Self-assembled half-sandwich polyhedral cages via flexible Schiff-base ligands: an unusual macrocycle-to-cage conversion

2016 ◽  
Vol 45 (35) ◽  
pp. 13675-13679 ◽  
Author(s):  
Jing-Jing Liu ◽  
Yue-Jian Lin ◽  
Zhen-Hua Li ◽  
Guo-Xin Jin

Half-sandwich M6(L1)4 octahedral and M8(L2)4 cubic cages have been assembled by flexible Schiff-base ligands upon coordination to Cp*Rh(iii) organometallic acceptors. In particular, the Rh(iii)-based half-sandwich M2(HL1)2 macrocycle rearranges in solution to give a M6(L1)4 cage.

RSC Advances ◽  
2015 ◽  
Vol 5 (82) ◽  
pp. 67011-67030 ◽  
Author(s):  
Harsh Vardhan ◽  
Akshay Mehta ◽  
Ipsita Nath ◽  
Francis Verpoort

This review highlights the intercession of Schiff base ligands in the preparation of self-assembled architectures mainly metal–organic polyhedra and describes their unprecedented role in various key applications.


2019 ◽  
Vol 33 (10) ◽  
Author(s):  
C.E. Satheesh ◽  
Pushpanathan N. Sathish Kumar ◽  
P. Raghavendra Kumara ◽  
Ramasamy Karvembu ◽  
Amar Hosamani ◽  
...  

2015 ◽  
Vol 44 (39) ◽  
pp. 17152-17165 ◽  
Author(s):  
Amit Kumar ◽  
Rampal Pandey ◽  
Ashish Kumar ◽  
Rakesh Kumar Gupta ◽  
Mrigendra Dubey ◽  
...  

Tetranuclear supramolecular copper(ii) complexes derived from asymmetric Schiff bases have been synthesized, characterized and demonstrated as size selective hosts for ADP/ATP.


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