Fixation of carbon dioxide concurrently or in tandem with free radical polymerization for highly transparent polyacrylates with specific UV absorption

2016 ◽  
Vol 7 (22) ◽  
pp. 3731-3739 ◽  
Author(s):  
Bin Liu ◽  
Ying-Ying Zhang ◽  
Xing-Hong Zhang ◽  
Bin-Yang Du ◽  
Zhi-Qiang Fan
Keyword(s):  
Carbon Dioxide ◽  
Free Radical ◽  
Radical Polymerization ◽  
Wavelength Range ◽  
Free Radical Polymerization ◽  
Uv Absorption ◽  
Fixation Of Carbon Dioxide

Highly transparent CO2-based polyacrylates with nearly 100% UV absorption in a wavelength range of 200–313 nm are prepared.

Controlled Dispersion Polymerization in Supercritical Carbon Dioxide

2009 ◽  
Vol 62 (8) ◽  
pp. 786 ◽  
Author(s):  
Kristofer J. Thurecht ◽  
Steven M. Howdle
Keyword(s):  
Carbon Dioxide ◽  
Free Radical ◽  
Radical Polymerization ◽  
Material Properties ◽  
Supercritical Co2 ◽  
Dispersion Polymerization ◽  
Free Radical Polymerization ◽  
Short Report ◽  
Controlled Polymerization ◽  
Increased Activity

Recent advances in controlled polymerization have led to increased activity in controlled free radical polymerization in unconventional solvents. This short report focuses on the renewed interest in dispersion polymerization in supercritical CO2 brought about by the application of controlled free radical polymerization techniques. The emergence of novel and industrially-applicable materials is discussed, as well as the dependence of material properties and morphology upon factors such as surfactant type and how it is employed during the polymerization.

Kinetics of Free Radical Polymerization of Spacerless Dendronized Macromonomers in Supercritical Carbon Dioxide

2011 ◽  
Vol 44 (11) ◽  
pp. 4038-4048 ◽  
Author(s):  
L. I. Costa ◽  
G. Storti ◽  
M. Morbidelli ◽  
X. Zhang ◽  
B. Zhang ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Free Radical ◽  
Supercritical Carbon Dioxide ◽  
Radical Polymerization ◽  
Free Radical Polymerization ◽  
Kinetics Of ◽  
Supercritical Carbon

Non-isothermal Kinetics of Free Radical Polymerization of 2-Phenylethyl (Meth)acrylate

2018 ◽  
Vol 8 (3) ◽  
pp. 585-594
Author(s):  
Khdbudin Mulani ◽  
Ravindra Ghorpade ◽  
Surendra Ponrathnam ◽  
Nayaku Chavan ◽  
Kamini Donde
Keyword(s):  
Free Radical ◽  
Radical Polymerization ◽  
Free Radical Polymerization ◽  
Isothermal Kinetics ◽  
Kinetics Of
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