Half‐sandwich Ru (II) complexes containing (N, O) Schiff base ligands: Catalysts for base‐free transfer hydrogenation of ketones

2019 ◽  
Vol 33 (10) ◽  
Author(s):  
C.E. Satheesh ◽  
Pushpanathan N. Sathish Kumar ◽  
P. Raghavendra Kumara ◽  
Ramasamy Karvembu ◽  
Amar Hosamani ◽  
...  
2016 ◽  
Vol 45 (35) ◽  
pp. 13675-13679 ◽  
Author(s):  
Jing-Jing Liu ◽  
Yue-Jian Lin ◽  
Zhen-Hua Li ◽  
Guo-Xin Jin

Half-sandwich M6(L1)4 octahedral and M8(L2)4 cubic cages have been assembled by flexible Schiff-base ligands upon coordination to Cp*Rh(iii) organometallic acceptors. In particular, the Rh(iii)-based half-sandwich M2(HL1)2 macrocycle rearranges in solution to give a M6(L1)4 cage.


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