A benchtop capillary flow layer-by-layer (CF-LbL) platform for rapid assembly and screening of biodegradable nanolayered films

Lab on a Chip ◽  
2016 ◽  
Vol 16 (23) ◽  
pp. 4601-4611 ◽  
Author(s):  
Ziye Dong ◽  
Ling Tang ◽  
Caroline C. Ahrens ◽  
Zhenya Ding ◽  
Vi Cao ◽  
...  
Keyword(s):  
Surface Roughness ◽  
Film Thickness ◽  
Capillary Flow ◽  
Layer By Layer

We report a benchtop platform to systematically study film thickness, surface roughness, biocompatibility and degradation of a series of biodegradable nanolayered films.

Detection of Interfaces States Correlated with Layer-by-Layer Oxidation on Si(100)

1999 ◽  
Vol 592 ◽  
Author(s):  
T. Hattori ◽  
H. Nohira ◽  
Y Teramoto ◽  
N. Watanabe
Keyword(s):  
Surface Roughness ◽  
Oxide Film ◽  
Film Thickness ◽  
Interface State ◽  
State Density ◽  
Layer By Layer ◽  
Oxide Film Thickness ◽  
Maximum Value ◽  
State Densities ◽  
Atomically Flat

ABSTRACTThe interface state densities near the midgap were measured with the progress of oxidation of atomically flat Si(100) surface. It was found that the interface state distribution in Si bandgap changes periodically with the progress of oxidation. Namely, the interface-state density near the midgap of Si exhibits drastic decrease at oxide film thickness where the surface roughness of oxide film takes its minimum value, while that does not exhibit decrease at the oxide film thickness where the surface roughness takes its maximum value. In order to minimize interface state densities the oxide film thickness should be precisely controlled to within an accuracy of 0.02 nm.

Morphological Transition of Epitaxial Rhodium (111)

1995 ◽  
Vol 399 ◽  
Author(s):  
Frank Tsui ◽  
Joanne Wellman ◽  
Ctirad Uher ◽  
Roy Clarke
Keyword(s):  
Surface Roughness ◽  
Film Thickness ◽  
Nucleation And Growth ◽  
Layer Growth ◽  
Morphological Transition ◽  
Layer By Layer ◽  
Surface Features ◽  
General Pathway ◽  
Nucleation Size ◽  
Persistent Layer

ABSTRACTWe report a global morphological transition in the nucleation and growth of epitaxial Rh (111). The transition occurs near 600 K, about 1/4 of the Rh melting temperature, and is signaled by a change in the shape of the surface features from fingered to compact. The transition appears to be related to a change in the critical nucleation size from 1 to 2 atoms. On both sides of the transition, there lies a regime of persistent layer-by-layer growth indicated by a minimum in surface roughness and by the presence of RHEED oscillations. The general surface features exhibit well defined length scales that are not self-affine, and as growth proceeds they increase in size following a power-law dependence on film thickness with a temperature-independent exponent of 0.33 ± 0.03. The results suggest a general pathway to the layer-by-layer growth of close-packed metals.

A new method for quantifying the blocking of coated paperboard

TAPPI Journal ◽  
2010 ◽  
Vol 9 (5) ◽  
pp. 29-35 ◽  
Author(s):  
PAULINE SKILLINGTON ◽  
YOLANDE R. SCHOEMAN ◽  
VALESKA CLOETE ◽  
PATRICE C. HARTMANN
Keyword(s):  
Surface Roughness ◽  
Fatty Acid ◽  
Surface Energy ◽  
Film Thickness ◽  
External Factors ◽  
Additive Concentration ◽  
Pressure Surface ◽  
Fatty Acid Amides ◽  
Coated Surfaces ◽  
Definite Period

Blocking is undesired adhesion between two surfaces when subjected to pressure and temperature constraints. Blocking between two coated paperboards in contact with each other may be caused by inter-diffusion, adsorption, or electrostatic forces occurring between the respective coating surfaces. These interactions are influenced by factors such as the temperature, pressure, surface roughness, and surface energy. Blocking potentially can be reduced by adjusting these factors, or by using antiblocking additives such as talc, amorphous silica, fatty acid amides, or polymeric waxes. We developed a method of quantifying blocking using a rheometer. Coated surfaces were put in contact with each other with controlled pressure and temperature for a definite period. We then measured the work necessary to pull the two surfaces apart. This was a reproducible way to accurately quantify blocking. The method was applied to determine the effect external factors have on the blocking tendency of coated paperboards, i.e., antiblocking additive concentration, film thickness, temperature, and humidity.

scholarly journals Modeling the Layer-by-Layer Growth of HKUST-1 Metal-Organic Framework Thin Films

Nanomaterials ◽  
2021 ◽  
Vol 11 (7) ◽  
pp. 1631
Author(s):  
Qiang Zhang ◽  
Yohanes Pramudya ◽  
Wolfgang Wenzel ◽  
Christof Wöll
Keyword(s):  
Thin Films ◽  
Surface Roughness ◽  
Deposition Rate ◽  
Layer Growth ◽  
Coarse Grained ◽  
Structural Defects ◽  
Effect Of Temperature ◽  
Layer By Layer ◽  
Reactant Concentration ◽  
Metal Organic

Metal organic frameworks have emerged as an important new class of materials with many applications, such as sensing, gas separation, drug delivery. In many cases, their performance is limited by structural defects, including vacancies and domain boundaries. In the case of MOF thin films, surface roughness can also have a pronounced influence on MOF-based device properties. Presently, there is little systematic knowledge about optimal growth conditions with regard to optimal morphologies for specific applications. In this work, we simulate the layer-by-layer (LbL) growth of the HKUST-1 MOF as a function of temperature and reactant concentration using a coarse-grained model that permits detailed insights into the growth mechanism. This model helps to understand the morphological features of HKUST-1 grown under different conditions and can be used to predict and optimize the temperature for the purpose of controlling the crystal quality and yield. It was found that reactant concentration affects the mass deposition rate, while its effect on the crystallinity of the generated HKUST-1 film is less pronounced. In addition, the effect of temperature on the surface roughness of the film can be divided into three regimes. Temperatures in the range from 10 to 129 °C allow better control of surface roughness and film thickness, while film growth in the range of 129 to 182 °C is characterized by a lower mass deposition rate per cycle and rougher surfaces. Finally, for T larger than 182 °C, the film grows slower, but in a smooth fashion. Furthermore, the potential effect of temperature on the crystallinity of LbL-grown HKUST-1 was quantified. To obtain high crystallinity, the operating temperature should preferably not exceed 57 °C, with an optimum around 28 °C, which agrees with experimental observations.

Effect of Water Temperature, pH Value, and Film Thickness on the Wettability Behaviour of Copper Surfaces Coated with Copper Using EB-PVD Technique

2019 ◽  
Vol 60 ◽  
pp. 124-141 ◽  
Author(s):  
Naser Ali ◽  
Joao Amaral Teixeira ◽  
Abdulmajid Addali
Keyword(s):  
Surface Roughness ◽  
Contact Angle ◽  
Film Thickness ◽  
Water Temperature ◽  
Ph Value ◽  
Surface Wettability ◽  
Copper Surfaces ◽  
Force Microscopy ◽  
Atomic Force ◽  
Static Contact

This research investigates the effect of surface roughness, water temperature, and pH value on the wettability behaviour of copper surfaces. An electron beam physical vapour deposition technique was used to fabricate 25, 50, and 75 nm thin films of copper on the surface of copper substrates. Surface topographical analysis, of the uncoated and coated samples, was performed using an atomic force microscopy device to observe the changes in surface microstructure. A goniometer device was then employed to examine the surface wettability of the samples by obtaining the static contact angle between the liquid and the attached surface using the sessile drops technique. Waters of pH 4, 7, and 9 were employed as the contact angle testing fluids at a set of fixed temperatures that ranged from 20°C to 60°C. It was found that increasing the deposited film thickness reduces the surface roughness of the as-prepared copper surfaces and thus causing the surface wettability to diverge from its initial hydrophobic nature towards the hydrophilic behaviour region. A similar divergence behaviour was seen with the rise in temperature of water of pH 4, and 9. In contrast, the water of pH 7, when tested on the uncoated surface, ceased to reach a contact angle below 90o. It is believed that the observed changes in surface wettability behaviour is directly linked to the liquid temperature, pH value, surface roughness, along with the Hofmeister effect between the water and the surface in contact.

Rough Air-Soft Elastohydrodynamic Lubrication

2013 ◽  
Vol 420 ◽  
pp. 30-35
Author(s):  
Khanittha Wongseedakaew ◽  
Jesda Panichakorn
Keyword(s):  
Surface Roughness ◽  
Film Thickness ◽  
Modulus Of Elasticity ◽  
Contact Region ◽  
Elastohydrodynamic Lubrication ◽  
Multilevel Methods ◽  
Inlet Temperature ◽  
Film Pressure ◽  
Air Inlet ◽  
Air Film

This paper presents the effects of rough surface air-soft elastohydrodynamic lubrication (EHL) of rollers for soft material under the effect of air molecular slip. The time independent modified Reynolds equation and elasticity equation were solved numerically using finite different method, Newton-Raphson method and multigrid multilevel methods were used to obtain the film pressure profiles and film thickness in the contact region. The effects of amplitude of surface roughness, modulus of elasticity and air inlet temperature are examined. The simulation results showed surface roughness has effect on film thickness but it little effect to air film pressure. When the amplitude of surface roughness and modulus of elasticity increased, the air film thickness decreased but air film pressure increased. However, the air inlet temperature increased when the air film thickness increased.

The Surface-Roughness of Bearing-Surfaces and its Relation to Oil Film Thickness at Breakdown

1949 ◽  
Vol 161 (1) ◽  
pp. 73-79 ◽  
Author(s):  
A. Cameron
Keyword(s):  
Surface Roughness ◽  
Film Thickness ◽  
Hydrodynamic Theory ◽  
Quantitative Relation ◽  
Metal Contact ◽  
Initial Contact ◽  
Frictional Drag ◽  
Average Roughness ◽  
Finished Steel ◽  
Oil Film

In this paper the relation of surface roughness of bearing surfaces to allowable film thickness is studied quantitatively with a simple Michell pad apparatus. The pads used were faced with white metal and ran against mild steel collars. The lubricants studied were water, soap solution, paraffin, and light oil. There was little difference in the frictional behaviour of any of the lubricants, except that the aqueous lubricants would not run with very finely finished steel surfaces. The onset of metal to metal contact was detected by an increase in the frictional drag, and also by the change in electrical conductivity between the pad and collar—an extremely sensitive method. The paper shows that there is, at any rate for this system, a quantitative relation between the total surface roughness of the rubbing surfaces and the calculated oil film thickness both at the initial metal to metal contact and seizure. Initial contact occurs when the outlet film thickness, calculated from normal hydrodynamic theory, falls to three times the maximum surface roughness and seizure occurs when it is double the average roughness.

Effect of Rolling Velocity and Maximum Hertzian Pressure on Fluid Film in Steady State EHL Line Contact with Rough Surface and Linear Piezoviscosity

2014 ◽  
Vol 592-594 ◽  
pp. 1371-1375
Author(s):  
Nitesh Talekar ◽  
Punit Kumar
Keyword(s):  
Surface Roughness ◽  
Steady State ◽  
Film Thickness ◽  
Rough Surface ◽  
Computer Code ◽  
Fluid Film ◽  
Line Contact ◽  
Rolling Velocity ◽  
Load Carrying ◽  
Lubricated Contact

Consideration of surface roughness in steady state EHL line contact is the first step towards understanding the lubrication of rough surface problem. Current paper investigates the use of sinusoidal waviness in the contact; more precisely it gives performance of real fluid in EHL line contact. The effect of various parameters like rolling velocity (U) and maximum Hertzian pressure (ph) on surface roughness by using properties of linear and exponential piezo-viscosity is taken into consideration to evaluate behavior of pressure distribution of load carrying fluid film and film thickness. Full isothermal, Newtonian simulation of EHL problem gives described effects. Spiking or fluctuation of pressure and film thickness curves is expected to show presence of irregularities on the surface chosen and amount of fluctuation depends on certain parameters and intensity of irregularities present. Rolling side domain of-4.5 ≤ X ≤ 1.5 with grid size ∆X=0.01375 is selected. A computer code is developed to solve Reynolds equation, which governs the generation of pressure in the lubricated contact zone is discritized and solved along with load balance equation using Newton-Raphson technique.

A Starved Mixed Elastohydrodynamic Lubrication Model for the Prediction of Lubrication Performance, Friction and Flash Temperature With Arbitrary Entrainment Angle

2017 ◽  
Vol 140 (3) ◽  
Author(s):  
Wei Pu ◽  
Dong Zhu ◽  
Jiaxu Wang
Keyword(s):  
Surface Roughness ◽  
Film Thickness ◽  
Elastohydrodynamic Lubrication ◽  
Industrial Applications ◽  
Operating Conditions ◽  
Flash Temperature ◽  
Machined Surface ◽  
Lubrication Performance ◽  
Wide Range ◽  
Starved Lubrication

In this study, a modified mixed lubrication model is developed with consideration of machined surface roughness, arbitrary entraining velocity angle, starvation, and cavitation. Model validation is executed by means of comparison between the obtained numerical results and the available starved elastohydrodynamic lubrication (EHL) data found from some previous studies. A comprehensive analysis for the effect of inlet oil supply condition on starvation and cavitation, mixed EHL characteristics, friction and flash temperature in elliptical contacts is conducted in a wide range of operating conditions. In addition, the influence of roughness orientation on film thickness and friction is discussed under different starved lubrication conditions. Obtained results reveal that inlet starvation leads to an obvious reduction of average film thickness and an increase in interasperity cavitation area due to surface roughness, which results in significant increment of asperity contacts, friction, and flash temperature. Besides, the effect of entrainment angle on film thickness will be weakened if the two surfaces operate under starved lubrication condition. Furthermore, the results show that the transverse roughness may yield thicker EHL films and lower friction than the isotropic and longitudinal if starvation is taken into account. Therefore, the starved mixed EHL model can be considered as a useful engineering tool for industrial applications.

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