scholarly journals Copolymer films containing amphiphilic side chains of well-defined fluoroalkyl-segment length with biofouling-release potential

RSC Advances ◽  
2016 ◽  
Vol 6 (71) ◽  
pp. 67127-67135 ◽  
Author(s):  
Giancarlo Galli ◽  
David Barsi ◽  
Elisa Martinelli ◽  
Antonella Glisenti ◽  
John A. Finlay ◽  
...  
Keyword(s):  
Segment Length ◽  
Side Chains ◽  
Copolymer Films ◽  
Methacrylate Copolymers ◽  
Surface Active ◽  
Release Potential

Novel methacrylate copolymers containing polysiloxane (SiMA) and mixed poly(ethyleneglycol)-perfluorohexyl side chains (MEF) were synthesised and dispersed as surface-active additives in crosslinked PDMS films.

pH-Responsive Random Copolymer Films with Amine Side Chains

2007 ◽  
Vol 111 (1) ◽  
pp. 461-466 ◽  
Author(s):  
Dongshun Bai ◽  
Zulkifli Ibrahim ◽  
G. Kane Jennings
Keyword(s):  
Random Copolymer ◽  
Side Chains ◽  
Ph Responsive ◽  
Copolymer Films

Quantifying chloride binding and salt extraction with poly(methyl methacrylate) copolymers bearing aryl-triazoles as anion receptor side chains

2014 ◽  
Vol 50 (87) ◽  
pp. 13285-13288 ◽  
Author(s):  
Kevin P. McDonald ◽  
Bo Qiao ◽  
Eric B. Twum ◽  
Semin Lee ◽  
Patrick J. Gamache ◽  
...  
Keyword(s):  
Methyl Methacrylate ◽  
Side Chains ◽  
Chloride Binding ◽  
Anion Receptor ◽  
Poly Methyl Methacrylate ◽  
Salt Extraction ◽  
Methacrylate Copolymers

scholarly journals Surface Segregation of Amphiphilic PDMS-Based Films Containing Terpolymers with Siloxane, Fluorinated and Ethoxylated Side Chains

Coatings ◽  
2019 ◽  
Vol 9 (3) ◽  
pp. 153 ◽  
Author(s):  
Elisa Martinelli ◽  
Elisa Guazzelli ◽  
Antonella Glisenti ◽  
Giancarlo Galli
Keyword(s):  
Photoelectron Spectroscopy ◽  
Surface Segregation ◽  
Water Environment ◽  
Film Surface ◽  
Side Chain ◽  
Chemical Compositions ◽  
Side Chains ◽  
Air Interface ◽  
High Enrichment ◽  
Surface Active

(Meth)acrylic terpolymers carrying siloxane (Si), fluoroalkyl (F) and ethoxylated (EG) side chains were synthesized with comparable molar compositions and different lengths of the Si and EG side chains, while the length of the fluorinated side chain was kept constant. Such terpolymers were used as surface-active modifiers of polydimethylsiloxane (PDMS)-based films with a loading of 4 wt%. The surface chemical compositions of both the films and the pristine terpolymers were determined by angle-resolved X-ray photoelectron spectroscopy (AR-XPS) at different photoemission angles. The terpolymer was effectively segregated to the polymer−air interface of the films independent of the length of the constituent side chains. However, the specific details of the film surface modification depended upon the chemical structure of the terpolymer itself. The exceptionally high enrichment in F chains at the surface caused the accumulation of EG chains at the surface as well. The response of the films to the water environment was also proven to strictly depend on the type of terpolymer contained. While terpolymers with shorter EG chains appeared not to be affected by immersion in water for seven days, those containing longer EG chains underwent a massive surface reconstruction.

ABC Triblock Surface Active Block Copolymer with Grafted Ethoxylated Fluoroalkyl Amphiphilic Side Chains for Marine Antifouling/Fouling-Release Applications

Langmuir ◽  
2009 ◽  
Vol 25 (20) ◽  
pp. 12266-12274 ◽  
Author(s):  
Craig J. Weinman ◽  
John A. Finlay ◽  
Daewon Park ◽  
Marvin Y. Paik ◽  
Sitaraman Krishnan ◽  
...  
Keyword(s):  
Block Copolymer ◽  
Side Chains ◽  
Fouling Release ◽  
Surface Active ◽  
Marine Antifouling ◽  
Active Block

Methacrylate Copolymers with Liquid Crystalline Side Chains for Organic Gate Dielectric Applications

2014 ◽  
Vol 7 (23) ◽  
pp. 12339-12347 ◽  
Author(s):  
Andreas Berndt ◽  
Doris Pospiech ◽  
Dieter Jehnichen ◽  
Liane Häußler ◽  
Brigitte Voit ◽  
...  
Keyword(s):  
Liquid Crystalline ◽  
Gate Dielectric ◽  
Side Chains ◽  
Methacrylate Copolymers

scholarly journals Effects of surface-active block copolymers with oxyethylene and fluoroalkyl side chains on the antifouling performance of silicone-based films

Biofouling ◽  
2016 ◽  
Vol 32 (1) ◽  
pp. 81-93 ◽  
Author(s):  
Elisa Martinelli ◽  
Deniz Gunes ◽  
Brandon M. Wenning ◽  
Christopher K. Ober ◽  
John A. Finlay ◽  
...  
Keyword(s):  
Block Copolymers ◽  
Side Chains ◽  
Surface Active ◽  
Active Block

Preparation and characterization of acrylonitrile-ethyl methacrylate copolymers and the effect of LiClO4 salt on electrical properties of copolymer films

2011 ◽  
Vol 124 (1) ◽  
pp. 840-846 ◽  
Author(s):  
Elif Vargün ◽  
Mehmet Sankır ◽  
Ali Usanmaz ◽  
Yasin Kanbur ◽  
Ufuk Abacı ◽  
...  
Keyword(s):  
Electrical Properties ◽  
Ethyl Methacrylate ◽  
Copolymer Films ◽  
Methacrylate Copolymers

Solid-state structure and formation of organized molecular films of methacrylate copolymers containing fluorinated and hydrogenated side-chains

2007 ◽  
Vol 47 (4) ◽  
pp. 354-364 ◽  
Author(s):  
Atsuhiro Fujimori ◽  
Satoshi Kobayashi ◽  
Hiroko Hoshizawa ◽  
Ryosuke Masuya ◽  
Toru Masuko
Keyword(s):  
Solid State ◽  
Side Chains ◽  
Molecular Films ◽  
State Structure ◽  
Solid State Structure ◽  
Methacrylate Copolymers
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