Encapsulation of tungstophosphoric acid into harmless MIL-101(Fe) for effectively removing cationic dye from aqueous solution

RSC Advances ◽  
2016 ◽  
Vol 6 (85) ◽  
pp. 81622-81630 ◽  
Author(s):  
Ting-Ting Zhu ◽  
Zhi-Ming Zhang ◽  
Wei-Lin Chen ◽  
Zhu-Jun Liu ◽  
En-Bo Wang

H3PW12O40 was incorporated into cages of harmless MIL-101(Fe). The composite material exhibited excellent adsorption performance for the cationic dyes MB and RhB, can be utilized in the selective capture and separation of organic dyes in water and is reusable and stable.

2014 ◽  
Vol 955-959 ◽  
pp. 38-46
Author(s):  
Da Mei Yu ◽  
Yun Lin ◽  
Yi Min Zhang ◽  
Wen Juan Zhou ◽  
Dan Hua Zhao ◽  
...  

A new hybrid adsorbent of calcium-alginate encapsulated BaSO4-CR (CABSC) has been prepared. The adsorption selectivity and mechanism were studied by investigating the adsorption performance of two anionic and two cationic dyes. The adsorption of two cationic dyes (EV and MB) from aqueous solutions was examined using a batch sorption technique. The effects of time, pH, temperature and ionic strength on the adsorption were examined. Besides, this material was applied in the treatment of two practical cationic dye wastewaters. Our study shows that the sorbent could be a potential candidate for utilization in dye wastewater treatment processes.


2014 ◽  
Vol 665 ◽  
pp. 479-482
Author(s):  
Chao Shuai ◽  
Yun Wen Liao ◽  
He Jun Gao ◽  
Luan Luan Zhang

A novel organic-inorganic PAA@Fe-Si composite material was synthesized by acrylic acid and mesoporous iron-incorporated material and used as an efficient and specific adsorbent for the removal of methylene blue (MB), a cationic dye from aqueous solution. The properties of the composite material were characterized by scanning electron microscopy, Fourier transform infrared and thermogravimetric. The effects of initial solution pH, adsorbent dosage, and contact time on MB adsorption and temperature have been investigated. The results showed that the maximum adsorption capacity of PAA@Fe-Si reached 587mg/g at 298 K, which was much better than pure Fe-Si adsorbent.


RSC Advances ◽  
2017 ◽  
Vol 7 (85) ◽  
pp. 53984-53995 ◽  
Author(s):  
Aliyar Mahdizadeh ◽  
Saeed Farhadi ◽  
Abedin Zabardasti

Graphene-analogue hexagonal boron nitride (h-BN) nanosheets are successfully synthesizedviaa facile and fast microwave-assisted method in 10 min and used as a novel adsorbent for the ultrafast removal of cationic organic dyes in aqueous solution.


2015 ◽  
Vol 63 (2) ◽  
pp. 119-124 ◽  
Author(s):  
Sati Saha ◽  
M Yousuf Ali Mollah ◽  
Md Abu Bin Hasan Susan ◽  
Md Mominul Islam

The recovery of a cationic dye, methylene blue (MB), from the residue generated during its removal via adsorption on starch-based adsorbents from aqueous solution was studied. Adsorption characteristics of MB on wheat flour (WF) and pure starch were analyzed using UV-visible spectroscopy. WF and starch were loaded with an optimum amount of MB producing MB-WF and MB-starch, respectively, leaving residues. The desorption characteristics and % recovery of MB from both the synthetic wastes were determined. The effects of yeast and temperature on the recovery of MB were also investigated. The mechanism of desorption of MB from the surface of starch was established by analyzing the weight loss profiles for different mixtures containing water, MB, WF or starch and yeast. Finally, the MB-WF and MB-starch species were fermented using diastase enzyme and yeast and the products formed were characterized by chemical, UV-visible spectroscopic and gas chromatographic analyses. The fermentation process was found to successfully convert starch to ethanol without decolorizing the MB species present in the residue.Dhaka Univ. J. Sci. 63(2):119-124, 2015 (July)


2018 ◽  
Vol 47 (11) ◽  
pp. 3913-3920 ◽  
Author(s):  
Ji-Min Yang ◽  
Rong-Jian Ying ◽  
Chun-Xiang Han ◽  
Qi-Tu Hu ◽  
Hui-Min Xu ◽  
...  

Ce(iii)-doped UiO-66 nanocrystals exhibited better dye adsorption performance than pristine UiO-66, showing the advantages of high stability and excellent porosity.


2020 ◽  
Vol 16 ◽  
Author(s):  
Reda M. El-Shishtawy ◽  
Abdullah M. Asiri ◽  
Nahed S. E. Ahmed

Background: Color effluents generated from the production industry of dyes and pigments and their use in different applications such as textile, paper, leather tanning, and food industries, are high in color and contaminants that damage the aquatic life. It is estimated that about 105 of various commercial dyes and pigments amounted to 7×105 tons are produced annually worldwide. Ultimately, about 10–15% is wasted into the effluents of the textile industry. Chitin is abundant in nature, and it is a linear biopolymer containing acetamido and hydroxyl groups amenable to render it atmospheric by introducing amino and carboxyl groups, hence able to remove different classes of toxic organic dyes from colored effluents. Methods: Chitin was chemically modified to render it amphoteric via the introduction of carboxyl and amino groups. The amphoteric chitin has been fully characterized by FTIR, TGA-DTG, elemental analysis, SEM, and point of zero charge. Adsorption optimization for both anionic and cationic dyes was made by batch adsorption method, and the conditions obtained were used for studying the kinetics and thermodynamics of adsorption. Results: The results of dye removal proved that the adsorbent was proven effective in removing both anionic and cationic dyes (Acid Red 1 and methylene blue (MB)), at their respective optimum pHs (2 for acid and 8 for cationic dye). The equilibrium isotherm at room temperature fitted the Freundlich model for MB, and the maximum adsorption capacity was 98.2 mg/g using 50 mg/l of MB, whereas the equilibrium isotherm fitted the Freundlich and Langmuir model for AR1 and the maximum adsorption capacity was 128.2 mg/g. Kinetic results indicate that the adsorption is a two-step diffusion process for both dyes as indicated by the values of the initial adsorption factor (Ri) and follows the pseudo-second-order kinetics. Also, thermodynamic calculations suggest that the adsorption of AR1 on the amphoteric chitin is an endothermic process from 294 to 303 K. The result indicated that the mechanism of adsorption is chemisorption via an ion-exchange process. Also, recycling of the adsorbent was easy, and its reuse for dye removal was effective. Conclusion: New amphoteric chitin has been successfully synthesized and characterized. This resin material, which contains amino and carboxyl groups, is novel as such chemical modification of chitin hasn’t been reported. The amphoteric chitin has proven effective in decolorizing aqueous solution from anionic and cationic dyes. The adsorption behavior of amphoteric chitin is believed to follow chemical adsorption with an ion-exchange process. The recycling process for few cycles indicated that the loaded adsorbent could be regenerated by simple treatment and retested for removing anionic and cationic dyes without any loss in the adsorbability. Therefore, the study introduces a new and easy approach for the development of amphoteric adsorbent for application in the removal of different dyes from aqueous solutions.


2016 ◽  
Vol 57 (53) ◽  
pp. 25812-25821 ◽  
Author(s):  
J. Jegan ◽  
J. Vijayaraghavan ◽  
T. Bhagavathi Pushpa ◽  
S.J. Sardhar Basha

Polymers ◽  
2021 ◽  
Vol 13 (11) ◽  
pp. 1691
Author(s):  
Angela Marotta ◽  
Enrica Luzzi ◽  
Martina Salzano de Luna ◽  
Paolo Aprea ◽  
Veronica Ambrogi ◽  
...  

Organic dyes are extensively used in many industrial sectors, and their uncontrolled disposal into wastewaters raises serious concerns for environmental and human health. Due to the large variety of such pollutants, an effective remediation strategy should be characterized by a broad-spectrum efficacy. A promising strategy is represented by the combination of different adsorbent materials with complementary functionalities to develop composite materials that are expected to remove different contaminants. In the present work, a broad-spectrum adsorbent was developed by embedding zeolite 13X powder (ZX) in a chitosan (CS) aerogel (1:1 by weight). The CS–ZX composite adsorbent removes both anionic (indigo carmine, IC) and cationic (methylene blue, MB) dyes effectively, with a maximum uptake capacity of 221 mg/g and 108 mg/g, respectively. In addition, the adsorption kinetics are rather fast, with equilibrium conditions attained in less than 2 h. The composite exhibits good mechanical properties in both dry and wet state, which enables its handling for reusability purposes. In this regard, preliminary tests show that the full restoration of the IC removal ability over three adsorption–desorption cycles is achieved using a 0.1 M NaOH aqueous solution, while a 1 M NaCl aqueous solution allows one to preserve >60% of the MB removal ability.


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