Catalytic photodegradation of pharmaceuticals – homogeneous and heterogeneous photocatalysis

2017 ◽  
Vol 16 (1) ◽  
pp. 67-71 ◽  
Author(s):  
S. Klementova ◽  
D. Kahoun ◽  
L. Doubkova ◽  
K. Frejlachova ◽  
M. Dusakova ◽  
...  

Photoinitiated processes involving Fe(iii) as the catalyst – a feasible mechanism for the degradation of pharmaceuticals and personal care products in natural waters. Reactivity in the homogeneous phase was compared with degradation on TiO2.

2002 ◽  
Vol 46 (3) ◽  
pp. 97-104 ◽  
Author(s):  
A. Bruchet ◽  
C. Prompsy ◽  
G. Filippi ◽  
A. Souali

This paper describes the implementation of a broad-spectrum analytical scheme which was used at three wastewater plants for the screening of organic micropollutants. The more than 200 compounds identified comprised a variety of endocrine disrupters, pharmaceutical compounds and personal care products. Glycol ethers which have well established effects on the development of the embryo were outstanding in all plants investigated. The first plant, which was investigated at various stages of treatment, was quite efficient at removing undesirable compounds. The second plant, which received 50% of effluents from pharmaceutical industries, released low but significant levels of drugs. An antibiotic, cyclamidomycine, was identified in the effluent from the third plant.


BMC Chemistry ◽  
2020 ◽  
Vol 14 (1) ◽  
Author(s):  
Adewumi Olufemi Oluwole ◽  
Elizabeth Oyinkansola Omotola ◽  
Olatunde Stephen Olatunji

Abstract The presence of emerging contaminants such as pharmaceutical and personal care products in many aqueous matrices have been reported. One of such matrix is streams of wastewater, including wastewater treatment plants inflows and outflows and wastewater flow by-passing wastewater treatment plants. Their persistence arises from their resistant to breakdown, hence they may remain in the environment over long time, with a potential to cause adverse effects including endocrine disruption, gene toxicity, the imposition of sex organs, antibiotic resistance and many others in some aquatic organisms exposed to arrays of residues of pharmaceutical and personal care products. Among the treatment techniques, advanced oxidation processes have been reported to be a better technique through which these PPCPs can be degraded in the WWTPs. Heterogeneous photocatalysis using various photocatalyst immobilized on solid support such as activated carbon, graphene and carbon nanotubes in AOPs have been shown to be a viable and efficient method of PPCPs degradation. This is because, the performance of most WWTPs is limited since they were not designed to degrade toxic and recalcitrant PPCPs. This review highlight the occurrence, concentration of PPCPs in wastewater and the removal efficiency of heterogeneous photocatalysis of TiO2 immobilized on solid supports.


2018 ◽  
Vol 12 ◽  
pp. 117863021879583 ◽  
Author(s):  
Sabino Maldonado-Torres ◽  
Rubi Gurung ◽  
Hom Rijal ◽  
Andrew Chan ◽  
Shishir Acharya ◽  
...  

With the growth of the human population, a greater quantity of pharmaceutical and personal care products (PPCPs) have been released into the environment. Although research has addressed the levels and the impact of PPCPs in the environment, the fate of these compounds in surface waters is neither well known nor characterized. In the environment, PPCPs can undergo various transformations that are critically dependent on environmental factors such as solar radiation and the presence of soil particles. Given that the degradation products of PPCPs are poorly characterized, these “secondary residues” can be a significant environmental health hazard due to their drastically different toxicologic effects when compared with the parent compounds. To better understand the fate of PPCPs, we studied the degradation of selected PPCPs, including ibuprofen and clofibric acid, in aqueous solutions that contained kaolinite clay and were irradiated with a solar simulator. The most abundant degradation products were identified and assessed for their toxicologic impact on selected microorganisms. The degraded mixtures showed lower toxicity than the starting compounds; however, as these degradation products are capable of further transformation and interaction with other PPCPs in natural waters, our work highlights the importance of additionally characterizing the PPCP degradation products.


2012 ◽  
Vol 2 (10) ◽  
pp. 1-2
Author(s):  
D. Muthukrishnaveni D. Muthukrishnaveni ◽  
◽  
Dr. D. Muruganandam Dr. D. Muruganandam

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