Recent progress in mild Csp3–H bond dehydrogenative or (mono-) oxidative functionalization

2017 ◽  
Vol 15 (6) ◽  
pp. 1294-1312 ◽  
Author(s):  
Andrea Gini ◽  
Tobias Brandhofer ◽  
Olga García Mancheño

This review summarizes recent advances in mild and green dehydrogenative and mono-oxidative Csp3–H bond functionalization reactions, considering both new approaches and the re-elaboration of known methodologies.

Author(s):  
Zhaoming Kang ◽  
Muhammad Arif Khan ◽  
Yanmei Gong ◽  
Rida Javed ◽  
Yuan Xu ◽  
...  

In this review, recent advances in MXenes and MXene-based nanomaterials applied in HER electrocatalysis are overviewed in terms of their synthesis, characterization, functional mechanisms, and HERperformance/optimization.


2015 ◽  
Author(s):  
Arash Zakeri ◽  
Ed Clukey ◽  
Buba Kebadze ◽  
Philippe Jeanjean ◽  
Dan Walker ◽  
...  

2021 ◽  
Author(s):  
Sandeep Pimparkar ◽  
Aishwarya K. Dalvi ◽  
Adithyaraj Koodan ◽  
Siddhartha Maiti ◽  
Shaeel Al-Thabaiti ◽  
...  

Carbon dioxide (CO2) has emerged as one of the exciting cost-effective, abundant, and ready-to-use C1 sources in synthetic organic chemistry. However, the thermodynamic stability, as well as the kinetic inertness,...


2016 ◽  
Vol 12 ◽  
pp. 2834-2848 ◽  
Author(s):  
Pavel Nagorny ◽  
Zhankui Sun

Hydrogen bond donor catalysis represents a rapidly growing subfield of organocatalysis. While traditional hydrogen bond donors containing N–H and O–H moieties have been effectively used for electrophile activation, activation based on other types of non-covalent interactions is less common. This mini review highlights recent progress in developing and exploring new organic catalysts for electrophile activation through the formation of C–H hydrogen bonds and C–X halogen bonds.


1998 ◽  
Vol 51 (3) ◽  
pp. 312-320
Author(s):  
S. Ratcliffe

Recent advances in technology have encouraged proposals for new approaches to ATC in Europe and elsewhere. Two such proposals, both rather loosely framed, are for ‘free flight’ or for ‘seamless contracts’; otherwise ‘tubes of flight’. These concepts, and variations on them, aim to increase the traffic capacity of the airspace. They have been the subject of numerous published papers. Given the declared objects of these systems, it is surprising that, nearly without exception, these papers discuss the proposals only in qualitative terms. The present paper discusses idealised versions of these systems on the basis of quantitative studies. It is concluded that the ‘seamless contract’ is very probably unworkable in Europe. ‘free flight’ is workable in principle, but there is a need for investigation of possible mechanisms by which last-minute problems may be resolved.


Nanoscale ◽  
2015 ◽  
Vol 7 (11) ◽  
pp. 4820-4868 ◽  
Author(s):  
Manish Srivastava ◽  
Jay Singh ◽  
Tapas Kuila ◽  
Rama K. Layek ◽  
Nam Hoon Kim ◽  
...  

This review highlights the recent progress in graphene and graphene-based metal-oxide hybrids for use as electrode materials in lithium-ion batteries.


Synlett ◽  
2018 ◽  
Vol 29 (20) ◽  
pp. 2595-2600 ◽  
Author(s):  
Dongbing Zhao ◽  
Wen-Tao Zhao ◽  
Fang Gao

The σ-bond cross-exchange reaction, which involves cleavage and subsequent exchange between different nonpolar σ-bonds, constitutes an attractive protocol for rapid access to organic skeletons with 100% atom economy. Herein, we give a brief summary of recent achievements in this approach for the synthesis of diverse silacycles, highlighting our recent advances in the first intermolecular σ-bond exchange between C–C bonds of cyclopropenones and C–Si bonds of (benzo)silacyclobutanes.1 Introduction2 σ-Bond Exchange-Reaction of Benzocyclobutanones to Silacycles3 σ-Bond Exchange-Reaction of Ethyl Cyclopropylideneacetates to Silacycles4 σ-Bond Exchange-Reaction of Cyclopropenones to Silacycles5 Conclusion


2020 ◽  
Vol 8 (15) ◽  
pp. 4988-5014 ◽  
Author(s):  
Bing Wang ◽  
Zhi Bin Zhang ◽  
Shi Peng Zhong ◽  
Zhao Qiang Zheng ◽  
Ping Xu ◽  
...  

This review introduces recent advances in the materials, fabrication and application of pulsed-laser deposition for high performance photo-detectors from an overall perspective. Challenges and future development trends are also discussed.


2002 ◽  
Vol 2002 ◽  
pp. 235-236
Author(s):  
N.T. Hobbs

My remarks explore the role of theory in making progress in science generally and particularly in ecology. I discuss what theory is (and isn’t). I argue that theory is a fundamentally important part of doing science efficiently, and I discuss some exciting new approaches for combining theory, data, and statistics to enhance scientific understanding. I illustrate these approaches using examples from work on foraging by mammalian herbivores.


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