Self-assembled half-sandwich polyhedral cages via flexible Schiff-base ligands: an unusual macrocycle-to-cage conversion
Half-sandwich M6(L1)4 octahedral and M8(L2)4 cubic cages have been assembled by flexible Schiff-base ligands upon coordination to Cp*Rh(iii) organometallic acceptors. In particular, the Rh(iii)-based half-sandwich M2(HL1)2 macrocycle rearranges in solution to give a M6(L1)4 cage.
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