene oxide nanosheets (GONS) via click chemistry and the conjugates are used for the electrocatalytic oxidation of 2-mercaptoethanol. CoPc derivatives where the alkyne group is separated from the Pc ring by an aliphatic and benzene ring (complex 3) showed the best catalytic activity (in terms of oxidation potential) in comparison to when only aliphatic chains were employed without the benzene ring (complex 2) and when there were no substituents (complex 1). The anodic oxidation of 2-mercaptoethanol on 3-GONS (linked) occurred at the least positive oxidation potential (-0.22 V vs. Ag|AgCl). 3-GONS (linked) was found to have the highest sensitivity with the lowest limit of detection of 0.08 [Formula: see text]M. When the CoPc derivative and GONS were not linked but placed sequentially on the electrode, the electrocatalytic activity (in terms of LOD) was poorer than when linked. The electrodes modified with CoPc clicked to GONS are highly promising electrochemical sensors in terms of stability, sensitivity, good catalytic activity and ease of fabrication.


RSC Advances ◽  
2015 ◽  
Vol 5 (107) ◽  
pp. 87831-87837 ◽  
Author(s):  
Tongjie Yao ◽  
Quan Zuo ◽  
Hao Wang ◽  
Jie Wu ◽  
Xiao Zhang ◽  
...  

A one-step method to prepare reduced graphene oxide/PdxAuy/polypyrrole composites with good catalytic activity was introduced. The morphologies of alloy nanostructures could turn to be spherical, coral-like and porous cluster-like.


2018 ◽  
Vol 54 (27) ◽  
pp. 3343-3346 ◽  
Author(s):  
Tingting Liu ◽  
Shuo Wang ◽  
Qiuju Zhang ◽  
Liang Chen ◽  
Weihua Hu ◽  
...  

A Pt-free catalyst of ultrasmall Ru2P nanoparticles on reduced graphene oxide nanosheets (Ru2P/RGO-20) shows remarkable HER catalytic activity under acidic and alkaline conditions, respectively, both superior to those of commercial Pt/C.


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