Sphere-like CoS with nanostructures as peroxidase mimics for colorimetric determination of H2O2 and mercury ions

RSC Advances ◽  
2016 ◽  
Vol 6 (71) ◽  
pp. 66963-66970 ◽  
Author(s):  
Haiguan Yang ◽  
Junqi Zha ◽  
Peng Zhang ◽  
Yuhao Xiong ◽  
Linjing Su ◽  
...  

CoS, which was prepared using a facile solvothermal method, and characterized using various analytical techniques, was demonstrated for the first time to exhibit intrinsic peroxidase-like activity.

2020 ◽  
Vol 44 (30) ◽  
pp. 12962-12966
Author(s):  
Jing Sun ◽  
Rui Wang ◽  
Meng Xia ◽  
Shuyun Zhu ◽  
Xian-En Zhao

A facile colorimetric assay for the sensitive and selective detection of alendronate sodium has been developed based on Ce4+-triggered oxidation of TMB for the first time.


2020 ◽  
Vol 187 (8) ◽  
Author(s):  
Zhe Wang ◽  
Peng Ju ◽  
Yu Zhang ◽  
Fenghua Jiang ◽  
Haibing Ding ◽  
...  

2021 ◽  
Vol 37 (3) ◽  
pp. 679-682
Author(s):  
S. Kavitha ◽  
S. Mary Jelastin Kala ◽  
A. Anand Babu Christus

This paper presents colorimetric determination of Hg(II) based on MoS2 nanosheets with peroxidase mimics activity. The structure of the this sensor by the peroxidase mimic activity material of MoS2 nanosheets with TMB (Tetramethylbenzidine) solution, the colorimetric detection target of Hg(II) is determined by on-off mechanism using biomolecule of cysteine. The MoS2 nanosheets evaluated by X-ray diffraction, FT-IR and SEM image, confirms formation of a flower like structure. Our results shows that a simple colorimetric detection using peroxidase mimic mechanism can be used to MoS2 nanosheets and determine the Hg(II) in aqueous solution with high sensitivity (10 nM) comparable to those of other nanomaterials. The result suggests that MoS2 nanosheets is a promising new and simple colorimetric sensor for applications in environmental and biological applications.


1998 ◽  
Vol 4 (S2) ◽  
pp. 812-813
Author(s):  
A. P. Smith ◽  
A. Garcia ◽  
H. Ade

Determination of internal structure of complex polymeric materials often requires a variety of analytical techniques. One technique that we have developed and recently employed for the first time for quantitative analysis is x-ray linear dichroism microscopy. With sensitivity to the presence and orientation of specific chemical functionalities within polymer molecules, x-ray linear dichroism microscopy provides a powerful tool to probe the internal structure of such molecules. We have used this ability to quantitatively analyze the lateral orientational order (tangential and radial orientation of transverse sections) within different grades of poly(p-phenylene terephthalamide) (Kevlar) fibers.Kevlar fibers are highly crystalline and possess a complicated internal structure that exhibits lateral radial orientation. Figure 1 shows x-ray micrographs of (a) Kevlar 149, (b) Kevlar 49 and (c) Kevlar 29 fibers imaged at a photon energy specific to the aromatic functionality.


2020 ◽  
Vol 56 (4) ◽  
pp. 519-522 ◽  
Author(s):  
Bin Wang ◽  
Xicheng Liu ◽  
Peiwei Gong ◽  
Xingxing Ge ◽  
Zhe Liu ◽  
...  

For the first time, a facile solvothermal method to synthesize COFs with a nanosized structure and bright fluorescence was reported to monitor drug loading with the naked eye and realize responsive release.


2016 ◽  
Vol 99 (4) ◽  
pp. 1049-1057 ◽  
Author(s):  
Qiao-Ying Chang ◽  
Guo-Fang Pang ◽  
Chun-Lin Fan ◽  
Hui Chen ◽  
Zhi-Bin Wang

Abstract The degradation rate of 271 pesticide residues in aged Oolong tea at two spray concentrations, named a and b (a < b), were monitored for 120 days using GC–tandem MS (GC-MS/MS). To research the degradation trends and establish regression equations, determination days were plotted as horizontal ordinates and the residue concentrations of pesticide were plotted as vertical ordinates. Here, we consider the degradation equations of 271 pesticides over 40 and 120 days, summarize the degradation rates in six aspects (A–F), and discuss the degradation trends of the 271 pesticides in aged Oolong tea in detail. The results indicate that >70% of the determined pesticides coincide with the degradation regularity of trends A, B, and E, i.e., the concentration of pesticide will decrease within 4 months. Next, 20 representative pesticides were selected for further study at higher spray concentrations, named c and d (d > c > b > a), in aged Oolong tea over another 90 days. The determination days were plotted on the x-axis, and the differences between each determined result and first-time-determined value of target pesticides were plotted on the y-axis. The logarithmic function was obtained by fitting the 90-day determination results, allowing the degradation value of a target pesticide on a specific day to be calculated. These logarithmic functions at d concentration were applied to predict the residue concentrations of pesticides at c concentration. Results revealed that 70% of the 20 pesticides had the lower deviation ratios of predicted and measured results.


2017 ◽  
Vol 5 (31) ◽  
pp. 16412-16421 ◽  
Author(s):  
Jingsheng Cai ◽  
Jianying Huang ◽  
Yuekun Lai

To develop an efficient visible-light-driven photocatalyst electrode for environmental remediation, a novel ternary nanocomposite of an Au-decorated Bi2MoO6 nanosheet/TiO2 nanotube array (NTA) heterojunction was successfully fabricated for the first time via a facile solvothermal method combined with mussel-inspired functional modification of electrochemical polymerization of dopamine.


Author(s):  
A. Anand Babu Christus ◽  
P. Panneerselvam ◽  
A. Ravikumar ◽  
Norhashimah Morad ◽  
S. Sivanesan

RSC Advances ◽  
2017 ◽  
Vol 7 (5) ◽  
pp. 2943-2952 ◽  
Author(s):  
Jia Yang ◽  
Xiaojun Niu ◽  
Shaorong An ◽  
Weiyi Chen ◽  
Jie Wang ◽  
...  

A novel Bi2MoO6–MIL-100(Fe) photocatalyst was synthesized by a facile solvothermal method for the first time, and characterized by XRD, SEM, XPS, UV-vis, TEM, and PL. The Bi2MoO6–MIL-100(Fe) exhibited excellent photocatalytic activity and stability.


2021 ◽  
Author(s):  
Chonlada Bennett ◽  
Phumon Sookwong ◽  
Jaroon Jakmunee ◽  
Sugunya Mahatheeranont

In this research, the pH differential method was explored for the first time using a mobile phone as a detector, replacing UV-Vis spectrophotometry. A smartphone digital image colorimetric (SDIC) system...


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