Optimizing conditions for utilization of an H2 oxidation catalyst with outer coordination sphere functionalities

2016 ◽  
Vol 45 (24) ◽  
pp. 9786-9793 ◽  
Author(s):  
Arnab Dutta ◽  
Bojana Ginovska ◽  
Simone Raugei ◽  
John A. S. Roberts ◽  
Wendy J. Shaw
Keyword(s):  
Coordination Sphere ◽  
Oxidation Catalyst ◽  
Outer Coordination Sphere ◽  
H2 Oxidation

[Ni(PCy2NArginine2)2]2+ (CyArg) or [Ni(PCy2NBenzyl2)2]2+ (CyBn) were evaluated for H2 oxidation as a function of temperature, pressure, and solvent. 70 °C and 100 atm H2 result in a TOF of 1.1 × 106 s−1 and an overpotential of 240 mV for CyArg in water. In methanol the rates were 280 s−1 for CyArg and 80 s−1 for CyBn, demonstrating the importance of water and the outer coordination sphere (OCS).

Evaluating the role of acidic, basic, and polar amino acids and dipeptides on a molecular electrocatalyst for H2 oxidation

2017 ◽  
Vol 7 (5) ◽  
pp. 1108-1121 ◽  
Author(s):  
Nilusha Priyadarshani Boralugodage ◽  
Rajith Jayasingha Arachchige ◽  
Arnab Dutta ◽  
Garry W. Buchko ◽  
Wendy J. Shaw
Keyword(s):  
Amino Acids ◽  
Coordination Sphere ◽  
Oxidation Catalysts ◽  
Outer Coordination Sphere ◽  
H2 Oxidation

Outer coordination sphere interactions reduce the overpotential for H2 oxidation catalysts (brown ellipse) compared to those that have –COOH groups but don't have stabilizing interactions (blue ellipse).

Phenol Reduces Nitrite to NO at Copper(II): Role of a Proton-Responsive Outer Coordination Sphere in Phenol Oxidation

2020 ◽  
Vol 142 (4) ◽  
pp. 1726-1730 ◽  
Author(s):  
Aditesh Mondal ◽  
Kiran P. Reddy ◽  
Jeffery A. Bertke ◽  
Subrata Kundu
Keyword(s):  
Coordination Sphere ◽  
Phenol Oxidation ◽  
Outer Coordination Sphere

Macromolecular Engineering of the Outer Coordination Sphere of [2Fe-2S] Metallopolymers to Enhance Catalytic Activity for H2 Production

2018 ◽  
Vol 7 (11) ◽  
pp. 1383-1387 ◽  
Author(s):  
William P. Brezinski ◽  
Metin Karayilan ◽  
Kayla E. Clary ◽  
Keelee C. McCleary-Petersen ◽  
Liye Fu ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
Coordination Sphere ◽  
H2 Production ◽  
Outer Coordination Sphere

Outer Coordination Sphere Proton Relay Base and Proximity Effects on Hydrogen Oxidation with Iron Electrocatalysts

2019 ◽  
Vol 38 (6) ◽  
pp. 1391-1396 ◽  
Author(s):  
Neeraj Kumar ◽  
Jonathan M. Darmon ◽  
Charles J. Weiss ◽  
Monte L. Helm ◽  
Simone Raugei ◽  
...  
Keyword(s):  
Coordination Sphere ◽  
Hydrogen Oxidation ◽  
Proximity Effects ◽  
Proton Relay ◽  
Outer Coordination Sphere

Active Hydrogenation Catalyst with a Structured, Peptide-Based Outer-Coordination Sphere

ACS Catalysis ◽  
2012 ◽  
Vol 2 (10) ◽  
pp. 2114-2118 ◽  
Author(s):  
Avijita Jain ◽  
Garry W. Buchko ◽  
Matthew L. Reback ◽  
Molly O’Hagan ◽  
Bojana Ginovska-Pangovska ◽  
...  
Keyword(s):  
Coordination Sphere ◽  
Hydrogenation Catalyst ◽  
Outer Coordination Sphere

Chicken fat for catalysis: a scaffold is as important for molecular complexes for energy transformations as it is for enzymes in catalytic function

2019 ◽  
Vol 3 (12) ◽  
pp. 3260-3278 ◽  
Author(s):  
Joseph A. Laureanti ◽  
Molly O'Hagan ◽  
Wendy J. Shaw
Keyword(s):  
Coordination Sphere ◽  
Molecular Complexes ◽  
Catalytic Performance ◽  
Chicken Fat ◽  
Catalytic Function ◽  
Outer Coordination Sphere

The outer coordination sphere, sometimes called chicken fat, is essential to achieving the best catalytic performance for energy transductions.

scholarly journals Cover Picture: The Role of a Dipeptide Outer-Coordination Sphere on H2 -Production Catalysts: Influence on Catalytic Rates and Electron Transfer (Chem. Eur. J. 6/2013)

2013 ◽  
Vol 19 (6) ◽  
pp. 1837-1837
Author(s):  
Matthew L. Reback ◽  
Bojana Ginovska-Pangovska ◽  
Ming-Hsun Ho ◽  
Avijita Jain ◽  
Thomas C. Squier ◽  
...  
Keyword(s):  
Electron Transfer ◽  
Coordination Sphere ◽  
H2 Production ◽  
Outer Coordination Sphere

Using the Outer Coordination Sphere to Tune the Strength of Metal Extractants

2011 ◽  
Vol 50 (10) ◽  
pp. 4515-4522 ◽  
Author(s):  
Ross S. Forgan ◽  
Benjamin D. Roach ◽  
Peter A. Wood ◽  
Fraser J. White ◽  
John Campbell ◽  
...  
Keyword(s):  
Coordination Sphere ◽  
Outer Coordination Sphere

Incorporating Peptides in the Outer-Coordination Sphere of Bioinspired Electrocatalysts for Hydrogen Production

2011 ◽  
Vol 50 (9) ◽  
pp. 4073-4085 ◽  
Author(s):  
Avijita Jain ◽  
Sheri Lense ◽  
John C. Linehan ◽  
Simone Raugei ◽  
Herman Cho ◽  
...  
Keyword(s):  
Hydrogen Production ◽  
Coordination Sphere ◽  
Outer Coordination Sphere
Sign in / Sign up

Export Citation Format

Share Document