Significantly improving mechanical, thermal and dielectric properties of cyanate ester resin through building a new crosslinked network with unique polysiloxane@polyimide core–shell microsphere

RSC Advances ◽  
2016 ◽  
Vol 6 (47) ◽  
pp. 40962-40969 ◽  
Author(s):  
Xinyi Dong ◽  
Zhijuan Zhang ◽  
Li Yuan ◽  
Guozheng Liang ◽  
Aijuan Gu
Keyword(s):  
Dielectric Properties ◽  
Cyanate Ester ◽  
Core Shell ◽  
Cyanate Ester Resin

Tough, rigid and thermally resistant resins with outstanding dielectric properties were developed based on polysiloxane@polyimide core–shell microspheres and cyanate ester.

An in situ (K0.5Na0.5)NbO3-doped barium titanate foam framework and its cyanate ester resin composites with temperature-stable dielectric properties and low dielectric loss

2019 ◽  
Vol 3 (4) ◽  
pp. 726-736 ◽  
Author(s):  
Longhui Zheng ◽  
Li Yuan ◽  
Guozheng Liang ◽  
Aijuan Gu
Keyword(s):  
Dielectric Properties ◽  
Dielectric Loss ◽  
Barium Titanate ◽  
Cyanate Ester ◽  
Resin Composites ◽  
Cyanate Ester Resin ◽  
Low Dielectric ◽  
Doped Barium Titanate

High-k composites with temperature-stable dielectric properties and low dielectric loss obtained through building a network with in situ-doped barium titanate foam.

scholarly journals Cyanate ester resin based composites with high toughness and thermal conductivity

RSC Advances ◽  
2019 ◽  
Vol 9 (10) ◽  
pp. 5722-5730 ◽  
Author(s):  
Le Zhai ◽  
Zhenxin Liu ◽  
Chen Li ◽  
Xiongwei Qu ◽  
Qingxin Zhang ◽  
...  
Keyword(s):  
Thermal Conductivity ◽  
Impact Strength ◽  
Cyanate Ester ◽  
Core Shell ◽  
Microelectronic Packaging ◽  
Cyanate Ester Resin ◽  
High Toughness ◽  
The Impact

h-BN particles were used to fabricate cyanate ester/core–shell structured polyacrylic/BN composites. The impact strength and the thermal conductivity of the composites were simultaneously increased, which may be used in microelectronic packaging.

Preparation and Dielectric Properties of POSS-NH2/Cyanate Ester Resin Organic-Inorganic Hybrids

2011 ◽  
Vol 216 ◽  
pp. 635-639 ◽  
Author(s):  
Zeng Ping Zhang ◽  
Jian Zhong Pei ◽  
Shuan Fa Chen ◽  
Hong Zhao Du ◽  
Yong Wen
Keyword(s):  
Dielectric Constant ◽  
Dielectric Properties ◽  
Dielectric Loss ◽  
Cyanate Ester ◽  
Cyanate Ester Resin ◽  
Curing Reaction ◽  
Ft Ir ◽  
Different Content

In order to improve the dielectric and overal properties of cyanate ester (CE) resin, a functional POSS monomer(octa(aminopropyl)silsesquioxane, POSS-NH2), was employed to modify CE. A series of POSS-NH2/CE hybrids (CE, CE1, CE2, CE3 and CE4) containing different content of POSS have been prepared by melt casting and then curing. The curing reaction of the resin systems were monitored by FT-IR. Dielectric properties of the hybrids were investigated in detail. FT-IR results showed the almost disappearance of the –OCN for all resin systems, suggesting the complete curing of CE using the experimental curing technique. Dielectric investigation indicates that CE1 which contains 1 wt% of POSS has the best dielectric properties with not only lowest dielectric constant but also lowest dielectric loss.

Dielectric and Hot/Wet Properties of Methyl-Silsesquioxane/Cyanate Ester Resin Hybrid Materials

2011 ◽  
Vol 216 ◽  
pp. 630-634
Author(s):  
Zeng Ping Zhang ◽  
Yong Wen ◽  
Hong Zhao Du ◽  
Jian Zhong Pei ◽  
Shuan Fa Chen
Keyword(s):  
Dielectric Constant ◽  
Dielectric Properties ◽  
Dielectric Loss ◽  
High Performance ◽  
Printed Circuit Board ◽  
Cyanate Ester ◽  
Circuit Board ◽  
Printed Circuit ◽  
Cyanate Ester Resin ◽  
Properties Of Materials

Methylsilsesquioxane (Me-SSQ) was incorporated into cyanate ester resin (CE) to obtain organic-inorganic hybrids with better dielectric properties in this study. First, methyltriethoxysilane was hydrolyzed and condensed to synthesize Me-SSQ. Then several Me-SSQ/CE hybrids containing different contents of Me-SSQ were prepared. The effect of Me-SSQ content on the dielectric and hot/wet properties of materials was investigated. Results showed that the Me-SSQ/CE hybrid containing 20wt% of Me-SSQ shows a dielectric constant of 2.78, which is much lower than the pure CE resin. At the same time, the dielectric loss of the Me-SSQ/CE hybrids was slightly increased (tanδ<0.006). It indicates that Me-SSQ/CE hybrid is a promising matrix materials for high-performance printed circuit board (PCB).

POSS-NH2/Cyanate Ester Resin Organic-Inorganic Hybrids: Curing Reaction and Dielectric Properties

2011 ◽  
Vol 266 ◽  
pp. 147-150 ◽  
Author(s):  
Zeng Ping Zhang ◽  
Shuan Fa Chen ◽  
Jian Zhong Pei
Keyword(s):  
Dielectric Properties ◽  
Catalytic Effect ◽  
Curing Kinetics ◽  
Cyanate Ester ◽  
Cyanate Ester Resin ◽  
Curing Reaction ◽  
Ft Ir ◽  
Higher Temperature ◽  
Lower Temperature ◽  
Different Content

A functional POSS monomer (POSS-NH2) was employed to modify cyanate ester (CE) resin. A series of POSS-NH2/CE hybrids containing different content of POSS have been prepared by melt casting and then curing. The curing kinetics and reaction mechanisms of the resin systems were studied by using FT-IR. Dielectric properties of the hybrids were also investigated. FT-IR results show that both temperature and POSS content may influence the curing reaction of CE. POSS-NH2 mainly displays the catalytic effect at higher temperature (220oC). The circumstance is more complex at lower temperature(190oC). CE1 containing 1 wt% of POSS has the best dielectric properties.

Simultaneously toughening and strengthening cyanate ester resin with better dielectric properties by building nanostructures in its crosslinked network using polyimide-block-polysiloxane rod-coil block copolymers

RSC Advances ◽  
2016 ◽  
Vol 6 (55) ◽  
pp. 49436-49447 ◽  
Author(s):  
Yayi Ye ◽  
Li Yuan ◽  
Guozheng Liang ◽  
Aijuan Gu
Keyword(s):  
Dielectric Properties ◽  
Block Copolymers ◽  
High Performance ◽  
Cyanate Ester ◽  
Cyanate Ester Resin ◽  
Cyanate Ester Resins

The fabrication and origin of high performance cyanate ester resins by building nanostructures in its crosslinked network with polyimide-block-polysiloxane block copolymers.

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