Highly efficient hydrogen evolution from seawater by a low-cost and stable CoMoP@C electrocatalyst superior to Pt/C

2017 ◽  
Vol 10 (3) ◽  
pp. 788-798 ◽  
Author(s):  
Yuan-Yuan Ma ◽  
Cai-Xia Wu ◽  
Xiao-Jia Feng ◽  
Hua-Qiao Tan ◽  
Li-Kai Yan ◽  
...  

A low-cost CoMoP@C electrocatalyst exhibits high efficiency and stable HER performance superior to commercial 20% Pt/C, and can directly work in seawater for the HER with a Faradaic efficiency of 92.5%.

2021 ◽  
Author(s):  
Meng Wang ◽  
Zepeng Lv ◽  
Xuewei Lv ◽  
Qian Li ◽  
Jie Dang

Abstract Density functional theory (DFT) calculation indicators (ΔG, densities of state, D-band and bader charge) are commonly used to predict and analyze the hydrogen evolution reaction (HER) activity of catalysts, and most studies discuss only one or few of these indicators’ impact on catalysis, but still no report has comprehensively evaluated the influence of all these indicators on catalytic performance. Herein, foreseen by comprehensive consideration first, we report transition metal doped Ni3N nanosheets combined on Ni foam for utra-efficient alkaline hydrogen evolution. For dual transition metals doped Ni3N, Co,V-Ni3N exhibits remarkable HER performance with a significantly low overpotential of only 10 mV in alkaline electrolyte and 41 mV in alkaline seawater electrolyte at 10 mA cm− 2; while for single transition metal doped Ni3N, V-Ni3N exhibits the best performance with an overpotential of 15 mV and a Tafel slope of 37 mV dec− 1. Our work highlights the importance of comprehensive evaluation of DFT calculation indexes, and opens up a new method for the rational design of efficient and low-cost catalysts.


2019 ◽  
Vol 6 (10) ◽  
pp. 2727-2735 ◽  
Author(s):  
Xue Song ◽  
Pan Yang ◽  
Jingchuan Wang ◽  
Xiaochong Zhao ◽  
Yuanlin Zhou ◽  
...  

NiFe nano-catalysts modified by the dopant of Pd were reducted on UiO-66 by NaBH4, which have been used as a low cost and high efficient catalyst with outstanding activity and durability for hydrogen generation from the decomposition of hydrazine hydrate.


2019 ◽  
Vol 7 (8) ◽  
pp. 3752-3756 ◽  
Author(s):  
Hong Wu ◽  
Xingxing Li ◽  
Ruiqi Zhang ◽  
Jinlong Yang

Proposal of a B3S nanosheet as a low-cost and high-efficiency catalyst for hydrogen evolution.


2016 ◽  
Vol 4 (18) ◽  
pp. 6824-6830 ◽  
Author(s):  
Heng Deng ◽  
Chi Zhang ◽  
Yunchao Xie ◽  
Travis Tumlin ◽  
Lily Giri ◽  
...  

The direct laser writing method has emerged as a novel technique for fabricating MoS2/carbon hybrid HER catalysts with low cost, high efficiency, and flexible designability.


2020 ◽  
Vol 1 (5) ◽  
pp. 1161-1167
Author(s):  
Zhixing Cheng ◽  
Ali Saad ◽  
Samira Adimi ◽  
Haichuan Guo ◽  
Siqi Liu ◽  
...  

A new means of producing MOF derived TMN materials, which in conjunction with suitable dyes, offer high-efficiency and low-cost avenues for making photocatalysts for hydrogen production.


Nanoscale ◽  
2020 ◽  
Vol 12 (45) ◽  
pp. 23125-23133
Author(s):  
Yifan Tian ◽  
Xinying Xue ◽  
Yu Gu ◽  
Zhaoxi Yang ◽  
Guo Hong ◽  
...  

Electrochemically splitting water into hydrogen and oxygen plays a significant role in the commercialization of hydrogen energy as well as fuel cells, but it remains a challenge to design and fabricate low-cost and high-efficiency electrocatalysts.


2021 ◽  
Author(s):  
Lijun Ma ◽  
Jing Xu ◽  
Juan Zhang ◽  
Zhenlu Liu ◽  
Xinyu Liu

The development of high-efficiency and low-cost photocatalysts for hydrogen production reaction is very important to solve energy problems. This paper studied the photocatalytic H2 evolution activity of CeO2/CoS2 heterojunction catalyst...


2016 ◽  
Vol 213 ◽  
pp. 236-243 ◽  
Author(s):  
Li Shao ◽  
Xing Qian ◽  
Xiaoying Wang ◽  
Hongmei Li ◽  
Rucai Yan ◽  
...  

2015 ◽  
Vol 51 (81) ◽  
pp. 15067-15070 ◽  
Author(s):  
Belete B. Beyene ◽  
Sandeep B. Mane ◽  
Chen-Hsiung Hung

CoTPPS is an efficient electrocatalyst for H2 generation from neutral phosphate buffer solution. It features quantitative Faradaic efficiency with a TOF of ∼1.83 s−1 and a TON of 1.9 × 104 mol of H2 per mole of catalyst at an applied potential of −1.29 V (vs. SHE).


Author(s):  
Benzhi Wang ◽  
Lixia Wang ◽  
Yongteng Qian ◽  
Yuting Yang ◽  
Tayirjan Taylor Isimjan ◽  
...  

The development of low-cost and highly efficient hydrogen evolution reaction (HER) catalysts remains a significant challenge for the advancement of sustainable energy conversion systems. Herein, we have reported the successful...


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