Oxidative Heck Reactions using Aryltrifluoroborates and Aryl N
-Methyliminodiacetic Acid (MIDA) Boronates

Jonas Sävmarker; Jonas Lindh; Peter Nilsson; Per J. R. Sjöberg; Mats Larhed

doi:10.1002/open.201200007

Oxidative Heck Reactions using Aryltrifluoroborates and Aryl N -Methyliminodiacetic Acid (MIDA) Boronates

ChemistryOpen ◽

10.1002/open.201200007 ◽

2012 ◽

Vol 1 (3) ◽

pp. 140-146 ◽

Cited By ~ 4

Author(s):

Jonas Sävmarker ◽

Jonas Lindh ◽

Peter Nilsson ◽

Per J. R. Sjöberg ◽

Mats Larhed

Keyword(s):

Heck Reactions ◽

Methyliminodiacetic Acid

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Heterogeneity in Heck Reactions with Heterogeneous Precatalysts

Current Organic Chemistry ◽

10.2174/1385272822666180129143614 ◽

2018 ◽

Vol 22 (10) ◽

pp. 1022-1038 ◽

Cited By ~ 5

Author(s):

Lin Huang

Keyword(s):

Heck Reactions

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Nickel and Cobalt-Catalyzed Coupling of Alkyl Halides with Alkenes via Heck Reactions and Radical Conjugate Addition

Mini-Reviews in Medicinal Chemistry ◽

10.2174/1389557511313060003 ◽

2013 ◽

Vol 13 (6) ◽

pp. 802-813 ◽

Cited By ~ 17

Author(s):

Qun Qian ◽

Zhenhua Zang ◽

Yang Chen ◽

Weiqi Tong ◽

Hegui Gong

Keyword(s):

Conjugate Addition ◽

Alkyl Halides ◽

Heck Reactions

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Electroanalytical chemistry of vanadium complexes. Comparison of the voltammetric features of amavadine with those of the vanadium complexes with iminodiacetic acid and methyliminodiacetic acid

Collection of Czechoslovak Chemical Communications ◽

10.1135/cccc19890053 ◽

1989 ◽

Vol 54 (1) ◽

pp. 53-63 ◽

Cited By ~ 4

Author(s):

Roland Meier ◽

Harald Frank ◽

Reinhard Kirmse ◽

Reiner Salzer ◽

Joachim Stach ◽

...

Keyword(s):

Iminodiacetic Acid ◽

Vanadium Complexes ◽

Reduction Mechanism ◽

Reversible Process ◽

Electroanalytical Chemistry ◽

Probable Explanation ◽

Chemical Sense ◽

Ece Mechanism ◽

Methyliminodiacetic Acid

The voltammetric behaviour of amavadine (AV) was found to be considerably different from that of the complexes of VO2+ with methyliminodiacetic acid (MIDA) and iminodiacetic acid (IDA). To get an insight in the rather complicated reduction mechanism of the latter complexes the reductions of V(III) (MIDA) and V(III) (IDA) have been studied for comparison. The species V(III) (MIDA)2 and V(III) (IDA)2 are reduced to the appropriate V(II) complexes in a chemically reversible process. VO(MIDA)2 and VO(IDA)2 are reduced to the same complexes via an ECE mechanism. The investigation of the electroreduction of AV shows that this process is not reversible in the chemical sense. As a probable explanation, the conclusion was drawn that AV and the usual V(IV)O-iminocarboxylato complexes differ in their structures.

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