Methyl-viologen modified ZnO nanotubes for use in electrochromic devices

RSC Advances ◽  
2016 ◽  
Vol 6 (76) ◽  
pp. 72037-72043 ◽  
Author(s):  
Shao-yang Li ◽  
Yue Wang ◽  
Jia-Gen Wu ◽  
Li-feng Guo ◽  
Mao Ye ◽  
...  

Efficiently changing optical properties (reflectance, transmittance, and absorbance) through reversible color changes of electrochromic (EC) materials is challenging and critical in achieving high-performance EC devices.

2020 ◽  
Vol 0 (0) ◽  
Author(s):  
Ali A. Alhazime ◽  
Nesreen T. El-Shamy ◽  
Kaoutar Benthami ◽  
Mai ME. Barakat ◽  
Samir A. Nouh

AbstractNanocomposite films of polymethylmethacrylate PMMA with Sn0.75Fe0.25S2 nanoparticles (NPs) were fabricated by both thermolysis and casting techniques. Changes in PMMA/Sn0.75Fe0.25S2 nanocomposite (NCP) due to gamma irradiation have been measured. XRD results indicate that the gamma doses of 10–80 kGy cause intermolecular crosslinking that reduces the ordered portion in the NPs. Bonding between the NPs and the host PMMA was confirmed by FTIR. TGA results indicate an enhancement in thermal stability in the NCP films irradiated with doses 20–80 kGy. The optical band gap was reduced from 3.23 to 2.47 eV upon gamma irradiation up to 80 kGy due bonding between the NPs and PMMA which enhanced the amorphous part of the NPs. Finally, the color variation between the blank and irradiated films (ΔE) was determined. Color changes immensely when the PMMA/Sn0.75Fe0.25S2 NCP films are gamma irradiated. Values of ΔE were as much as 31.6 which is an acceptable match in commercial reproduction on printing presses.


Nanomaterials ◽  
2021 ◽  
Vol 11 (1) ◽  
pp. 197
Author(s):  
Giorgia Giovannini ◽  
René M. Rossi ◽  
Luciano F. Boesel

The development of hybrid materials with unique optical properties has been a challenge for the creation of high-performance composites. The improved photophysical and photochemical properties observed when fluorophores interact with clay minerals, as well as the accessibility and easy handling of such natural materials, make these nanocomposites attractive for designing novel optical hybrid materials. Here, we present a method of promoting this interaction by conjugating dyes with chitosan. The fluorescent properties of conjugated dye–montmorillonite (MMT) hybrids were similar to those of free dye–MMT hybrids. Moreover, we analyzed the relationship between the changes in optical properties of the dye interacting with clay and its structure and defined the physical and chemical mechanisms that take place upon dye–MMT interactions leading to the optical changes. Conjugation to chitosan additionally ensures stable adsorption on clay nanoplatelets due to the strong electrostatic interaction between chitosan and clay. This work thus provides a method to facilitate the design of solid-state hybrid nanomaterials relevant for potential applications in bioimaging, sensing and optical purposes.


RSC Advances ◽  
2015 ◽  
Vol 5 (71) ◽  
pp. 57339-57345 ◽  
Author(s):  
Yooseong Yang ◽  
Youngsuk Jung ◽  
Myung Dong Cho ◽  
Seung Geol Lee ◽  
Soonchul Kwon

Stable optical properties of high transmittance and low yellow index, which are required for a polyimide film as a flexible display substrate could be affected by thermal imidization even in oxidative-stable fluorinated polyimides.


2018 ◽  
Vol 62 ◽  
pp. 151-156 ◽  
Author(s):  
Keon-Woo Kim ◽  
Seong Been Lee ◽  
Se Hyun Kim ◽  
Hong Chul Moon

2013 ◽  
Vol 118 (1) ◽  
pp. 476-481 ◽  
Author(s):  
David D. Yao ◽  
Rozina A. Rani ◽  
Anthony P. O’Mullane ◽  
Kourosh Kalantar-zadeh ◽  
Jian Zhen Ou

Micromachines ◽  
2018 ◽  
Vol 9 (7) ◽  
pp. 350 ◽  
Author(s):  
Dong Shin ◽  
Suk-Ho Choi

Graphene transparent conductive electrodes are highly attractive for photodetector (PD) applications due to their excellent electrical and optical properties. The emergence of graphene/semiconductor hybrid heterostructures provides a platform useful for fabricating high-performance optoelectronic devices, thereby overcoming the inherent limitations of graphene. Here, we review the studies of PDs based on graphene/semiconductor hybrid heterostructures, including device physics/design, performance, and process technologies for the optimization of PDs. In the last section, existing technologies and future challenges for PD applications of graphene/semiconductor hybrid heterostructures are discussed.


2018 ◽  
Vol 73 (8) ◽  
pp. 601-609 ◽  
Author(s):  
Bei Wang ◽  
Pei-Zhi Zhang ◽  
Xin Chen ◽  
Ai-Quan Jia ◽  
Qian-Feng Zhang

AbstractA series of guanidinium chloride derivatives have been synthesized by condensation of 1,3-diaminoguanidine monohydrochloride with heteroaromatic formaldehydes in good yields. All compounds were characterized by nuclear magnetic resonances and infrared spectroscopies, and the molecular structures of four compounds were determined by single crystal X-ray diffraction. The optical properties of these guanidinium chloride derivatives with fluoride anions were investigated, showing selective color changes from colorless to yellow or orange, red-shifted in the ultraviolet/visible absorption spectra.


2012 ◽  
Vol 134 (51) ◽  
pp. 20756-20767 ◽  
Author(s):  
Chi Xu ◽  
Richard T. Beeler ◽  
Gordon J. Grzybowski ◽  
Andrew V.G. Chizmeshya ◽  
David J. Smith ◽  
...  

Nano Letters ◽  
2018 ◽  
Vol 18 (9) ◽  
pp. 5646-5651 ◽  
Author(s):  
Ashraful Azam ◽  
Jungmo Kim ◽  
Junyong Park ◽  
Travis G. Novak ◽  
Anand P. Tiwari ◽  
...  

Coatings ◽  
2018 ◽  
Vol 8 (10) ◽  
pp. 329 ◽  
Author(s):  
Dong Shin ◽  
Suk-Ho Choi

It is necessary to develop semitransparent photovoltaic cell for increasing the energy density from sunlight, useful for harvesting solar energy through the windows and roofs of buildings and vehicles. Current semitransparent photovoltaics are mostly based on Si, but it is difficult to adjust the color transmitted through Si cells intrinsically for enhancing the visual comfort for human. Recent intensive studies on translucent polymer- and perovskite-based photovoltaic cells offer considerable opportunities to escape from Si-oriented photovoltaics because their electrical and optical properties can be easily controlled by adjusting the material composition. Here, we review recent progress in materials fabrication, design of cell structure, and device engineering/characterization for high-performance/semitransparent organic and perovskite solar cells, and discuss major problems to overcome for commercialization of these solar cells.


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