Measuring giant anisotropy in paramagnetic transition metal complexes with relevance to single-ion magnetism

2016 ◽  
Vol 45 (42) ◽  
pp. 16751-16763 ◽  
Author(s):  
J. Krzystek ◽  
Joshua Telser
Keyword(s):  
Transition Metal ◽  
Magnetic Anisotropy ◽  
Metal Complexes ◽  
Transition Metal Complexes ◽  
Coordination Complexes ◽  
Multiple Methods

“Giant magnetic anisotropy” is a phenomenon identified in certain coordination complexes of nd- and nf-block ions. The strengths and weaknesses of multiple methods used to measure it are evaluated.

scholarly journals Magnetic Anisotropy in “Scorpionate” First-Row Transition-Metal Complexes: A Theoretical Investigation

2015 ◽  
Vol 21 (9) ◽  
pp. 3716-3726 ◽  
Author(s):  
Marko Perić ◽  
Amador García-Fuente ◽  
Matija Zlatar ◽  
Claude Daul ◽  
Stepan Stepanović ◽  
...  
Keyword(s):  
Transition Metal ◽  
Magnetic Anisotropy ◽  
Metal Complexes ◽  
Transition Metal Complexes ◽  
Theoretical Investigation

Inter-ligand delocalisations in transition metal complexes containing multiple non-innocent ligands

2019 ◽  
Vol 48 (39) ◽  
pp. 14801-14807 ◽  
Author(s):  
Ho Chuen Wan ◽  
Jing-Xuan Zhang ◽  
Chung Sum Leung ◽  
Fu Kit Sheong ◽  
Zhenyang Lin
Keyword(s):  
Transition Metal ◽  
Metal Complexes ◽  
Transition Metal Complexes ◽  
Coordination Complexes ◽  
Metal Centre

Inter-ligand delocalisation across the metal centre has been identified in a number of coordination complexes and systematically investigated with the help of PIO analysis.

Late first-row transition metal complexes of a 17-membered piperazine-based macrocyclic ligand: structures and magnetism

2020 ◽  
Vol 49 (26) ◽  
pp. 9057-9069
Author(s):  
Eva Zahradníková ◽  
Radovan Herchel ◽  
Ivan Šalitroš ◽  
Ivana Císařová ◽  
Bohuslav Drahoš
Keyword(s):  
Transition Metal ◽  
Magnetic Anisotropy ◽  
Metal Complexes ◽  
Transition Metal Complexes ◽  
Macrocyclic Ligand ◽  
Coordination Numbers

Three different coordination numbers and moderate/large magnetic anisotropy were observed in transition metal complexes of a 17-membered piperazine-based macrocyclic ligand.

scholarly journals Tools for Predicting the Nature and Magnitude of Magnetic Anisotropy in Transition Metal Complexes: Application to Co(II) Complexes

2016 ◽  
Vol 2 (3) ◽  
pp. 31 ◽  
Author(s):  
Benjamin Cahier ◽  
Rémi Maurice ◽  
Hélène Bolvin ◽  
Talal Mallah ◽  
Nathalie Guihéry
Keyword(s):  
Transition Metal ◽  
Magnetic Anisotropy ◽  
Metal Complexes ◽  
Transition Metal Complexes

Trigonal Prismatic Tris-pyridineoximate Transition Metal Complexes: A Cobalt(II) Compound with High Magnetic Anisotropy

2017 ◽  
Vol 56 (12) ◽  
pp. 6943-6951 ◽  
Author(s):  
Alexander A. Pavlov ◽  
Svetlana A. Savkina ◽  
Alexander S. Belov ◽  
Yulia V. Nelyubina ◽  
Nikolay N. Efimov ◽  
...  
Keyword(s):  
Transition Metal ◽  
Magnetic Anisotropy ◽  
Metal Complexes ◽  
Transition Metal Complexes ◽  
Trigonal Prismatic
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