scholarly journals Regioselective routes to orthogonally-substituted aromatic MIDA boronates

2016 ◽  
Vol 14 (28) ◽  
pp. 6751-6756 ◽  
Author(s):  
Adam J. Close ◽  
Paul Kemmitt ◽  
S. Mark Roe ◽  
John Spencer
Keyword(s):  
Methyliminodiacetic Acid

A series of tetrasubstituted aromatics has been synthesized, many of which are based on elaborated N-methyliminodiacetic acid (MIDA)-boronates.

Electroanalytical chemistry of vanadium complexes. Comparison of the voltammetric features of amavadine with those of the vanadium complexes with iminodiacetic acid and methyliminodiacetic acid

1989 ◽  
Vol 54 (1) ◽  
pp. 53-63 ◽  
Author(s):  
Roland Meier ◽  
Harald Frank ◽  
Reinhard Kirmse ◽  
Reiner Salzer ◽  
Joachim Stach ◽  
...  
Keyword(s):  
Iminodiacetic Acid ◽  
Vanadium Complexes ◽  
Reduction Mechanism ◽  
Reversible Process ◽  
Electroanalytical Chemistry ◽  
Probable Explanation ◽  
Chemical Sense ◽  
Ece Mechanism ◽  
Methyliminodiacetic Acid

The voltammetric behaviour of amavadine (AV) was found to be considerably different from that of the complexes of VO2+ with methyliminodiacetic acid (MIDA) and iminodiacetic acid (IDA). To get an insight in the rather complicated reduction mechanism of the latter complexes the reductions of V(III) (MIDA) and V(III) (IDA) have been studied for comparison. The species V(III) (MIDA)2 and V(III) (IDA)2 are reduced to the appropriate V(II) complexes in a chemically reversible process. VO(MIDA)2 and VO(IDA)2 are reduced to the same complexes via an ECE mechanism. The investigation of the electroreduction of AV shows that this process is not reversible in the chemical sense. As a probable explanation, the conclusion was drawn that AV and the usual V(IV)O-iminocarboxylato complexes differ in their structures.

scholarly journals Microwave-mediated synthesis of N-methyliminodiacetic acid (MIDA) boronates

Tetrahedron ◽  
2014 ◽  
Vol 70 (47) ◽  
pp. 9125-9131 ◽  
Author(s):  
Adam J. Close ◽  
Paul Kemmitt ◽  
Matthew K. Emmerson ◽  
John Spencer
Keyword(s):  
Methyliminodiacetic Acid

Palladium-catalyzed ligand-free and efficient Suzuki–Miyaura reaction of heteroaryl halides with MIDA boronates in water

RSC Advances ◽  
2015 ◽  
Vol 5 (67) ◽  
pp. 54312-54315 ◽  
Author(s):  
Chun Liu ◽  
Xinmin Li ◽  
Chao Liu ◽  
Xinnan Wang ◽  
Jieshan Qiu
Keyword(s):  
Pure Water ◽  
Environment Friendly ◽  
Ligand Free ◽  
Palladium Catalyzed ◽  
Methyliminodiacetic Acid

A simple and environment-friendly protocol for the palladium-catalyzed Suzuki–Miyaura reaction of heteroaryl halides with N-methyliminodiacetic acid (MIDA) boronates in pure water is developed.

scholarly journals Vibrational Spectroscopy of N-Methyliminodiacetic Acid (MIDA)-Protected Boronate Ester: Examination of the B–N Dative Bond

2011 ◽  
Vol 115 (24) ◽  
pp. 6426-6431 ◽  
Author(s):  
Dana N. Reinemann ◽  
Ashley M. Wright ◽  
Jonathan D. Wolfe ◽  
Gregory S. Tschumper ◽  
Nathan I. Hammer
Keyword(s):  
Vibrational Spectroscopy ◽  
Boronate Ester ◽  
Dative Bond ◽  
Methyliminodiacetic Acid

A new 3s–3d heterometallic polymer containingN-methyliminodiacetic acid: synthesis, structure and characterization

2007 ◽  
Vol 21 (5) ◽  
pp. 350-354 ◽  
Author(s):  
Feng-Xian Gao ◽  
Wen Gu ◽  
Jing Qian ◽  
Yong-Sheng Yang ◽  
Shi-Ping Yan
Keyword(s):  
Acid Synthesis ◽  
Heterometallic Polymer ◽  
Methyliminodiacetic Acid

scholarly journals Oxidative Heck Reactions using Aryltrifluoroborates and Aryl N -Methyliminodiacetic Acid (MIDA) Boronates

ChemistryOpen ◽  
2012 ◽  
Vol 1 (3) ◽  
pp. 140-146 ◽  
Author(s):  
Jonas Sävmarker ◽  
Jonas Lindh ◽  
Peter Nilsson ◽  
Per J. R. Sjöberg ◽  
Mats Larhed
Keyword(s):  
Heck Reactions ◽  
Methyliminodiacetic Acid
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