Chemical Applications of Magnetic Anisotropy Studies on Transition Metal Complexes

2007 ◽  
pp. 309-408b ◽  
Author(s):  
S. Mitra
Keyword(s):  
Transition Metal ◽  
Magnetic Anisotropy ◽  
Metal Complexes ◽  
Transition Metal Complexes

Measuring giant anisotropy in paramagnetic transition metal complexes with relevance to single-ion magnetism

2016 ◽  
Vol 45 (42) ◽  
pp. 16751-16763 ◽  
Author(s):  
J. Krzystek ◽  
Joshua Telser
Keyword(s):  
Transition Metal ◽  
Magnetic Anisotropy ◽  
Metal Complexes ◽  
Transition Metal Complexes ◽  
Coordination Complexes ◽  
Multiple Methods

“Giant magnetic anisotropy” is a phenomenon identified in certain coordination complexes of nd- and nf-block ions. The strengths and weaknesses of multiple methods used to measure it are evaluated.

scholarly journals Magnetic Anisotropy in “Scorpionate” First-Row Transition-Metal Complexes: A Theoretical Investigation

2015 ◽  
Vol 21 (9) ◽  
pp. 3716-3726 ◽  
Author(s):  
Marko Perić ◽  
Amador García-Fuente ◽  
Matija Zlatar ◽  
Claude Daul ◽  
Stepan Stepanović ◽  
...  
Keyword(s):  
Transition Metal ◽  
Magnetic Anisotropy ◽  
Metal Complexes ◽  
Transition Metal Complexes ◽  
Theoretical Investigation

Late first-row transition metal complexes of a 17-membered piperazine-based macrocyclic ligand: structures and magnetism

2020 ◽  
Vol 49 (26) ◽  
pp. 9057-9069
Author(s):  
Eva Zahradníková ◽  
Radovan Herchel ◽  
Ivan Šalitroš ◽  
Ivana Císařová ◽  
Bohuslav Drahoš
Keyword(s):  
Transition Metal ◽  
Magnetic Anisotropy ◽  
Metal Complexes ◽  
Transition Metal Complexes ◽  
Macrocyclic Ligand ◽  
Coordination Numbers

Three different coordination numbers and moderate/large magnetic anisotropy were observed in transition metal complexes of a 17-membered piperazine-based macrocyclic ligand.

scholarly journals Tools for Predicting the Nature and Magnitude of Magnetic Anisotropy in Transition Metal Complexes: Application to Co(II) Complexes

2016 ◽  
Vol 2 (3) ◽  
pp. 31 ◽  
Author(s):  
Benjamin Cahier ◽  
Rémi Maurice ◽  
Hélène Bolvin ◽  
Talal Mallah ◽  
Nathalie Guihéry
Keyword(s):  
Transition Metal ◽  
Magnetic Anisotropy ◽  
Metal Complexes ◽  
Transition Metal Complexes

Trigonal Prismatic Tris-pyridineoximate Transition Metal Complexes: A Cobalt(II) Compound with High Magnetic Anisotropy

2017 ◽  
Vol 56 (12) ◽  
pp. 6943-6951 ◽  
Author(s):  
Alexander A. Pavlov ◽  
Svetlana A. Savkina ◽  
Alexander S. Belov ◽  
Yulia V. Nelyubina ◽  
Nikolay N. Efimov ◽  
...  
Keyword(s):  
Transition Metal ◽  
Magnetic Anisotropy ◽  
Metal Complexes ◽  
Transition Metal Complexes ◽  
Trigonal Prismatic

Mechanochemical changes on cyclometalated Ir(iii) acyclic carbene complexes – design and tuning of luminescent mechanochromic transition metal complexes

2020 ◽  
Vol 7 (3) ◽  
pp. 786-794 ◽  
Author(s):  
Jingqi Han ◽  
Kin-Man Tang ◽  
Shun-Cheung Cheng ◽  
Chi-On Ng ◽  
Yuen-Kiu Chun ◽  
...  
Keyword(s):  
Transition Metal ◽  
Metal Complexes ◽  
Transition Metal Complexes ◽  
Carbene Complexes ◽  
New Class

A new class of luminescent cyclometalated Ir(iii) complexes with readily tunable mechanochromic properties derived from the mechanically induced trans-to-cis isomerization have been developed.

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