Enhancing the permeation and fouling resistance of PVDF microfiltration membranes by constructing an auto-soak surface

RSC Advances ◽  
2016 ◽  
Vol 6 (114) ◽  
pp. 113267-113274 ◽  
Author(s):  
Xinzhen Zhao ◽  
Changkun Liu

A new kind of hydrophilic polyvinylidene fluoride microfiltration membrane with an auto-soak surface was fabricated by plasma treatment and interfacial crosslinking to improve the separation efficiency and fouling resistance in water treatment.

2017 ◽  
Vol 125 (12) ◽  
pp. 899-905 ◽  
Author(s):  
Jongman LEE ◽  
Jang-Hoon HA ◽  
In-Hyuck SONG ◽  
Dong Woo SHIN

Separations ◽  
2021 ◽  
Vol 9 (1) ◽  
pp. 2
Author(s):  
Shijie Xu ◽  
Wenzhong Ma ◽  
Haicun Yang ◽  
Zheng Cao ◽  
Fanghong Gong ◽  
...  

The inherent strong hydrophobicity of Polytetrafluoroetylene (PTFE) microfiltration membranes results in low separation efficiency and easy contamination. In order to enhance its hydrophilic and antifouling properties, we first modified the PTFE microfiltration membrane by using Polyethylene glycol laurate (PEGML) for first layer deposition and then used Polyvinyl alcohol (PVA)/citric acid (CA) cross-linked coatings for second layer deposition. The Scanning Electron Microscope (SEM) results showed that the fibers and nodes of the modified PTFE microfiltration membrane were coated with PVA/CA hydrophilic coating. FT-IR Spectromete and X-ray photoelectron spectrometer (XPS) analysis results confirmed that crosslinking of PVA and CA occurred and that PEGML and PVA/CA were successfully deposited onto the membrane surface. The modification conditions were optimized by hydrophilicity testing, and the best hydrophilicity of the modified membrane was achieved when the crosslinking content of PEGML was 2 g·L−1, PVA was 5 g·L−1, and CA was 2 g·L−1. PTFE microfiltration membranes modified by the optimal conditions achieved a water flux of 396.9 L·m−2·h−1 (three times that of the original membrane) at low operating pressures (0.05 MPa), and the contact angle decreased from 120° to 40°. Meanwhile, the modified PTFE microfiltration membrane has improved contamination resistance and good stability of the hydrophilic coating.


2021 ◽  
Author(s):  
Steinar Asdahl ◽  
Johann Jansen van Rensburg ◽  
Martin Einarson Waag ◽  
Rune Glenna Nilssen

Abstract Traditionally, produced water from production separators is handled by multiple steps and different technologies in order to meet the required quality for either discharge or reinjection of the water. The development of the latest Compact Flotation Unit (CFU) technology has unlocked the potential for savings on cost, complexity, footprint and weight for the produced water treatment system. The developed CFU technology has proven applicable through field testing as a single treatment technology for reducing Oil-in-Water (OiW) content directly from tie-in at separator and still meet stringent requirements for outlet OiW quality. Field tests were conducted with inlet OiW concentration ranging from 200-2000 ppm, achieving results in the range 2.5 to 21 ppm only with a two-stage latest generation CFU. Compared to a traditional produced water system setup consisting of de-oiling hydrocyclones and a horizontal degassing vessel, the savings in footprint and operational weight is estimated to 54 % and 53 % respectively utilizing a two-stage CFU for a system with a design capacity of 76.000 BWPD. Furthermore, the development of the latest generation CFU technology has enabled the retrofit concept, incorporating the developed CFU internals into existing gravity separation based produced water vessels, converting them to more efficient flotation vessels with increased capacity. For brownfield and debottlenecking applications, operators are challenged by increasing water cut from maturing wells, and as a result exceeding the facilities design capacity for produced water treatment. This challenge is often further reinforced by increasingly stricter environmental legislation for OiW content for discharge or re-injection. The retrofit concept will offer a highly cost-, footprint- and weight-efficient solutions to these challenges utilizing existing vessels. Benefits of the retrofit concept: Bring proven and unique performance of the technology to other produced water separation vessels helping the operators improve the separation efficiency and increase throughput while meeting discharge requirementsShort execution time compared to installation of new process equipmentLow cost compared to installation of new process equipmentUtilization of existing equipment saves valuable footprint.


Membranes ◽  
2021 ◽  
Vol 11 (9) ◽  
pp. 709
Author(s):  
Asmat Ullah ◽  
Kamran Alam ◽  
Saad Ullah Khan ◽  
Victor M. Starov

A new method is proposed to increase the rejection in microfiltration by applying membrane oscillation, using a new type of microfiltration membrane with slotted pores. The oscillations applied to the membrane surface result in reduced membrane fouling and increased separation efficiency. An exact mathematical solution of the flow in the surrounding solution outside the oscillating membrane is developed. The oscillation results in the appearance of a lift velocity, which moves oil particles away from the membrane. The latter results in both reduced membrane fouling and increased oil droplet rejection. This developed model was supported by the experimental results for oil water separation in the produced water treatment. It was proven that the oil droplet concentration was reduced notably in the permeate, due to the membrane oscillation, and that the applied shear rate caused by the membrane oscillation also reduced pore blockage. A four-times lower oil concentration was recorded in the permeate when the membrane vibration frequency was 25 Hz, compared to without membrane vibration. Newly generated microfiltration membranes with slotted pores were used in the experiments.


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